W orkplace H azardous M aterials I nformation S ystem WHMIS is a Canada wide hazard communication system developed to provide employers and workers information about hazardous products used in the workplace ID: 363948
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What does WHMIS mean?
W
orkplaceHazardousMaterialsInformationSystem
WHMIS is a Canada wide hazard communication system developed to provide employers and workers information about hazardous products used in the workplaceSlide3
What does WHMIS mean?
WHMIS is composed of
3 main elements to communicate the hazards of controlled products: Labels – affixed to containers of hazardous materials and provides information regarding the hazards Safety Data Sheets (SDS) – provide supplementary information to hazards outlined on the labels (Note: These were formerly called Material Safety Data Sheets (MSDS)3. Education – training on how to use the information providedSlide4
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Chemical Classifications
Chemicals are classified using a globally harmonized system (GHS) that provides standardized language for:
Health Hazard CategoriesPhysical Hazard CategoriesEnvironmental Hazard Categories*Slide6Slide7
Labels: Pictograms – Health Hazards
Irritant (skin and eye)
Skin Sensitizer
Acute Toxicity (harmful)
Specific Target Organ Toxicity
Respiratory Tract Irritant
Hazardous to Ozone Layer (Non-Mandatory)
Acute toxicity (Severe
)
Fatal or toxic
Skull and Crossbones:
Exclamation Mark:Slide8
Acute (short term)
and
Chronic (long term)
Eyes
Respiratory System
SkinSlide9
Labels: Pictograms –
Health Hazards
Skin Corrosion/Burns
Eye Damage
Corrosive to Metals
Carcinogen
Mutagenicity
Reproductive Toxicity
Respiratory Sensitizer
Target Organ Toxicity
Aspiration Hazard
Health Hazard
CorrosionSlide10
Labels: Pictograms –
Physical Hazards
Flammables
Pyrophorics
Self-Heating
Emits Flammable Gas
Self-
Reactives
Organic Peroxides
Explosives
Self reactives
Organic peroxides
Exploding Bomb
Explosives
Self-
Reactives
Organic Peroxides
FlameSlide11
Labels: Pictograms –
Physical Hazards
oxidizer
Explosives
Self reactives
Organic peroxides
Gas Cylinder
Gas under pressure
Flame over CircleSlide12
Labels:
Pictograms
Aquatic Toxicity (non-mandatory in Canada)
Explosives
Self reactives
Organic peroxides
Biohazardous
Biohazardous Infectious Materials
EnvironmentSlide13
Labels
There are several new label elements:
Symbols called “Pictograms”Signal WordsHazard StatementsPrecautionary StatementsProduct IdentificationSupplier/Manufacturer Identification
www.osha.gov/Publications/HazComm_QuickCard_Labels.htmlSlide14
Labels: Signal Word
These are words
used to indicate the severity of the hazard and alert employees to the potential hazard.Only 2 signal words will appear:“DANGER” (more severe hazard)“WARNING” (less severe hazard)Not all labels will have a signal word. Some chemicals are not hazardous enough to require that a signal word appear on the label.Slide15
Labels: Hazard Statement
A statement assigned to a hazard class and category that describes the nature of the hazard(s) of a chemical; including, where appropriate, the degree of hazards
Fatal if swallowedToxic if swallowedHarmful if swallowedMay be harmful if swallowedHighly flammable liquid and vaporSlide16
Labels: Precautionary Statements
Recommended measures related to:
PreventionResponseStorageDisposalExamples:Wear respiratory protectionWash with soap and waterStore in a well ventilated placeKeep away from heat/sparks/open flameSlide17
Safety Data Sheets (SDS) - (formerly MSDS)
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Section
Hazardous Product Regulations Heading
1
Identification
2
Hazard identification (including classification and label text)
3
Composition/information on ingredients
4
First-aid measures
5
Fire-fighting measures
6
Accidental release measures
7
Handling and storage
8
Exposure controls/personal protection
9
Physical and chemical properties
10
Stability and reactivity
11
Toxicological information
12-15
Ecological
,
transport and regulatory information
,
disposal
considerations
16
Other informationSlide18
Section 1 – Identification:
Identifies
the chemical on the SDS as well as the recommended uses. It also provides the essential contact information of the supplier.Section 2 - Hazards Identification:Hazards of the chemical presented on the SDS Appropriate warning information associated with those hazards.
Safety Data Sheets Slide19
Safety Data Sheets
Section 3 – Composition / Ingredients:
Identifies the ingredient(s) contained in the product indicated on the SDS, including:impurities and stabilizing additives. information on substances, mixtures, and all chemicals where a trade secret is claimed.Section 4 - First-Aid Measures:Describes the initial care that should be given by untrained responders to an individual who has been exposed to the chemical.Slide20
Safety Data Sheets
Section 5 – Fire-Fighting
Measures:Provides recommendations for fighting a fire caused by the chemical.Section 6 - Accidental Release Measures:Provides recommendations:Appropriate response to spills, leaks, or releases, (e.g. containment and cleanup practices)Response for large vs. small spills, if different.Slide21
Safety Data Sheets
Section 7 – Handling and Storage:
Provides guidance on the safe handling practices and conditions for safe storage of chemicals.Section 8 – Exposure Controls / Personal Protection:Indicates the exposure limits, engineering controls, and personal protective measures that can be used to minimize worker exposure.Slide22
Safety Data Sheets
Section 9 – Physical and Chemical Properties:
Identifies physical and chemical properties associated with the substance or mixture.Section 10 – Stability and ReactivityDescribes the reactivity hazards of the chemical and the chemical stability information. Includes: reactivity, chemical stability, and other.Slide23
Safety Data Sheets
Section 11 - Toxicological Information:
Identifies toxicological and health effects information or indicates is data unavailable.Section 12 – Ecological InformationSection 13 – Disposal ConsiderationSection 14 – Transport InformationSection 15 – Regulatory InformationSection 16 – Other InformationSlide24
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Match the WHMIS Pictograms below with the corresponding hazard:
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