PPT-Amines Dr. Shatha I Alaqeel

108 Chem Learning Objectives Chapter ten discusses the amines and by the end of this chapter the students will Know the structure and classification of amines Know the naming rules for . 1. Chapter 20. Amines. Ch. . 20. . - . 2. About The Authors. . These PowerPoint Lecture Slides were created and prepared by Professor William Tam and his wife, Dr. Phillis Chang. . . Professor William Tam received his B.Sc. at the University of Hong Kong in 1990 and his Ph.D. at the University of Toronto (Canada) in 1995. He was an NSERC postdoctoral fellow at the Imperial College (UK) and at Harvard University (USA). He joined the Department of Chemistry at the University of Guelph (Ontario, Canada) in 1998 and is currently a Full Professor and Associate Chair in the department. Professor Tam has received several awards in research and teaching, and according to . July 2012. Amines . AIM – to investigate the properties of amines. Amines are . near relatives of ammonia, . NH. 3. . where hydrogen atoms . in the ammonia . have . been replaced . by a hydrocarbon group. . Amine nomenclature. diisopropylamine. pyrrole. nicotine. histamine. pyrrolidine. Formation of amines. triethylamine. Mechanism for LAH reduction of amides. 1-methylpiperidine. One equivalent . SN2 is faster the more R groups on N. Ch19 Amines( Page 1 Amines Amines are derivatives of ammonia with one or more alkyl groups bonded to the nitrogen . Amines can be classified as primary , secondary or tertiary , meaning one , t Amines are derivatives of ammonia, NH. 3. . Amines can be classified as primary, secondary or tertiary. . Primary amines . have one carbon attached to the nitrogen atom of the amine group. . Secondary amines . Types of Reactions. Types of Reactions. There are . 9. . main types of reactions we will examine:. Combustion. Substitution. Addition. Halogenation. , . Hydrogenation, . Hydrohalogenation. , Hydration. Chapter 16. Amines. Amines are nitrogen-containing compounds. Structure and Classification. Amines are classified as 1°, 2°, or 3° depending on the number of carbon groups bonded to nitrogen.. Aliphatic amine:. A heterocyclic amine is a cyclic organic compound that consists of a ring of five or six atoms, of which one or two are nitrogen atoms.. The aroma of pepper is due to . piperidine. , a heterocyclic amine. 3. . Amines can be classified as primary, secondary or tertiary. . Primary amines . have one carbon attached to the nitrogen atom of the amine group. . Secondary amines . have two carbons attached to the nitrogen atom of the amine functional group. . Indigofera tinctoria. .. Learning . Goal . Write the common names for amines; draw the condensed structural formulas when given their names. Classify amines as primary . (1. °. ), . secondary . (. 2. Amines are classified as primary, secondary, or tertiary based upon the number of carbon-containing groups that are attached to the nitrogen atom. Those amine compounds that have only one group attached to the nitrogen atom are primary, while those with two or three groups attached to the nitrogen atom are secondary and tertiary, respectively. 1439 . Outline. Structure and Classification. Nomenclature. Physical Properties. Preparation. Reaction. 2. 340 . Chem. 1. st. 1439 . Structure and Classification. Amines are organic derivatives of ammonia in which one or more hydrogens are replaced with alkyl or aryl groups.. 1. objectives:. Fundamental concepts on basic character of amines.. Applications of these concepts in comparing the relative basic strengths of NH. 3. , various alkyl amines, C. 6. H. 5. NH. 2. and other substituted aromatic amines.. Amines are more basic than ammonia due to the presence of unshared electron pair on nitrogen atom. THE ORDER OF BASICITY. T. ertiary amines- Secondary- Primary amine. H .