Gas laws describe the relationships between the 4 key parameters describing the behavior of gases Temperature T a measure of the kinetic energy KE of atoms and molecules C F Expressed in K for calculations ID: 784216
Download The PPT/PDF document "Gas Laws The atmosphere is made up of ga..." is the property of its rightful owner. Permission is granted to download and print the materials on this web site for personal, non-commercial use only, and to display it on your personal computer provided you do not modify the materials and that you retain all copyright notices contained in the materials. By downloading content from our website, you accept the terms of this agreement.
Slide1
Gas Laws
The atmosphere is made up of gases so we need to know the basic laws of how gases behave
Slide2Gas laws describe the relationships between the 4 key parameters describing the behavior of gases
Temperature (T)
: a measure of the
kinetic energy (KE)
of atoms and molecules. (°C, °F). Expressed in °K for calculations.
Pressure (P)
: Force per unit area: F/A. Expressed in Pascal (N/m
2
)-- Newton per meter squared. Often in terms of
hPa
(100 N/m
2
)
Slide3Key Parameters
Density (
r
):
r
= Mass/Volume. R= M/V Expressed in kg/m3 in the metric system. At the earth’s surface r ~ 1 kg/m3 , 1 kg = 1000 grams ~2.2 lbsVolume (V): Expressed in m3
Slide4The Key Gas Parameters are Related by
GAS LAWS
Slide5Boyle’s Law (~1660)
Start with a sample of air with a temperature (T), pressure (P), and volume (V). If T is kept constant, then:
PV=constant
Slide6Boyles Law
Basis of air pumps we all use
Slide7Law of Charles and Guy
Lussac
If you increases temperature, while keeping pressure constant, volume will increase.
V= constant * T (°K)
V = CT
So if you increase T, V will increaseBasis of car engines.
Slide8Slide9One have two gas laws when you can have one?
Slide10Can combine both gas laws into one: the
Perfect Gas Law
(a.k.a.,
the Ideal Gas Law
)
P= rRTWhere r is density (kg m-3), R is a gas constant, P is pressure (Nm-2), and T is temperature (K)One of the key relationships of meteorology
Slide11Let’s prove it contains the other laws
Start with
P=
r
RT
for a particular sample of air (thus mass is constant)Assume T=constant. Then you have: P= r *constant orP = constant* M/V or PV=constant BOYLE’S LAW!
Slide12More fun: Law of Charles and Guy
Lussac
Or assume P=constant. Then you have:
Constant=(M/V)*R*T
Since Mass and R are constants:
Constant= T/VV = constant*T: Law of Charles and Guy Lussac
Slide13Gas Law Importance
We will these gas laws to explain many weather features
The perfect gas law is one of the key relationships used in computer weather forecast models.
Slide14Adiabatic Processes
Clouds form as air cools when it rises.
But why does rising air cool?
Air warms as it forced to sink. Why?
Why does the spray of aerosol cans feel cold?
And why are bike pumps warm after use?
Slide15Explained by adiabatic processes!
Air parcel: An identifiable collection of air that stays together.
Think of the air in balloon.
An
adiabatic process
is a processes that occurs WITHOUT the exchange of energy with the surroundings.In an meteorological context, an adiabatic process is one in which there is no exchange of energy between an air parcel and the surrounding air.
Slide16Slide17How do temperature and pressure vary for an air parcel under an adiabatic process?
Imagine an insulated cylinder with air in it, so NO heat exchange with the outside environment.
Push down the piston. Pressure and temperature increases.
T
1
, P1T2, P2P2 > P1T2 > T1
Slide18Adiabatic processes
So if an air parcel is compressed adiabatically
, temperature will rise
Similarly, if you expand an air parcel,
its temperature will fall
.Why?When compressing air, you are doing work on the molecules, giving them a “shove” and making them go faster.If you allow the air parcel to expand, it takes energy to push the boundaries of the parcel out (or to push the piston out), resulting in cooling.
Slide19To Put It Another Way: The Adiabatic Law
In the absence of heat exchange, air warms when compressed and cools when it expands.
Explains a great deal of what it occurring in the atmosphere, when air is forced to rise or sink
When air is forced to rise, it goes into an environment of lesser pressure (since pressure declines with height).
With less pressure on the air parcel, it is able to expand
Expansion results in cooling
Slide20Adiabatic Law
When air sinks, its environment has higher pressure, compressing and warming the air parcel.
Slide21Influence on saturation and clouds
Adiabatic cooling can result in increased relative humidity and saturation where there is upward motion.
The amount of water vapor in the air parcel does not change as it rises, but as the temperature falls, the air parcel has less ability to hold water vapor.
Thus, RH increases.
With enough vertical motion, the RH climbs to 100% and the air can reach saturation—water condenses out and clouds can form.
Mountains are prime example of this process.
Slide22Downslope warming and drying
On the other hand, when air sinks it warms adiabatically and relative humidity decreases. Clouds thus evaporate, producing a cloud or
rain shadow
.
Slide23Great examples here in Washington
Slide24Slide25Slide26Adiabatic cooling/warming can occur outside of mountains as well
Slide27Warm Front
Slide28These clouds are associated with adiabatic cooling