Structure - PDF document

1 M i YO Structure Pastes Safety Data
M i YO Structure Pastes Safety Data Sheet Revision Date : 5 /17/ 17 Rev 0 MI SPZ .SDS * MI SP Z * 5 /17/17 EN ( English US ) 1 / 1 2 SECTION 1: IDENTIFICATION Product Identifier Product Form: Mixture Product Name: MiYO Structure Pastes Synonyms: Structure Pastes Intended Use of the Product Dental ceramics Name, Address, and Telephone of t he Responsible Party Company Jensen Industries Inc. 50 Stillman Road North Haven, CT 06473 T 1 - 800 - 243 - 2000 Emergency Telephone Number Emergency Number (USA & Canada Only): CHEMTREC 1 - 800 - 424 - 9300 CCN803910 Emergency Number (All other Countries): 203 - 239 - 2090 SECTION 2: HAZARDS IDENTIFICATION Classification of the Substance or Mixture Classification (GHS - US) Carc. 1 A H 350 Repr. 1B H360 Aquatic Acute 2 H401 Aquatic Chronic 2 H411 Full text of H - phrases: see section 16 Label Elements GHS - US Labeling Hazard Pictograms (GHS - US) : GHS05 GHS08 GHS09 Signal Word (GHS - US) : Danger Hazard Statements (GHS - US) : H3 50 - Carcinogenicity Category 1A . H360 - May damage fertility or the unborn child (oral). H401 - Toxic to aquatic life. H411 - Toxic to aquatic life with long lasting effects. Precautionary Statements (GHS - US) : P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P273 - Avoid release to the environment. P280 - Wear protective gloves, protective clothing, and eye protection. P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 - If exposed or concerned: Get medical advice/attention. P310 - Immediately call a poison center or doctor. P391 - Collect spillage. P405 - Store locked up. P501 - Dispose of contents/container in accordance with local, regional, national, territorial, provincial, and international regulations. MiYO Structure Pastes Safety Data Sheet 5 /17/17 EN ( English US ) 2 / 1 2 Other Hazards Exposure may aggravate those with pre - existing eye, skin, or respiratory conditions. The dried or powdered form of this substance may form combustible dust concentrations in air. - May cause irritation to the eyes, skin, and up per respiratory tract. May cause headache, nausea, vomiting; kidney injury. - May cause irritation to lower and upper respiratory tracts. May cau

2 se irritation to eyes, skin, nose, throa
se irritation to eyes, skin, nose, throat; conjunctivitis; cough, copious sputum; dyspnea (breathing difficulty ), chest pain, pulmonary edema, pneumonitis; pulmonary fibrosis, cor pulmonale; fever; cyanosis; tachypnea; skin burns. - Inhalation of silicon dust/fumes may cause irritation to the upper respiratory system; symptoms include: cough/irritation. Co ntact wit h skin and/or eyes may cause dermatitis/irritation. - Repeated inhalation of silica crystalline dust/particulates can cause serious chronic lung damage, known as silicosis. Silico sis involves inflammation and scarring of the lung tissue; pulmonary fibrosis . Lung cancer is contributed to chronic exposure to silica (crystalline) dust/fumes. - Inhalation of certain elements and their oxides contained in this product may be hazardous. Dust/fumes can cause irritation t o the eyes, nasal passage, GI tract, skin, an d respiratory system. Unknown Acute Toxicity (GHS - US) Not available SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Mixture Name Product Identifier % (w/w) Classification (GHS - US) Trade Secret - Component A Proprietary Proprietary Carc. 1A, H350 STOT RE 1, H372 Trade Secret - Component B Proprietary Proprietary Carc. 1A, H350 STOT SE 3, H335 STOT RE 1, H372 Trade Secret - Component C Proprietary Proprietary Comb. Dust Trade Secret - Component D Proprietary Proprietary Repr. 1B, H360 Trade Secret - Component E Proprietary Proprietary Skin Irrit. 2, H315 Eye Irrit. 2B, H320 STOT SE 3, H335 Trade Secret - Component F Proprietary Proprietary Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Trade Secret - Component G Proprietary Proprietary No t classified Full text of H - phrases: see section 16 More than one of the ranges of concentration prescribed by the Controlled Products Regulations has been used where necessary, due to varying composition. SECTION 4: FIRST AID MEASURES Description of F irst Aid Measures General : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice. Inhalation : When symptoms occur: go into open air and ventilate suspected area. Get immediate medical advice/attention. Skin Contact : Remove contaminated clothing. Drench affected area with water for at least 15 minutes. Seek medical attention immediately if irritation develops or persists. Eye Contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing for at least 60 minutes. Immediately call a POISON CENTER or doctor/physician. Ingestion : Rinse mouth. Do NOT induce vomiting. Seek medical attention immediately. Most Important Symptoms and Effects Both Acute and Delaye d General : Causes serious eye damage. May damage fertility or the

3 unborn child (oral). Inhalation :
unborn child (oral). Inhalation : Inhalation of dusts and fumes can cause metal fume fever. Symptoms can include a metallic or sweet taste in the mouth, sweating, shivering, headache, thro at irritation, fever, chills, thirstiness, muscle aches, nausea, vomiting, weakness, fatigue, and shortness of breath. Skin Contact : May cause skin irritation. Eye Contact : Causes serious eye damage. Symptoms may include: Redness, pain, swelling, itc hing, burning, tearing, and blurred vision. Causes permanent damage to the cornea, iris, or conjunctiva. MiYO Structure Pastes Safety Data Sheet 5 /17/17 EN ( English US ) 3 / 1 2 Ingestion : Ingestion is likely to be harmful or have adverse effects. Chronic Symptoms: May damage fertility or the unborn child (oral) . This pro duct contains Cryst a lline Silica dust that is mixed with a liquid to form a paste mixture, and therefore the dust is not likely to be dispersed into the air. If dust is released into t he air, repeated exposure to respirable (airborne) crystalline silica du st may cause lung damage in the form of silicosis, lung cancer, or respiratory irritation. Indication of Any Immediate Medical Attention and Special Treatment Needed If you feel unwell, seek medical advice (show the label where possible). SECTION 5: FIRE - FIGHTING MEASURES Extinguishing Media Special Hazards Arising From the Substance or Mixture Advice for Firefighters Precautionary Measures Fire: Exercise caution when fighting any chemical fire. Under fire conditions, hazardous fumes will be present. Firefighting Instructions: Use water spra y or fog for cooling exposed containers. Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. Hazardous Combustion Products : Nitrogen oxides. Ammonia. Burning material releases hea vy metal oxide fumes. Reference to Other Sections Refer to section 9 for flammability properties. SECTION 6: ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Avoid all contact with ski n, eyes, or clothing. Avoid breathing (dust, fume, mist ). If the product is allowed to desiccate or dry out: Keep away from heat, hot surfaces, sparks, open flames, and other ignition sources. No smoking. Use spe cial care to avoid static electric charges. For Non - Emergency Personnel Protective Equipment: Use appropriate personal protection equipment (PPE). Emergency Procedures: Evacuate unnecessary personnel. For Emergency Personnel Protective Equipment: Equip cleanup crew with proper protection. Emer gency Procedures: Upon arrival at the scene, a first responder is expected to recognize the presence of dangerous goods, protect oneself and the public, secure the area, and call for the

4 assistance of trained personnel as soon
assistance of trained personnel as soon as conditions permi t. Enviro nmental Precautions Prevent entry to sewers and public waters. Dangerous due to potential toxicity for the environment. Methods and Material for Containment and Cleaning Up For Containment: Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams. Methods for Cleaning Up: Clean up spills immediately and dispose of waste safely. Spills should be contained with mechanical barriers. Transfer spilled material to a suitable container for disposal. Do not take up in com bustible material such as: saw dust or cellulosic material. Contact competent authorities after a spill. Reference to Other Sections See Section 13, Disposal Considerations. See Section 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE Precautions for Safe Handling Additional Hazards When Processed: Contains substances that are combustible dusts. If dried and allowed to accumulate, may form combustible dust concentrations in air that could ignite and cause an explosion. Tak e appropriate precautions. Precautions for Safe Handling: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Suitable Extinguishing Media: Dry chemical powder, alcohol - resistant foam, carbon dioxide (CO 2 ). Unsuitable Extinguishing Media: Do not use a heavy water stream. Use of heavy stream of water may spread fire. Fire Hazard: Product is not flammable. The dried or powdered form of this substance may form combustible dust concentrations in air. Explosion Hazard: Product is not explosive. Reactivity: Hazardou s reactions will not occur under normal conditions. MiYO Structure Pastes Safety Data Sheet 5 /17/17 EN ( English US ) 4 / 1 2 Hygiene Measures: Handle in accordance with good industrial hygiene and safety pr ocedures. Wash hands and other exposed areas with mild soap and water before eating, drinking, or smoking and again when leaving work. Conditions for Safe Storage, Including Any Incompatibilities Storage Conditions: Store in a dry, cool and well - ventilated place . Keep container closed when not in use. Incompatible Materials: Strong acids. Strong bases. Strong oxidizers. Specific End Use(s) Dental ceramics SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Control Parameters For substances list ed in section 3 that are not listed here, there are no established Exposure limits from the manufacturer, supplier, importer, or the appropriate advisory agency including: ACGIH (TLV), NIOSH (REL), OSHA (PEL), Canadian provincial governments , or the Mexica n government . Component E USA NIOSH ACGIH REL (TWA) (mg/m³) 10 mg/m³ 5 mg/m³ (respirable fraction) USA OSHA OSHA PEL (TWA) (mg/m³) 15 m

5 g/m³ (total dust) 5 mg/m³ (respirabl
g/m³ (total dust) 5 mg/m³ (respirable fraction) Component A Mexico OEL TWA (mg/m³) 0.05 mg/m³ (respirable fraction) USA ACGIH ACGIH TWA (mg/m³) 0.025 mg/m³ (respirable fraction) USA ACGIH ACGIH chemical category Suspected Human Carcinogen USA NIOSH NIOSH REL (TWA) (mg/m³) 0.05 mg/m³ (respirable dust) USA IDLH US IDLH (mg/m³) 25 mg/m³ (respirable dust) Alberta OEL TWA (mg/m³) 0.025 mg/m³ (respirable particulate) British Columbia OEL TWA (mg/m³) 0.025 mg/m³ (respirable) Manitoba OEL TWA (mg/m³) 0.025 mg/m³ (respirable fraction) New Brunswick OEL TWA (mg/m³) 0.05 mg/m³ (respirable fraction) Newfoundland & Labrador OEL TWA (mg/m³) 0.025 mg/m³ (respirable fraction) Nova Scotia OEL TWA (mg/m³) 0.025 mg/m³ (respirable fraction) Nunavut OEL TWA (mg/m³) 0.05 mg/m³ (respirable mass) 0.15 mg/m³ (total mass) Northwest Territories OEL TWA (mg/m³) 0.05 mg/m³ (respirable ma ss) 0.15 mg/m³ (total mass) Ontario OEL TWA (mg/m³) 0.05 mg/m³ (designated substances regulation - respirable) Prince Edward Island OEL TWA (mg/m³) 0.025 mg/m³ (respirable fraction) Québec VEMP (mg/m³) 0.05 mg/m³ (respirable dust) Saskatchewan OEL TWA (m g/m³) 0.05 mg/m³ (respirable fraction) Yukon OEL TWA (mg/m³) 150 particle/mL Component C Mexico OEL TWA (mg/m³) 10 mg/m³ (inhalable fraction) Mexico OEL STEL (mg/m³) 20 mg/m³ USA OSHA OSHA PEL (TWA) (mg/m³) 15 mg/m³ (total dust) 5 mg/m³ (respirable f raction) USA NIOSH NIOSH REL (TWA) (mg/m³) 10 mg/m³ (total dust) 5 mg/m³ (respirable dust) British Columbia OEL TWA (mg/m³) 10 mg/m³ (total dust) 3 mg/m³ (respirable fraction) New Brunswick OEL TWA (mg/m³) 10 mg/m³ Nunavut OEL TWA (mg/m³) 5 mg/m³ (resp irable mass) 10 mg/m³ (total mass) Northwest Territories OEL TWA (mg/m³) 5 mg/m³ (respirable mass) 10 mg/m³ (total mass) MiYO Structure Pastes Safety Data Sheet 5 /17/17 EN ( English US ) 5 / 1 2 Ontario OEL TWA (mg/m³) 10 mg/m³ (total dust) Québec VEMP (mg/m³) 10 mg/m³ (containing no Asbestos and % Crystalline silica - total dust) Saskatchewan OEL STEL (mg/m³) 20 mg/m³ Saskatchewan OEL TWA (mg/m³) 10 mg/m³ Yukon OEL STEL (mg/m³) 20 mg/m³ Yukon OEL TWA (mg/m³) 30 mppcf 10 mg/m³ Component B Mexico OEL TWA (mg/m³) 0.1 mg/m³ (respirable fraction) USA ACGIH ACGIH TWA (mg/m³ ) 0.025 mg/m³ (respirable fraction) USA ACGIH ACGIH chemical category A2 - Suspected Human Carcinogen USA OSHA OSHA PEL (STEL) (mg/m³) 250 mppcf/%SiO 2 +5, 10mg/m 3 /%SiO 2 +2 USA NIOSH NIOSH REL (TWA) (mg/m³) 0.05 mg/m³ (respirable dust) USA IDLH US IDLH (m g/m³) 50 mg/m³ (respirable dust) Alberta OEL TWA (mg/m³) 0.025 mg/m³ (respirable particulate) British Columbia OEL TWA (mg/m³) 0.025 mg/m³ (respirable) Manitoba OEL TWA (m

6 g/m³) 0.025 mg/m³ (respirable fraction
g/m³) 0.025 mg/m³ (respirable fraction) New Brunswick OEL TWA (mg/m³) 0.1 mg/m³ ( respirable fraction) Newfoundland & Labrador OEL TWA (mg/m³) 0.025 mg/m³ (respirable fraction) Nova Scotia OEL TWA (mg/m³) 0.025 mg/m³ (respirable fraction) Nunavut OEL TWA (mg/m³) 0.1 mg/m³ (respirable mass) 0.3 mg/m³ (total mass) Northwest Territorie s OEL TWA (mg/m³) 0.1 mg/m³ (respirable mass) 0.3 mg/m³ (total mass) Ontario OEL TWA (mg/m³) 0.10 mg/m³ (designated substances regulation - respirable) Prince Edward Island OEL TWA (mg/m³) 0.025 mg/m³ (respirable fraction) Québec VEMP (mg/m³) 0.1 mg/m³ (r espirable dust) Saskatchewan OEL TWA (mg/m³) 0.05 mg/m³ (respirable fraction) Yukon OEL TWA (mg/m³) 300 particle/mL Component D Mexico OEL TWA (mg/m³) 10 mg/m³ Mexico OEL STEL (mg/m³) 20 mg/m³ USA ACGIH ACGIH TWA (mg/m³) 10 mg/m³ USA OSHA OSHA PEL (TWA) (mg/m³) 15 mg/m³ (total dust) USA NIOSH NIOSH REL (TWA) (mg/m³) 10 mg/m³ USA IDLH US IDLH (mg/m³) 2000 mg/m³ Alberta OEL TWA (mg/m³) 10 mg/m³ British Columbia OEL TWA (mg/m³) 10 mg/m³ Manitoba OEL TWA (mg/m³) 10 mg/m³ New Brunswick OEL TWA (mg/ m³) 10 mg/m³ Newfoundland & Labrador OEL TWA (mg/m³) 10 mg/m³ Nova Scotia OEL TWA (mg/m³) 10 mg/m³ Nunavut OEL STEL (mg/m³) 20 mg/m³ Nunavut OEL TWA (mg/m³) 10 mg/m³ Northwest Territories OEL STEL (mg/m³) 20 mg/m³ Northwest Territories OEL TWA (mg/m³ ) 10 mg/m³ Ontario OEL TWA (mg/m³) 10 mg/m³ Prince Edward Island OEL TWA (mg/m³) 10 mg/m³ Québec VEMP (mg/m³) 10 mg/m³ Saskatchewan OEL STEL (mg/m³) 20 mg/m³ Saskatchewan OEL TWA (mg/m³) 10 mg/m³ MiYO Structure Pastes Safety Data Sheet 5 /17/17 EN ( English US ) 6 / 1 2 Yukon OEL TWA (mg/m³) 10 mg/m³ Component F Mexico O EL TWA (mg/m³) 5 mg/m³ (fume) 10 mg/m³ (dust) Mexico OEL STEL (mg/m³) 10 mg/m³ (fume) USA ACGIH ACGIH TWA (mg/m³) 2 mg/m³ (respirable fraction) USA ACGIH ACGIH STEL (mg/m³) 10 mg/m³ (respirable fraction) USA OSHA OSHA PEL (TWA) (mg/m³) 5 mg/m³ (fume) 1 5 mg/m³ ( total dust) 5 mg/m³ (respirable fraction) USA NIOSH NIOSH REL (TWA) (mg/m³) 5 mg/m³ (dust and fume) USA NIOSH NIOSH REL (STEL) (mg/m³) 10 mg/m³ (fume) USA NIOSH NIOSH REL (ceiling) (mg/m³) 15 mg/m³ (dust) USA IDLH US IDLH (mg/m³) 500 mg/m³ Al berta OEL STEL (mg/m³) 10 mg/m³ (respirable) Alberta OEL TWA (mg/m³) 2 mg/m³ (respirable) British Columbia OEL STEL (mg/m³) 10 mg/m³ (respirable) British Columbia OEL TWA (mg/m³) 2 mg/m³ (respirable) Manitoba OEL STEL (mg/m³) 10 mg/m³ (respirable fract ion) Manitoba OEL TWA (mg/m³) 2 mg/m³ (respirable fraction) New Brunswick OEL STEL (mg/m³) 10 mg/m³ (fume) New Brunswick OEL TWA (mg/m³) 10 mg/m³ (particulate matter containing no Asbestos and

7 1% Crystalline silica, dust) 5 mg/m
1% Crystalline silica, dust) 5 mg/m³ (fume) Newfoundland & Labrador OEL STEL (mg/m³) 10 mg/m³ (respirable fraction) Newfoundland & Labrador OEL TWA (mg/m³) 2 mg/m³ (respirable fraction) Nova Scotia OEL STEL (mg/m³) 10 mg/m³ (respirable fraction) Nova Scotia OEL TWA (mg/m³) 2 mg/m³ (respirable fraction) Nunavu t OEL STEL (mg/m³) 10 mg/m³ (fume) Nunavut OEL TWA (mg/m³) 5 mg/m³ (fume) 5 mg/m³ ( dust, respirable mass) 10 mg/m³ (total mass - dust) Northwest Territories OEL STEL (mg/m³) 10 mg/m³ (fume) Northwest Territories OEL TWA (mg/m³) 5 mg/m³ (fume) 5 mg/m³ ( dus t, respirable mass) 10 mg/m³ (total mass - dust) Ontario OEL STEL (mg/m³) 10 mg/m³ (respirable) Ontario OEL TWA (mg/m³) 2 mg/m³ (respirable) Prince Edward Island OEL STEL (mg/m³) 10 mg/m³ (respirable fraction) Prince Edward Island OEL TWA (mg/m³) 2 mg/m³ (respirable fraction) Québec VECD (mg/m³) 10 mg/m³ (fume) Québec VEMP (mg/m³) 10 mg/m³ (containing no Asbestos and % Crystalline silica - total dust) 5 mg/m³ (fume) Saskatchewan OEL STEL (mg/m³) 10 mg/m³ (dust and fume, respirable fraction) Saskatchew an OEL TWA (mg/m³) 2 mg/m³ (dust and fume, respirable fraction) Yukon OEL STEL (mg/m³) 10 mg/m³ (fume) Yukon OEL TWA (mg/m³) 5 mg/m³ (fume) 30 mppcf (dust) 10 mg/m³ (dust) Component G USA NIOSH NIOSH REL (TWA) (mg/m³) 2 mg/m³ MiYO Structure Pastes Safety Data Sheet 5 /17/17 EN ( English US ) 7 / 1 2 Alberta OEL TWA (mg/m³) 2 mg/m³ Exposure Controls Appropriate Engineering Controls: Local exhaust and general ventilation must be adequate to meet exposure standards. Site - specific risk assessments should be conducted to determine the appropriate exposure control measures. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure l imits. Emergency eye wash fountains should be available in the immediate vicinity of any potential exposure . Ensure all national/local regulations are observed. Personal Protective Equipment: Protective goggles. Gloves. Protective clothing. Insufficient ventilation: wear respiratory protection. Materials for Protective Clothing: Chemically resistant materials and fabrics. Hand Protection: Wear chemically resistant protective gloves. Eye Protection: Chemical safety goggles. Skin and Body Protection: Wear suitable protective clothing. Respiratory Protection: If exposure limits are exceeded or irritation is experienced, approved respiratory protection should be worn. Other Information: When using, do not eat, drink or smoke. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Information on Basic Physical and Chemical Properties Physical State : Liquid Appearance : Various

8 paste Odor : None Od
paste Odor : None Odor Threshold : Not available pH : Not available Evapo ration Rate : Not available Melting Point : ≈ 900 - 1000 °C ( ≈ 1652 - 1832 °F) Freezing Point : Not available Boiling Point : Not available Flash Point : Not available Auto - ignition Temperature : Not available Decompositio n Temperature : Not available Flammability (solid, gas) : Not available Lower Flammable Limit : Not available Upper Flammable Limit : Not available Vapor Pressure : Not available Relative Vapor Density at 20 °C : Not available Relative Density : Not available Specific gravity / density : ≈ 2.5 g/cm³ Specific Gravity : Not available Solubility : Insoluble in water Partition Coefficient: N - Octanol/Water : Not available Viscosity : Not available Explosion Data – Sensitivity to Mechanical Impact : Not expected to present an explosion hazard due to mechanical impact Explosion Data – Sensitivity to Static Discharge : Not expected to present an explosion hazard due to static discharge VOC content : None MiYO Structure Pastes Safety Data Sheet 5 /17/17 EN ( English US ) 8 / 1 2 SECTION 10: STABILITY AND REACTIVITY Reactivity : Hazardous reactions will not occur under normal conditions. Chemical Stability : Stable under recommended handling and storage conditions (see section 7). Possibility of Hazardous Reactions : Hazardous polymerization will not occur. Conditions to Avoid : Direct sunlight, extremely high or low temperatures, and incompatible materials. Incompatible Materials : Strong acids. Strong bases. Strong oxidizers. Hazardous Decomposition Products : Toxic acrolein. SECTION 11: TOXICOLOGICAL INFORMATION In formation on Toxicological Effects - Product LD50 and LC50 Data: Not available Skin Corrosion/Irritation: Not classified Serious Eye Damage/Irritation: Causes serious eye damage. Respiratory or Skin Sensitization: Not c lassified Germ Cell Mutagenicity: Not classified Teratogenicity: May cause birth defects Carcinogenicity: Not classified. Specific Target Organ Toxicity (Repeated Exposure): Not classified Reproductive Toxicity: May damag e fertility or the unborn c hild Specific Target Organ Toxicity (Single Exposure): Not classified. Aspiration Hazard: Not classified Symptoms/Injuries After Inhalation: Inhalation of dusts and fumes can cause metal fume fever. Symptoms can include a metallic or sweet taste in the m outh, sweating, shivering, headache, throat irritation, fever, chills, thirstiness, muscle aches, nause

9 a, vomiting, weakness, f atigue, and sh
a, vomiting, weakness, f atigue, and shortness of breath Symptoms/Injuries After Skin Contact: May cause skin irritation Symptoms/Injuries After Eye Conta ct: Causes serious eye damage. Symptoms may include: Redness, pain, swelling, itching, burning, tearing, and blurred vision. Causes permanent damage to the cornea, iris, or conjunct iva Symptoms/Injuries After Ingestion: Ingestion is likely to be harmful or have adverse effects Chronic Symptoms: May damage fertility or the unborn child (oral) . This product contains Crysta lline Silica dust that is mixed with a liquid to form a paste mixture, and therefore the dust is not likely to be dispersed into the air. I f dust is released into the air, repeated exposure to respirable (airborne) crystalline silica dust may cause lung damage in the form of silicosis, lung cancer, or res piratory irr itation Information on Toxicological Effects - Ingredient(s) LD50 and LC50 D ata: Component E LD50 Oral Rat 6450 mg/kg ATE US (Oral) 6450.000 mg/kg body weight Component G LD50 Oral Rat � 2000 mg/kg LD50 Dermal Rabbit � 2500 mg/kg Component C LD50 Oral Rat 3160 mg/kg Component B LD50 Oral Rat � 5000 mg/kg LD50 Dermal Rat � 5000 mg/kg Component F LD50 Oral Rat � 5000 mg/kg LD50 Dermal Rat � 2000 mg/kg Component G LD50 Oral Rat � 20 g/kg Acute Toxicity: Not classified MiYO Structure Pastes Safety Data Sheet 5 /17/17 EN ( English US ) 9 / 1 2 Component A IARC Group 1 OSHA Hazard Communication Carcinogen List In OSHA Hazard Communication Ca rcinogen list. Component B IARC Group 1 National Toxicology Program (NTP) Status Known Human Carcinogens. OSHA Hazard Communication Carcinogen List In OSHA Hazard Communication Carcinogen list. SECTION 12: ECOLOGICAL INFORMATION Toxicity Ecolo gy - General: Toxic to aquatic life. Toxic to aquatic life with long lasting effects. Component D EC50 Daphnia 1 370 - 490 mg/l (Exposure time: 48 h - Species: Daphnia magna) Component F LC50 Fish 1 780 μg/l (Exposure time: 96 h - Species: Pimephales promelas) EC50 Daphnia 1 0.122 mg/l NOEC chronic fish 0.026 mg/l (Species: Jordanella floridae) Persistence and Degradability MiYO Pastes Persistence and Degradability Not established. Bioaccu mulative Potential MiYO Pastes Bioaccumulative Potential Not established. Mobility in Soil Not available Other Adverse Effects Other Information: Avoid release to the environment. SECTION 13: DISPOSAL CONSIDERATIONS Sewage Disposal Recommendati ons: This material is hazardous to the aquatic environment . Keep out of sewers and waterways. Waste Disposal Recommendations: Dispose of w

10 aste material in accordance with all lo
aste material in accordance with all local, regional, national, provincial, territorial and international regulations. Ecology – Waste Materials: Avoid release to the environment. SECTION 14: TRANSPORT INFORMATION In Accordance with DOT Proper Shipping Name : ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O. S. ( Component F ) Hazard Class : 9 Identification N umber : UN3082 Label Codes : 9 Packing Group : III Marine Pollutant : Marine pollutant ERG Number : 171 In Ac cordance with IMDG Proper Shipping Name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O. S. ( Component F ) Hazard Class : 9 Identification Number : UN 3082 Packing Group : III Label Codes : 9 EmS - No. (Fire) : F - A EmS - No. (Spillage) : S - F Marine pollutant : Marine pollutant In Accordance with IATA Proper Shipping Name : ENVIRONMENTALLY HAZAR DOUS SUBSTANCE, LIQUID, N.O. S. ( Component F ) MiYO Structure Pastes Safety Data Sheet 5 /17/17 EN ( English US ) 10 / 1 2 Packing Group : III Identification Number : UN 3082 Hazard Class : 9 Label Codes : 9 ERG Code (IATA) : 9L In Accordance with TDG Proper Shipping Name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O. S. ( Component F ) Packing Group : III Hazard Class : 9 Identification Number : UN3082 Label Codes : 9 Marine Pollutant (TDG) : Marine pollutant SECTION 15: REGULATORY INFORMATION US Federal Regulations Component E Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on United States SARA Section 313 SARA Section 313 - Emission Repo rting Immediate (acute) health hazard Component A Listed on the United States TSCA (Toxic Substances Control Act) inventory SARA Section 311/312 Hazard Classes Delayed (chronic) health hazard Component C Listed on the United States TSCA (Toxic Subs tances Control Act) inventory Component B Listed on the United States TSCA (Toxic Substances Control Act) inventory SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Delayed (chronic) health hazard Component D Listed on the United States TSCA (Toxic Substances Control Act) inventory Component F Listed on the United States TSCA (Toxic Substances Control Act) inventory Component G Listed on the United States TSCA (Toxic Substances Control Act) inventory US State Regulations C omponent B U.S. - California - Proposition 65 - Carcinogens List WARNING: This product contains chemicals known to the State of California to cause cancer. Component E U.S. - Massachusetts - Right To Know List U.S. - New Jerse

11 y - Right to Know Hazardou s Substanc
y - Right to Know Hazardou s Substance List Component A U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List Component C U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List MiYO Pastes SARA Se ction 311/312 Hazard Classes Immediate (acute) health hazard Delayed (chronic) health hazard MiYO Structure Pastes Safety Data Sheet 5 /17/17 EN ( English US ) 11 / 1 2 U.S. - Pennsylvania - RTK (Right to Know) List Component B U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List Com ponent D U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List Component F U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardo us Substance List U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) List Component G U.S. - New Jersey - Right to Know Hazardous Substance List Canadian Regulations Component E Listed on the Canadian DSL (Domestic Substances List) Lis ted on the Canadian IDL (Ingredient Disclosure List) IDL Concentration 1 % WHMIS Classification Class D Division 2 Subdivision B – Toxic material causing other toxic effects Component A Listed on the Canadian DSL (Domestic Substances List) Listed on the Canadian IDL (Ingredient Disclosure List) IDL Concentration 1 % WHMIS Classification Class D Division 2 Subdivision A - Very toxic material causing other toxic effects Component C Listed on the Canadian DSL (Domestic Substances List) WHMIS Classi fication Uncontrolled product according to WHMIS classification criteria Component B Listed on the Canadian DSL (Domestic Substances List) Listed on the Canadian IDL (Ingredient Disclosure List) IDL Concentration 1 % WHMIS Classification Class D Divis ion 2 Subdivision A - Very toxic material causing other toxic effects Class D Division 2 Subdivision B - Toxic material causing other toxic effects Component D Listed on the Canadian DSL (Domestic Substances List) Listed on the Canadian IDL (Ingredient Disclosure List) IDL Concentration 1 % WHMIS Classification Class D Division 2 Subdivision B - Toxic material causing other toxic effects Component F Listed on the Canadian DSL (Domestic Substances List) MiYO Pastes WHMIS Cl assification Class D Division 2 Subdivision A - Very toxic material causing other toxic effects Class D Division 2 Sub

12 division B - Toxic material causing o
division B - Toxic material causing other toxic effects MiYO Structure Pastes Safety Data Sheet 5 /17/17 EN ( English US ) 12 / 1 2 Listed on the Canadian IDL (Ingredient Disclosu re List) IDL Concentration 1 % WHMIS Classification Uncontrolled product according to WHMIS classification criteria Component G Listed on the Canadian DSL (Domestic Substances List) WHMIS Classification Uncontrolled product according to WHMIS classif ication criteria This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS contains all of the information required by CPR. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATI ON OR LAST REVISION Revision Date : 5 /17/17 Other Information : This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200. GHS Full Text Phrases : ------ Aquatic Acute 1 Hazardous to the aquatic environment - Acute Hazard Category 1 ------ Aquatic Acute 2 Hazardous to the aquatic environment - Acute Hazard Category 2 ------ Aquatic Acute 3 Hazardous to the aquatic environment - Acute Hazard Category 3 ------ Aquatic Chronic 1 Haz ardous to the aquatic environment - Chronic Hazard Category 1 ------ Aquatic Chronic 2 Hazardous to the aquatic environment - Chronic Hazard Category 2 ------ Carc. 1A Carcinogenicity Category 1A ------ Comb. Dust Combustible Dust ------ Eye Dam. 1 Ser ious eye damage /eye irritation Category 1 ------ Repr. 1B Reproductive toxicity Category 1B ------ Skin Irrit. 2 Skin corrosion/irritation Category 2 ------ STOT RE 1 Specific target organ toxicity (repeated exposure) Category 1 ------ STOT SE 3 Specif ic target organ toxicity (single exposure) Category 3 ------ H232 May form combustible dust concentrations in air ------ H315 Causes skin irritation H320 Serious eye damage/eye irritation Category 2B ------ H335 May cause respiratory irritation ----- - H350 May cause cancer ------ H360 May damage fertility or the unborn child ------ H372 Causes damage to organs through prolonged or repeated exposure ------ H400 Very toxic to aquatic life ------ H401 Toxic to aquatic life ------ H410 Very toxic to aquatic life with long lasting effects ------ H411 Toxic to aquatic life with long lasting effects Party Responsible for the Preparation of This Document Jensen Industries 1 - 800 - 243 - 2000 This information is based on our current knowledge and is int ended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. NA GHS