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C3 topic 2  revision: Quantitative analysis. C3 topic 2  revision: Quantitative analysis.

C3 topic 2 revision: Quantitative analysis. - PowerPoint Presentation

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C3 topic 2 revision: Quantitative analysis. - PPT Presentation

Water hardness Molarity Salts Titrations Water hardness Which ions make water hard How can we test for water hardness How can we remove temporary hardness How can we remove permanent hardness ID: 916482

mol concentration hardness mass concentration mol mass hardness titration water conc formula sodium reacted caso hydroxide naoh acid moles

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Presentation Transcript

Slide1

C3 topic 2 revision: Quantitative analysis.

Water hardness.

Molarity

.

Salts

Titrations.

Slide2

Water hardness

Which ions make water hard?

How can we test for water hardness?

How can we remove temporary hardness?

How can we remove permanent hardness?

What do we need to do once all the Na

+

is used up?

Why don’t we use this method to remove temporary hardness?

Slide3

Temporary hardness

This can be removed by boiling.

Caused by

limescale

(the product of magnesium and calcium ion decomposition)Removing the ions makes the water soft so it will lather.

Slide4

Removing hardness.

Slide5

Concentration

Slide6

Slide7

Converting

You may also need to know that ...

mole conc. (mol/dm

3

) x formula mass = mass concentration (g/dm

3

)

mass conc. (g/dm

3

) / formula mass = mole concentration (mol/dm

3

)

Slide8

Slide9

What is the mass concentration of sodium chloride (NaCl

) in g/dm

3

in a 1.50 mol/dm

3

solution? At. masses: Na = 23,

Cl

= 35.5, formula mass

NaCl

= 23 + 35.5 = 58.5

mass conc. = mol conc. x formula mass

Mass conc. In g/dm

3

= 1.50 x 58.5

= 87.8 g/dm

3

Questions

Slide10

A solution of calcium sulphate (CaSO

4

) contained 0.500g dissolved in 2.00 dm

3

of water.

Calculate the concentration in (a) g/dm

3

and (b) mol/dm

3

.

(a)

concentration

= 0.500/2.00

= 0.250

g/dm

3

(b)

At. masses: Ca = 40, S = 32, O = 64, f. mass CaSO

4

= 40 + 32 + (4 x 16) = 136

moles CaSO

4

= 0.5 / 136 = 0.00368 mol

concentration CaSO

4

= 0.00368 / 2 =

0.00184 mol/dm

3

Slide11

Making soluble salts (1)

Slide12

Method 2

Which indicator to use?

Methyl orange: strong acid / weak alkali

Phenolphthalein: weak acid / strong alkali

We usually use methyl orange in titrations as the colour change from orange to pink is easier to see.

Slide13

Concentration =

no. of moles

volume

Learn

this formula triangle!

m

c

v

number of moles

concentration (in

mol

dm

-3

)

volume (in dm

3

)

Slide14

Titration calculations cont.

In a titration, 20 cm

3

of 2.0 mol dm

-3

HCl reacted with 25 cm3 of

NaOH

. What was the concentration of the sodium hydroxide

?

In a titration, 20 cm

3

of 0.2 mol dm

-3

HCl

reacted with 50 cm

3

of

NaOH

. What was the concentration of the sodium hydroxide?

Slide15

Titration calculations cont.

In a titration, 20 cm

3

of 1.0 mol dm

-3

sulphuric acid, H2SO4

, reacted with 25 cm

3

of

NaOH. What was the concentration of the sodium hydroxide

?

In a titration, 20 cm

3

of 1.0 mol dm

-3

nitric acid, HNO

3

, reacted with 25 cm

3

of

NaOH

. What was the concentration of the sodium hydroxide?