SAMPE BRAZIL October 2017 Joe Spangler Technical Services Manager Toho Tenax America Inc Phone 1859 2824897 Mobile 1513 3173552 jspanglertohotenaxuscom Slide 1 of 20 Slide 2 of 20 ID: 655789
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Toho Tenax America
Toho Tenax Recycling – Closing the Loop
SAMPE BRAZIL October 2017
Joe Spangler
Technical Services Manager
Toho Tenax America, Inc.
Phone: +1(859) 282.4897
Mobile: +1(513) 317.3552
jspangler@tohotenax-us.comSlide2
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Slide 2 of 20Slide4
Slide 3 of 20Slide5
•
General Toho Tenax CFRTP
Product
Families
•
Why Recycle?
•
Recycle
Forms
•
Material Characteristics/Properties• General Applications and Uses• Current Part Making• Conclusions
Content
Slide 4 of 20Slide6
Toho Tenax CFRTP
* Product Families
MECHANICAL PROPERTIES
PART GEOMETRY COMPLEXITY
Tenax
®
TPUD
ThermoPlastic
UniDirectional
Tenax
®
TPCL
ThermoPlastic
Consolidated Laminate
Long-Fiber
Stretch-Broken Fiber
Co-mingled
Woven
Fabric
Short fiber
Uni-directional
Tenax
®
Short Fiber
Limited Fiber Length
‟Unlimited” Fiber Length
Tenax
®
TPWF
ThermoPlastic
Woven Fabric
*CFRTP: Carbon Fiber Reinforced ThermoPlastics
Tenax
®
HTS45 P12
Tenax
®
IMS65 P12
Slide 5 of 20Slide7
Why Recycle?
Added Value from Production Scrap
Unique Material / Unique Market
100% Utilization
Saves
Energy & Resources
Slide 6 of 20Slide8
Recycle Forms
Slide 7 of 20
Tenax-A
rTPGMX
PEEK-HTA40 (granulate)
Tenax-A
rTPWFX
PEEK-HTA40 (chips)
Tenax-A
rTPGLX
PEEK-HTA40 (
granulate laminate)
Tenax-A
rTPWFCLX PEEK-HTA40 (chips laminate)Tenax-E COMPOUND rPEEK CF30 (chips injection pellet)Tenax-A rPEEK-HTA40 5HS Billet (thick TPCL)Tenax-A rPEEK-HTS45 UD tape (chopped PEEK tape)Slide9
Material Characteristics/Properties
Great Mechanical Properties
Exceptional Wear Resistance
Excellent Toughness
High Impact Strength
Excellent Vibration Dampening
Overmolding
, remolding, reforming
Co-consolidation/
Weldable
High Service Temperature
Slide 8 of 20Slide10
Recycle Mechanical Properties
COMPOSITE
PROPERTIES
1
UNITS
rTPGMX
rTPWFCX
rPEEK
COMPOUND CF30
Tensile Strength
MPa (ksi)
120 (17.4)
600 (87)
256 (37.1)
Tensile Modulus
GPa
(
Msi
)
28 (4.1)40 (5.8)23 (33.4)
Flexural StrengthMPa (ksi)266 (39)800 (116)240-260 (34.8-37.7)Flexural ModulusGPa (Msi)26 (3.8)60 (8.7)13-15 (1.9-2.2)
1 – tested per ASTM methodsSlide 9 of 20Slide11
Comparative Mechanical Properties
COMPOSITE
PROPERTIES
1
UNITS
[(0˚/90˚)
₃]s
TPCL Layup
ALUMINUM 6061
Titanium
Grade
1
PEEK RESIN
Tensile Modulus
GPa (Msi)60 (8.7)
69 (10)
105 (15.2)
3.5 (0.51)
Tensile Strength
MPa (
ksi)
954.9 (138.5)310 (45)170-310 (25-45)97 (14)Compression ModulusGPa (Msi)60 (8.7)69 (10)110 (16.0)4.1 (0.6)Compression Strength
MPa (ksi)725.3 (105.2)207 (30)NA118 (17)Flexural ModulusGPa (Msi)66.2 (9.6)69 (10)NA4.1 (0.59)Flexural Strength
MPa (ksi)1125.2 (177.7)607 (88)NA170 (24.7)Densityg/cm3
1.52.74.51.3HDT at 264 psi˚C (˚F)260 (500)NA
NA160 (320)Tg˚C (˚F)143 (289)NANA143 (289)
1 – tested per ASTM methods
Slide 10 of 20Slide12
General Applications
▲
Oil & Gas
▲
Medical
▲
Aerospace
▲
Industrial
▲
Automotive
Slide 11 of 20Slide13
Existing 3D Part Making (parent material)
Tenax
®
TPCL
PEEK-HTA40
-Laminate*
A
utomated Process
C
omplex Part Shape
V
ery Short Cycle Time
J
oining Technologies
*TPCL:
T
hermo
P
lastics
C
onsolidated
L
aminate
Slide 12 of 20Slide14
Utilization of Waste & By-Products
Slide 13 of 20
rTPWFX
Chip
rPEEK
COMPOUND CF30
rTPGMX
granulate
Chopped tapeSlide15
3D Part Making (recycle compounds)
rPEEK
HTA40 5HS
Finished Part(s)
Tenax
®
-A
rPEEK
Forms
Slide 14 of 20
rTPWFX
Chip
rPEEK
COMPOUND CF30
rTPWFX
Chip
Direct Machine
Finished Part
Thermoforming, Injection, ExtrusionSlide16
Detail Example - 3D Part Making
•
Cut TPWF*
PEEK
“semi-
preg
”
- .5 cm
squares.
•
Special Compression-Molded Processing with
Stainless Steel Inserts
rTPWFX
chips:
- Recycled Tenax
®
HTA40 PEEK 5HS Fabric
(a). Compression/cavity molded
*TPWF:
T
hermoPlastics Woven FabricSlide 15 of 20Slide17
Detail Example - 3D Part Making
•
Cut TPWF*
PEEK
“semi-
preg
”
- .5 cm
squares.
•
Special Compression-Molded Processing with
Stainless Steel Inserts
rPEEK
COMPOUND CF30 pellet:
- Recycled Tenax
®
HTA40 PEEK 5HS Fabric with virgin PEEK pellet
(a). Injection-molded
*TPWF:
ThermoPlastics Woven
FabricSlide 16 of 20rTPWFX ChiprPEEK COMPOUND CF30Slide18
Thick TPCL – 3D Direct Machine Part(s)
Tenax
®
-A TPCL rPEEK-HTA40 Billet
:
Toho Tenax HTA40 3K 5HS PEEK
Prepreg
.
Thickness from .31mm (.012”- 1 ply) to 101mm (4.0” – 325 plies)
Slide 17 of 20Slide19
Current Development 3D Part Making Recycle
•
Cut TPUD
PEEK
“UD Tape” – 1 X 3
cm
strip.
•
Special Compression-Molded
Processing
with
Stainless Steel Inserts
TPUD:
1
).
Tenax
®
HTS45
PEEK
UD Tape (P12 sized)
(a). Compression/cavity molded
*TPUD: ThermoPlastics Uni DirectionalSlide 18 of 20Slide20
Recycle Supply Chain of
Tenax®-E TP Compounds
Slide 19 of 20
TPWF
Scrap
TPCL
B-Grades
TPUD
Scrap
TPCL
Grids
Teijin
Kasei
Europe
Distributor
Toho
Tenax
Europe
r-Polymer Compounder
rPEEK
/CF pelletizingSlide21
Conclusions
Slide 20 of 20
High performance mechanical properties can be achieved using a combination of Recycled semi-
preg
, granulate, laminates, or UD tape.
Material combination has proven to create a new category of material that is capable of changing the selection of materials that designers currently have available.
Excellent machinability and ability to be molded into thick laminates or solid shapes creating a new category of material.
C
ombination of unique fiber placement and excellent machinability make it a great choice for high temperature and high pressure component applications.Slide22