PPT-C H A P T E R   15 Thermodynamics

Topics to be covered Laws of thermodynamics Zeroth law First law Second law and Third law Thermal Processes Isobaric Isochoric adiabatic and Isothermal Heat engines Refrigerators Airconditioners and Heat pumps . LIMITATION OF FIRST LAW OF . THERMODYNAMICS. It does not give information concerning feasibility of a thermodynamic . proces. .. why. NOT EXPLAINED BY FIRST LAW. It tells that work obtained is equal to heat absorbed but in actual heat absorbed can not be completely converted into work. 1. st. law of thermodynamics. Energy may be converted to different forms, but it is neither created nor destroyed during transformations. Energy from chemical bonds is converted to kinetic energy and heat (body and friction from tires). No engine, working in a continuous cycle, can take heat from a reservoir at a single temperature and convert that heat completely to work.. Therefore, no engine can have a greater efficiency than a Carnot engine operating between the same two temperatures.. AP Environmental Science. What is Energy?. Energy is a . measurable quantity. that can be stored in a physical system. Energy can be . transferred. from one system to another and so . cause changes. L. David . Kubiz. ňák. (Perimeter Institute). . Lambda and Quasi-Lambda workshop. University of Massachusetts, Amherst, MA, USA. April 10 – April 12, 2014. Plan of the talk. Black holes as thermodynamic objects . ~Energy. Intro. Most natural events involve a decrease in total energy and an increase in disorder.. The energy that was “lost” was converted to heat. . An increase in energy/motion decreases the overall order (organization) of the system.. Thermodynamics. Rub your hands together for 15 seconds.. Are your hands warm?. Thermal energy. Thermodynamics. The study of the effects of work, heat flow, and energy on a system. Movement of thermal energy. © 2014 Pearson Education, Inc.. Contents of Chapter 15. The First Law of Thermodynamics. Thermodynamic . Processes and the First Law. Human . Metabolism and the First Law. The . Second Law of . Thermodynamics—Introduction. Entropy: Criteria for Spontaneity. Second Law of Thermodynamics. Third Law of Thermodynamics. Free Energy . Coupled Reactions. Thermodynamics. The chemistry . that . deals with the flow of energy during a chemical or physical process;. Champion Deivanayagam. Center for Biophysical Sciences and Engineering. University of Alabama at Birmingham.. Outline:. Laws of thermodynamics. Enthalpy. Entropy. Gibbs free energy. some examples. Introduction. Zeroth Law of Thermodynamics. If objects A and B are separately in thermal equilibrium with a third object C, then A and B are in thermal equilibrium with each other. . Temperature . T. Thermometry. Concept of temperature. Boyle’s Law. Charles’ Law. Thermometers. Thermocouple. Calorimetry. Platinum resistance scale. Absolute zero. Lower fixed point. Temperature gradient. Thermodynamic . Temperature is the measurement of the average kinetic energy of material. . Atoms move around and collide with the thermometer and exchange its energy causing the thermometer to go up.. Three units of measuring temperature. The net entropy will increase or stay the same It will never decreaseThe net entropy will increase or stay the same It will never decreaseSYSqSx0000 0SqT 0 only for a reversible processx0000 0 f