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Crystal Field Theory Crystal Field Theory

Crystal Field Theory - PowerPoint Presentation

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Uploaded On 2015-11-20

Crystal Field Theory - PPT Presentation

Molecular Orbital Theory Donor Acceptor Interactions Molecular Orbital Theory Full ML 6 Molecular Orbital Theory Simplified Counting delectron Configurations Counting delectron Configurations ID: 199809

molecular theory acceptor ligands theory molecular ligands acceptor orbital counting configurations donor transition spectroscopy metal pyridine electron

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Presentation Transcript

Slide1
Slide2
Slide3
Slide4
Slide5

Crystal Field TheorySlide6
Molecular Orbital Theory:

Donor- Acceptor InteractionsSlide7
Molecular Orbital Theory: Full ML6Slide8
Molecular Orbital Theory: SimplifiedSlide9
Counting d-electron ConfigurationsSlide10
Counting d-electron ConfigurationsSlide11
Slide12

How do we predict/explain transition metal structures?Slide13
Slide14
Slide15
Slide16
Slide17

Colors and Spectroscopy of Transition Metal ComplexesSlide18

Sigma Interaction Strength

Spectrochemical

Series:

I

-

< Br

-

<

Cl

-

, F

-

< OH

-

< OH

2

< NH

3

< en < CN

-

< COSlide19

Pi Donor Ligands: Mainly oxides and halidesSlide20

Mn

2+

(aq) MnO

4

-Slide21

Pi Acceptor Ligands: CO, CN

-

, pyridineSlide22

Pi Acceptor Ligands and spectroscopy: CO, CN

-

, pyridineSlide23