Rule §106.261 and §106.262 - - PowerPoint Presentation

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Rule §106.261 and §106.262 - - PPT Presentation

Case Studies Amber Ni and Dan Sims Air Permits Division Advanced Air Permitting Seminar 2022 Topics New Hour UpstreamDownstream 106261 Annual Notifications 106261 and 106262 Brief Overview ID: 1040061

261 106 voc 262 106 261 262 voc butyl 003106 tpy 801 ether0 02110 valuel 02010 331 hractualtpyrulek hrmaxtpymaxbutane2

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1. Rule §106.261 and §106.262 -Case Studies Amber Ni and Dan SimsAir Permits DivisionAdvanced Air Permitting Seminar 2022

2. Topics New HourUpstream/Downstream106.261 Annual Notifications

3. §106.261 and §106.262 Brief Overview

4. § 106.261 / § 106.262…

5. §§ 106.261 / 106.262…

6. Emission Limits§106.2616 lb/hr 10 tpy1 lb/hr 4.38 tpy§106.262 Table 262E = L/KACGIH guide

7. Chemical SpeciationExample:Chemical plant with an NSR permitAdding 10 piping components to existing piping for maintenanceEmissions include Butane, Benzene, Emery, Di-n-butyl-ether, and Heptane

8. Speciation TablePollutantActuallb/hrActualtpyRuleK ValueL Valuelb/hrmaxtpymaxButane2.331.89?????Benzene0.02010.003?????Emery0.02110.003?????Di-n-butyl-ether0.801.36?????Heptane0.351.53?????

9. §§ 106.261 / 262 Speciation Order§106.261(a)(2)§106.262(a)(2)§106.261(a)(3)

10. §106.261(a)(2) Rule Language(a)(2) Total new or increased emissions, including fugitives shall not exceed 6.0 lb/hr and ten tons per year of the following materials:Acetylene,Argon, Butane,Crude oil…

11. Butane SpeciationPollutantActuallb/hrActualtpyRuleK ValueL Valuelb/hrmaxtpymaxButane2.331.89106.261(a)(2)----6.0010.00Benzene0.02010.003?????Emery0.02110.003?????Di-n-butyl-ether0.801.36?????Heptane0.351.53?????

12. Benzene SpeciationPollutantActuallb/hrActualtpyRuleK ValueL Valuelb/hrmaxtpymaxButane2.331.89106.261(a)(2)----6.0010.00Benzene0.02010.003?????Emery0.02110.003?????Di-n-butyl-ether0.801.36?????Heptane0.351.53?????

13. §§ 106.261 / 262 Case Study OrderBenzene isn’t listed.Let’s look at 106.262.

14. §106.262 Rule Language(a)(2) …nor in a quantity greater than E as determined using the equation E=L/K and the following table:Attached GraphicAttached GraphicBenzene is in the table at this link.The table at this link shows Benzene’s limit to be:3 mg/m3.

15. Benzen- SpeciationPollutantActuallb/hrActualtpyRuleK ValueL Valuelb/hrmaxtpymaxButane2.331.89106.261(a)(2)----6.0010.00Benzene0.02010.003106.262?3??Emery0.02110.003?????Di-n-butyl-ether0.801.36?????Heptane0.351.53?????

16. § 106.262 Rule Language(a)(2) …nor in a quantity greater than E as determined using the equation E=L/K and the following table:Attached GraphicAttached GraphicThe K value is in the table at this link.The table linked here shows the K value at 300 ft to be 139.

17. Benzene Speciation continuedPollutantActuallb/hrActualtpyRuleK ValueL Valuelb/hrmaxtpymaxButane2.331.89106.261(a)(2)----6.0010.00Benzene0.02010.003106.26213930.02160.0945Emery0.02110.003?????Di-n-butyl-ether0.801.36?????Heptane0.351.53?????E=L/KE=3/139

18. Emery SpeciationPollutantActuallb/hrActualtpyRuleK ValueL Valuelb/hrmaxtpymaxButane2.331.89106.261(a)(2)----6.0010.00Benzene0.02010.003106.26213930.02160.0945Emery0.02110.003?????Di-n-butyl-ether0.801.36?????Heptane0.351.53?????

19. §§ 106.261 / 262 Case Study Order (A)Emery isn’t listed.Emery isn’t listed.Next try the 1997 TLVs & BEIs.

20. ACGIH TLVs and BEIs Guide (1997 Version)…Divinyl benzene [1321-74-0] (1980)………….. 10 53Emery [1302-74-5] (1986)………….. --- 10(e)Endosulfan[115-29-7] --- …

21. Emery-SpeciationPollutantActuallb/hrActualtpyRuleK ValueL Valuelb/hrmaxtpymaxButane2.331.89106.261(a)(2)----6.0010.00Benzene0.02010.003106.26213930.02160.0945Emery0.02110.003106.262139100.07190.315Di-n-butyl-ether0.801.36?????Heptane0.351.53?????E=L/KE=10/139

22. Di-n-butyl Ether SpeciationPollutantActuallb/hrActualtpyRuleK ValueL Valuelb/hrmaxtpymaxButane2.331.89106.261(a)(2)----6.0010.00Benzene0.02010.003106.26213930.02160.0945Emery0.02110.003106.262139100.07190.315Di-n-butyl-ether0.801.36?????Heptane0.351.53?????

23. §§ 106.261 / 262 Case Study Order (B)§106.261(a)(2)§106.262(a)(2)§106.261(a)(3)Di-n-butyl-ether isn’t listed.Isn’t listed in Table 262.Not in the 1997 TLVs & BEIs.Let’s check here.

24. § 106.261(a)(3) Rule Language(3) …emissions, including fugitives, shall not exceed 1.0 lb/hr of any chemical…

25. Di-n-butyl-ether speciationPollutantActuallb/hrActualtpyRuleK ValueL Valuelb/hrmaxtpymaxButane2.331.89106.261(a)(2)----6.0010.00Benzene0.02010.003106.26213930.02160.0945Emery0.02110.003106.262139100.07190.315Di-n-butyl-ether0.801.36106.261(a)(3)----1.004.38Heptane0.351.53?????

26. Heptane speciationPollutantActuallb/hrActualtpyRuleK ValueL Valuelb/hrmaxtpymaxButane2.331.89106.261(a)(2)----6.0010.00Benzene0.02010.003106.26213930.02160.0945Emery0.02110.003106.262139100.07190.315Di-n-butyl-ether0.801.36106.261(a)(3)----1.004.38Heptane0.351.53?????

27. §§ 106.261 / 262 Case Study Order (C)§106.261(a)(2)§106.262(a)(2)§106.261(a)(3)Heptane isn’t listed.Heptane is listed.L Value = 350

28. §§ 106.261 / 262 Case Study Order (D)§106.261(a)(2)§106.262(a)(2)§106.261(a)(3)But wait!

29. § 106.261(a)(3) Rule Language (A)(3) …emissions, including fugitives, shall not exceed 1.0 lb/hr of any chemical having a limit value (L) greater than 200 milligrams per cubic meter…

30. Heptane-SpeciationPollutantActuallb/hrActualtpyRuleK ValueL Valuelb/hrmaxtpymaxButane2.331.89106.261(a)(2)----6.0010.00Benzene0.02010.003106.26213930.02160.0945Emery0.02110.003106.262139100.07190.315Di-n-butyl-ether0.801.36106.261(a)(3)----1.004.38Heptane0.351.53106.261(a)(3)----1.004.38

31. Emissions Summary Table

32. PBR Only SitePropane:3 lb/hr 4 tpy Propane:2 lb/hr 2 tpy

33. PBR Only SiteAPropane:3 lb/hr 4 tpy Propane:2 lb/hr 2 tpy Propane:2 lb/hr 4 tpy

34. § 106.261(a)(2) Rule Language(2) Total new or increased emissions, including fugitives shall not exceed 6.0 lb/hr and ten tons per year of the following materials:nonane,Oxides of nitrogen, Propane,Propyl alcohol…

35. Old Actual to New Potential Emissions

36. Old Actual to New Potential Emissions (A)

37. Old Actual to New Potential Emissions (B)All actual emissions increases must be evaluated to meet protectiveness

38. Physical or Operational Changes§106.261(a) Except as specified under subsection (b) of this section, facilities, or physical or operational changes to a facility, are permitted by rule provided that all of the following conditions of this section are satisfied.

39. New Hour Footnote

40. New HourHour 1 Hour 2Hour 3Hour 4Hour 51 bbl1 bbl1 bbl1 bbl1 bbl2 lb/hr VOC 2 lb/hr VOC 2 lb/hr VOC 2 lb/hr VOC 2 lb/hr VOC

41. New Hour (A)Hour 1 Hour 2Hour 3Hour 4Hour 52 bbl2 bbl2 bbl2 bbl2 bbl4 lb/hr VOC 4 lb/hr VOC 4 lb/hr VOC 4 lb/hr VOC 4 lb/hr VOC

42. New Hour (B)Hour 1 Hour 2Hour 3Hour 4Hour 5Hour 6 NEW HOUR1 bbl1 bbl1 bbl1 bbl1 bbl1 bbl2 lb/hr VOC 2 lb/hr VOC 2 lb/hr VOC 2 lb/hr VOC 2 lb/hr VOC 2 lb/hr

43. “New Hour” ScenarioStorage tank loading is increasing annual throughput, additional 1,000 hours of operation, currently permitted at 5,000 hours30 TAC 10630 TAC 116Hours 1-5000: 30 TAC 116. Protectiveness is demonstrated through 116.111, including compliance with BACT, MACT, NSPS, NESHAP, distance, PSD, NA, performance demonstration, modeling, etc. Special Conditions and monitoring requirements are implemented to represent compliance. This all goes through public notice. Hours 5,001-6,000: 30 TAC 106Protectiveness is demonstrated through 106.261/262, which authorizes a physical or operational change to a permitted facility within the emission limits of the rule. No changes to underlying BACT or environmental impacts

44. Upstream/Downstream Scenario

45. Upstream/Downstream EPN TNK1EPN TNK2EPN LOAD

46. Upstream/Downstream (A)EPN TNK1EPN TNK2EPN TNK3EPN LOAD

47. Upstream/Downstream (B)EPN TNK1EPN TNK2EPN TNK3EPN LOADPBR §106.478PBR §106.262

48. Upstream/Downstream (C)EPN TNK1EPN TNK2EPN TNK3EPN LOADPBR §106.478PBR §106.262

49. Upstream/Downstream (D)EPN TNK3EPN LOADEPNOld Actual EmissionsNew Potential EmissionsDelta (new potential – old actual) Permitted AllowableEPN LOAD6 tpy9 tpy 3 tpy10 tpy 9 tpy < 10 tpy

50. Upstream/Downstream (E)EPN TNK3EPN LOADEPNOld Actual EmissionsNew Potential EmissionsDelta (new potential – old actual) Permitted AllowableEPN LOAD6 tpy11 tpy 5 tpy10 tpy 11 tpy >10 tpy

51. Upstream/Downstream (F)EPN TNK3EPN LOAD

52. Upstream/Downstream (G)EPN TNK3EPN LOADItem No.FINEPNPermit No.ActualA BaselineB Proposed PTEC Projected ActualDifference (B-A) or (C-A)Project Increases1. LOAD2. FUG3. TNK3TotalProjectEmissionsIncrease

53. 106.261 Annual NotificationsCan §106.262 emissions be included in §106.261 annual notifications?

54. This and That

55. This and That continued...

56. Thank you APD Mainline512-239-1250airperm@tceq.texas.govAmber Ni512-239-0198amber.ni@tceq.texas.govDan Sims512-239-2118dan.sims@tceq.texas.gov