Evan M Peck and Bradley D Smith Department of Chemistry and Biochemistry 236 Nieuwland Science Hall University of Notre Dame Notre Dame 46556 IN USA Email smith115ndedu ID: 381766
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Chapter 1. Applications of Synthetic Receptors for Biomolecules
Evan M. Peck and Bradley D. Smith*Department of Chemistry and Biochemistry, 236 Nieuwland Science Hall, University of Notre Dame, Notre Dame, 46556 IN, USA *Email: smith.115@nd.edu
Supplementary information for
Synthetic Receptors for Biomolecules: Design Principles and Applications
©
The Royal Society of Chemistry
2015Slide2
Scheme 1.1 Receptor biomolecule association with 1:1 stoichiometry.
Supplementary information for Synthetic Receptors for Biomolecules: Design Principles and Applications© The Royal Society of Chemistry 2015Slide3
Scheme
1.2 Work flow diagram for supramolecular chemistry research.Supplementary information for Synthetic Receptors for Biomolecules: Design Principles and Applications© The Royal Society of Chemistry 2015Slide4
Scheme
1.3 Major categories of synthetic receptors.
Supplementary information for
Synthetic Receptors for Biomolecules: Design Principles and Applications
©
The Royal Society of Chemistry
2015Slide5
Scheme 1.4
Common scaffolds for organic molecular receptors.Supplementary information for Synthetic Receptors for Biomolecules: Design Principles and Applications© The Royal Society of Chemistry 2015Slide6
Scheme 1.5
Receptor scaffolds that incorporate Lewis acids.Supplementary information for Synthetic Receptors for Biomolecules: Design Principles and Applications© The Royal Society of Chemistry 2015Slide7
Scheme 1.6
X-ray structure of RNA aptamer complex with 5’-adenosine monophosphate (AMP) guest.Supplementary information for Synthetic Receptors for Biomolecules: Design Principles and Applications© The Royal Society of Chemistry 2015Slide8
Scheme 1.7
Molecular imprinted polymer created by non-covalent imprinting.Supplementary information for Synthetic Receptors for Biomolecules: Design Principles and Applications© The Royal Society of Chemistry 2015Slide9
Scheme 1.8
Guest encapsulation within the internal cavities of a dendrimer or hyperbranched polymer. Supplementary information for Synthetic Receptors for Biomolecules: Design Principles and Applications© The Royal Society of Chemistry 2015Slide10
Scheme 1.9
Nanoparticle with core shell architecture.Supplementary information for Synthetic Receptors for Biomolecules: Design Principles and Applications© The Royal Society of Chemistry 2015Slide11
Scheme 1.10
Major applications of receptors for biomolecules.Supplementary information for Synthetic Receptors for Biomolecules: Design Principles and Applications© The Royal Society of Chemistry 2015Slide12
Scheme 1.11
Affinity chromatography involves three major steps.Supplementary information for Synthetic Receptors for Biomolecules: Design Principles and Applications© The Royal Society of Chemistry 2015Slide13
Scheme 1.12
Synthetic receptors for separations.Slide14
Scheme 1.13
Liquid membrane transport.Slide15
Scheme 1.14
Supramolecular systems for imaging and sensing.Supplementary information for Synthetic Receptors for Biomolecules: Design Principles and Applications© The Royal Society of Chemistry 2015Slide16
Scheme 1.15
Synthetic receptors used for imaging and sensing.Supplementary information for Synthetic Receptors for Biomolecules: Design Principles and Applications© The Royal Society of Chemistry 2015Slide17
Scheme 1.16
Supramolecular catalysis of ligation or cleavage reactions.Slide18
Scheme 1.17
Synthetic pyridoxamine dendrimer as transaminase mimic.Slide19
Scheme 1.18
Synthetic receptors for catalysis.Slide20
Scheme 1.19
Pharmaceutically relevant protein biomolecule association systems.Supplementary information for Synthetic Receptors for Biomolecules: Design Principles and Applications© The Royal Society of Chemistry 2015Slide21
Scheme 1.20
Synthetic receptors with pharmaceutical activity.Supplementary information for Synthetic Receptors for Biomolecules: Design Principles and Applications© The Royal Society of Chemistry 2015Slide22
Scheme
1.21 Channel and carrier mechanisms for membrane transport.Supplementary information for Synthetic Receptors for Biomolecules: Design Principles and Applications© The Royal Society of Chemistry 2015