FEVE Emulsions in Architectural Coatings FEVE FluoropolymerResins 147FEVE148 is abbreviation for 147FluoroethyleneVinyl Ether148 resins for coatingsKnown for their high performance proper ID: 837281
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1 “FEVE Fluoropolymer Emulsions for P
“FEVE Fluoropolymer Emulsions for Performance Improvement in Architectural Coatings”Bob ParkerthWestern Coatings Symposium FEVE Emulsions in Architectural Coatings FEVE FluoropolymerResins “FEVE” is abbreviation for “FluoroethyleneVinyl Ether” resins for coatingsKnown for their high perf
2 ormance properties:Exceptional resistanc
ormance properties:Exceptional resistance to UV degradationSuperior Chemical ResistanceExcellent Thermal ResistanceKnown for their unique formulation properties:1) Solvent soluble2) Can be cured at ambient temperature with isocyanates 3) Can achieve high gloss formulations 1 Fluoroethylene Vinyl Ether (FEVE) Resins FL
3 UORINATED SEGMENTS: Weatherability, dur
UORINATED SEGMENTS: Weatherability, durability, chemical resistanceVINYL ETHER SEGMENTS: Gloss, solubility, crosslinking FEVE Emulsions in Architectural Coatings Commercial Types of “FEVE” Resins: Solvent soluble resins uses organic solvents for viscosity reduction; predominantly cured with isocyanates; av
4 ailable as resin solutions or as 100% so
ailable as resin solutions or as 100% solid resins2) Waterbased emulsions use vinyl ether macromonomerscontaining polyoxyethylene(EO) units to create stable emulsions 3 FEVE Emulsions in Architectural Coatings FEVE Waterborne EmulsionsSolids (Wt.)7 to 97 to 9Specific GravityMFTHydroxyl Value 4 FEVE Emulsions in Arc
5 hitectural Coatings White House Paint Fo
hitectural Coatings White House Paint Formulation PropertiesSolids (Volume)9.0 to 9.5TiO₂ ChoiceTiPurePVCThickenersboth cellulosic and associativeGloss RangeVOC1.24 #/gal. or 150 g/liter 5 FEVE Emulsions in Architectural Coatings Testing procedure # 1 : 1) Blending of FEVE emulsions and 4 different acrylic emulsi
6 ons to evaluate stability (3 weeks in 14
ons to evaluate stability (3 weeks in 140F. oven)2) Manufacture of 3 White House Paint formulations for each acrylic emulsion:Binder100% Acrylic EmulsionBinder50% Acrylic Emulsion + 50% FE4300 (FEVE Emulsion)Binder50% Acrylic Emulsion + 50% FE4500 (FEVE Emulsion)3) Stability testing of all formulations (6 weeks in
7 120F. oven)4) Preparation of test panels
120F. oven)4) Preparation of test panels ( primed Al panels coated with 4 wet mils of coating)5) QUV WeatherometerExposure (UVA 340 Bulbs used)Test Cycle = 8 hours UV light @ 60C. + 4 hours condensation @ 50C. 6 FEVE Emulsions in Architectural Coatings 7 010203040507080 050010001500200025003500450050006000 6500 Gloss
8 Decrease Acrylic #1 and 50/50 Blends
Decrease Acrylic #1 and 50/50 Blends 100% Acrylic 50/50 w/ FE 50/50 w/ FEGloss Decrease (%) Hours in QUV Weatherometer FEVE Emulsions in Architectural Coatings 8 010206070800500100015002500300035004000 5000 Gloss Decrease Acrylic #2 and 50/50 Blends 100% Acrylic 50/50 w/ FE 50/50 w/ FEGloss Decrease (%) Hours
9 in QUV Weatherometer FEVE Emulsions in A
in QUV Weatherometer FEVE Emulsions in Architectural Coatings 9 0102030406070 0 500 1000 1500 2000 2500 3000 3500 4000 4500 5000 5500 6000 6500 7000 7500 8000 Gloss Decrease Acrylic #3 and 50/50 Blends 100% Acrylic 50/50 w/ FE - 4300 50/50 w/ FE - 4500 Gloss Decrease (%) Hours in QUV Weatherometer FEVE Emulsions in A
10 rchitectural Coatings 10 010203040506070
rchitectural Coatings 10 010203040506070 0 500 1000 1500 2000 2500 3000 3500 4000 4500 5000 5500 6000 65007000 7500 8000 Gloss Decrease Acrylic #4 and 50/50 Blends 100% Acrylic 50/50 w/ FE - 4300 50/50 w/ FE - 4500 Gloss Decrease (%) Hours in QUV Weatherometer FEVE Emulsions in Architectural Coatings Red House Paint
11 Formulation PropertiesSolids (Volume)9.0
Formulation PropertiesSolids (Volume)9.0 to 9.5Pigment ChoiceOrganic Red + PhthaloBlue (trace)PVC6.5Thickenersboth cellulosic and associativeGloss RangeVOC1.24 #/gal. or 150 g/liter 11 FEVE Emulsions in Architectural Coatings Testing procedure # 2 : 1) Choose Acrylic Emulsion #3 as blending resin for Red HP formu
12 lation. 2) Manufacture of 6 Red House P
lation. 2) Manufacture of 6 Red House Paint formulations:Binder= 100% Acrylic EmulsionBinder= 50% Acrylic Emulsion + 50% FE4500 (FEVE Emulsion)Binder= 60% Acrylic Emulsion + 40% FE4500 (FEVE Emulsion)Binder= 70% Acrylic Emulsion + 30% FE4500 (FEVE Emulsion)Binder= 80% Acrylic Emulsion + 20% FE4500 (FEVE
13 Emulsion)f.Binder= 90% Acrylic Emulsion
Emulsion)f.Binder= 90% Acrylic Emulsion + 10% FE4500 (FEVE Emulsion)3) Preparation of test panels ( primed Al panels coated with 4 wet mils of coating)4) QUV Weatherometer Exposure (UVA 340 Bulbs used)Test Cycle = 8 hours UV light @ 60C. + 4 hours condensation @ 50C. 12 FEVE Emulsions in Architectural Coatings 13
14 010203040607080 0 500 1000 1500 2000 250
010203040607080 0 500 1000 1500 2000 2500 3000 3500 4000 4500 5000 5500 6000 6500 7000 7500 Gloss Decrease of Acrylic #3 and FE4500 Blends 100% Acrylic 10% FE - 4500 20% FE - 4500 30% FE - 4500 Gloss Decrease (%) Hours in QUV Weatherometer FEVE Emulsions in Architectural Coatings 14 01020405005001000150020002500 3000
15 3500 4000 4500 5000 5500 6000 6500 7000
3500 4000 4500 5000 5500 6000 6500 7000 7500 8000 Gloss Decrease of Acrylic and FE4500 Blends 100% Acrylic 40% FE - 4500 50% FE - 4500 Gloss Decrease (%) Hours in QUV Weatherometer FEVE Emulsions in Architectural Coatings White DTM I/M Paint Formulation PropertiesSolids (Volume)FEVE Emulsion9.0 to 9.5TiO₂ Choic
16 eTiPurePVCThickenersassociativetypeGloss
eTiPurePVCThickenersassociativetypeGloss RangeVOC1.24 #/gal. or 150 g/liter 15 FEVE Emulsions in Architectural Coatings Testing procedure # 3 : 1) Choose 3 different acrylic emulsions from 2 manufacturers as blending resins for White DTM I/M Formulation. These acrylic emulsions are targeted for architectural metal
17 finishes market. 2) Manufacture of 2 Wh
finishes market. 2) Manufacture of 2 White DTM I/M Paint formulations:Binder= 100% Acrylic EmulsionBinder= 50% Acrylic Emulsion + 50% FE4300 (FEVE Emulsion)3) Preparation of test panels ( primed Al panels coated with 4 wet mils of coating)4) QUV WeatherometerExposure (UVA 340 Bulbs used) Test Cycle = 8 hours UV
18 light @ 60C. + 4 hours condensation @ 50
light @ 60C. + 4 hours condensation @ 50C. 16 FEVE Emulsions in Architectural Coatings 17 010203040507080 0 500 1000 1500 2000 250030004500 5000 5500 6000 6500 7000 7500 8000 Gloss Decrease of Acrylic #5 and FE4300 Blend 100% Acrylic 50/50 BLEND w/ FE - 4300 Gloss Decrease (%) Hours in QUV Weatherometer FEVE Emulsio
19 ns in Architectural Coatings 18 01020708
ns in Architectural Coatings 18 010207080 0 5001000 1500 2000 2500 3000 3500 4000 4500 5000 5500 6000 6500 7000 75008000 Gloss Decrease of Acrylic #6 & FE - 4300 Blend 100% Acrylic 50/50 BLEND w/ FE - 4300 Gloss Decrease (%) Hours in QUV Weatherometer FEVE Emulsions in Architectural Coatings 19 010203040507080 0 50
20 0 1000 1500 2000 2500 3000 3500 4000 450
0 1000 1500 2000 2500 3000 3500 4000 4500 5000 5500 6000 6500 7000 7500 Gloss Decrease of Acrylic # 7 and FE4300 Blend 100% Acrylic 50/50 BLEND w/ FE - 4300 Gloss Decrease (%) Hours in QUV Weatherometer FEVE Emulsions in Architectural Coatings Black DTM I/M Paint Formulation PropertiesSolids (Volume)FEVE Emulsions4
21 300 and FE9.0 to 9.5Pigment ChoiceTintAy
300 and FE9.0 to 9.5Pigment ChoiceTintAydCW5331 MasstoneBlackPVC2.7ThickenersassociativetypeGloss RangeVOC1.24 #/gal. or 150 g/liter 20 FEVE Emulsions in Architectural Coatings Testing procedure # 4 : 1) Choose Acrylic Emulsion # 5 and Acrylic Emulsion # 6 as blending resins for Black DTM I/M Formulation. 2) Manuf
22 acture of 3 Black DTM I/M Paint formulat
acture of 3 Black DTM I/M Paint formulations for each Acrylic:Binder= 100% Acrylic EmulsionBinder= 50% Acrylic Emulsion + 50% FE4300 (FEVE Emulsion)Binder= 50% Acrylic Emulsion + 50% FE4500 (FEVE Emulsion)3) Preparation of test panels ( primed Al panels coated with 8 wet mils of coating)4) QUV Weatherometer Expo
23 sure (UVA 340 Bulbs used)Test Cycle = 8
sure (UVA 340 Bulbs used)Test Cycle = 8 hours UV light @ 60C. + 4 hours condensation @ 50C. 21 FEVE Emulsions in Architectural Coatings 22 010203040506070100 0 500 1000 1500 2000 2500 3000 3500 4000 4500 5000 5500 6000 Gloss Decrease of Acrylic #5 and FEVE Blends 100% Acrylic 50/50 w/ FE - 4300 50/50 w/ FE - 4500 Glo
24 ss Decrease (%) Hours in QUV Weatherome
ss Decrease (%) Hours in QUV Weatherometer FEVE Emulsions in Architectural Coatings 23 01020305060708090100 0 500 1000 1500 2000 2500 3000 3500 4000 4500 5000 5500 6000 6500 7000 7500 8000 Gloss Decrease of Acrylic #6 and FEVE Blends 100% Acrylic 50/50 w/ FE 50/50 w/ FEGloss Decrease (%) Hours in QUV Weatherometer F
25 EVE Emulsions in Architectural Coatings
EVE Emulsions in Architectural Coatings Testing procedure # 5 : 1) Choose Acrylic Emulsion # 5 and Acrylic Emulsion # 6 as blending resins for Black DTM I/M Formulation. 2) Manufacture of 3 Black DTM I/M Paint formulations for each Acrylic:Binder= 100% Acrylic EmulsionBinder= 80% Acrylic Emulsion + 20% FE4300
26 (FEVE Emulsion)Binder= 80% Acrylic Emuls
(FEVE Emulsion)Binder= 80% Acrylic Emulsion + 20% FE4500 (FEVE Emulsion)3) Preparation of test panels ( primed Al panels coated with 8 wet mils of coating)4) QUV Weatherometer Exposure (UVA 340 Bulbs used)Test Cycle = 8 hours UV light @ 60C. + 4 hours condensation @ 50C. 24 FEVE Emulsions in Architectural Coatings
27 25 0.010.020.030.040.050.060.070.080.090
25 0.010.020.030.040.050.060.070.080.090.0100.0 2500 3000 3500 4000 4500 5000 5500 6000 Gloss Decrease of Acrylic #5 and FE4300 Blends(DTM BLACK FORMULATION) 100% Acrylic 20% FE - 4300 Gloss Decrease (%) Hours in QUV Weatherometer FEVE Emulsions in Architectural Coatings 26 0.010.020.030.040.050.060.070.080.090.0100.
28 0 500 1000 1500 2000 2500 3000 3500 4000
0 500 1000 1500 2000 2500 3000 3500 4000 4500 5000 5500 6000 Gloss Decrease of Acrylic #5 and FE 4500 Blends (DTM BLACK FORMULATION) 100% Acrylic 20% FE - 4500 Gloss Decrease (%) Hours in QUV Weatherometer FEVE Emulsions in Architectural Coatings 27 0.010.020.030.040.050.060.070.080
29 .090.0100.0 1000 1500 2000 2500 3000 350
.090.0100.0 1000 1500 2000 2500 3000 3500 4000 4500 5000 5500 6000 Gloss Decrease of Acrylic #6 and FE4300 Blends(DTM BLACK FORMULATION) 100% Acrylic 20% FE - 4300 Gloss Decrease (%) Hours in QUV Weatherometer FEVE Emulsions in Architectural Coatings 28 0.010.020.030.040.050.060.070.080.090.0100.0 500 1000 1500 2000
30 2500 3000 3500 4000 4500 5000 5500 6000
2500 3000 3500 4000 4500 5000 5500 6000 Gloss Decrease of Acrylic #6 and FE 4500 Blends (DTM BLACK FORMULATION) 100% Acrylic 20% FE - 4500 Gloss Decrease (%) Hours in QUV Weatherometer FEVE Emulsions in Architectural Coatings Continuation of Project: 1) Testing of 50 g/liter House P
31 aint Formulations Testing of tinted Deep
aint Formulations Testing of tinted Deep Base DTM I/M Formulation with lower percentages of FEVE emulsionsas the binder 3) Testing of Clear HiGloss Concrete Sealer Formulationwith the FEVE emulsions replacing a percentageof the acrylic emulsion 29 FEVE Emulsions in Architectural Coatings Conclusion: Inclusion of FEVE
32 emulsions in architectural coating form
emulsions in architectural coating formulations can increase gloss retention and therefore prolong the aesthetic properties and the film integrity of these coatings, thereby increasing their life cycle and increasing the time between recoating exterior structures. 30 FEVE Emulsions in Architectural Coatings 31 Thank