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5. Electrochemistry: terms to know 5. Electrochemistry: terms to know

5. Electrochemistry: terms to know - PowerPoint Presentation

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5. Electrochemistry: terms to know - PPT Presentation

active electrode alkaline battery anode battery cathode cathodic protecdtion cell notation cell potential circuit concentration cell corrosion current dry cell electrical potential electrical work ID: 813559

battery cell standard electrode cell battery electrode standard reaction 0592 electrochemistry reduction potential 0257 equation ecell log

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Slide1

5. Electrochemistry: terms to know

active electrode

alkaline batteryanodebatterycathodecathodic protecdtioncell notationcell potentialcircuitconcentration cellcorrosioncurrentdry cellelectrical potentialelectrical workelectrolysisElectroplatingFaraday’s constantfuel cell

galvanic cell

galvanized iron

half-reaction method

inert electrode

lead acid battery

lithium ion battery

N

ernst equation

nickel-cadmium battery

overpotential

oxidation half-reaction

primary battery

reduction half-reaction

sacrificial anode

secondary battery

standard cell potential (

E

°cell

)

standard hydrogen electrode (SHE)

standard reduction potential (E°)

voltaic cell

Slide2

5. Electrochemistry: equations

E°cell

= E°cathode - E°anodeE°cell = RT ln(K)

nF

E°cell

=

0.0257 V

ln

(K) = 0.0592 V log(K) @ 25°C n n

Ecell = E°cell – RT ln(Q) Nernst equation nF

Ecell = E°cell - 0.0257 V ln(Q) = 0.0592 V log(Q) @ 25°C n n

ΔG = - nFEcell

ΔG° = - nFE°cell

wele = wmax = FEcell

Q = (I)(t) = (n)(F)