PDF-Heavy Aromatic Distillate

Revision Date 05152015 Version 1 5 Print Date 05262015 110000001324 Page 1 of 11 SAFETY DATA SHEET SECTION 1 IDENTIFICATION OF THE SUBSTANCEMIXTURE AND OF THE COMPANYUNDERTAKING Trade name. PAHs are found naturally in the environment but they can also be manmade In their purest form PAHs are solid and range in appearance from colorless to white or pale yellow green PAHs are created when products like coal oil gas and garbage are burned Karle and Padmanabhan Balaram Contribution from the Department of Physics Molecular Biophysics Unit and Department of Inorganic and Physical Chemistry Indian Institute of Science Bangalore560 012 India and Laboratory for the Structure of Matter Na Benzene is aromatic: a cyclic conjugated compound with 6 . . electrons. Reactions of benzene lead to the retention of the aromatic core. Types of Reactions. Electrophilic. substitution. Diazonium. 15-8. Benzene undergoes substitution reactions with electrophiles.. Electrophiles attack benzene by substituting for a hydrogen atom, not addition to the ring.. Under the conditions of this type of reaction, ordinary non-aromatic conjugated polyenes would polymerize rapidly.. Most common reactions for aromatics involve replacement of ring . hydrogens. by other atoms or groups . (substitution reactions). Mechanism of Electrophilic Aromatic Substitution Reactions. Electrophile. M.ARULSELVAN. Syllabus. Benzene and Aromaticity. 4.1 Concept of aromaticity:. . . -Huckel's rule for aromaticity, . -identification of aromatic, . -Non-aromatic and anti aromatic systems based on planarity, conjugation and Huckel's rule.. Leon. María. Elena. Larissa. Vanillin. Information. History of benzene. Ring structure. Functional groups. Hückel’s. rule. Vanillin. History of benzene. The . empirical formula for benzene had been long known, but its highly unsaturated structure was a challenge to determine. . In 1825, Michael Faraday isolated a hydrocarbon called benzene, which consists of a six-carbon ring with alternating double bonds and the molecular formula C. 6. H. 6. . . Learning Goal . Describe the bonding in benzene; name aromatic compounds, and draw their line-angle structural formulas.. 1435-1436. 2014-2015. Learning Objectives. . Understand the. . resonance description of structure of benzene. Understand the hybridization in benzene. Understand the relation between the stability of benzene and resonance energy. 240 . Chem. 1. The expressing . aromatic compounds . came to mean . benzene. . and derivatives of benzene. .. . Structure of Benzene: Resonance Description. C. 6. H. 6. It contains a six-membered ring and three additional degrees of unsaturation.. 1. Nomenclature . of Polycyclic Aromatic Compounds. Polycyclic . aromatic compounds have two or more benzene rings fused together. 2. Naphthalene, anthracene and phenanthrene are obtained from . coal tar. MICHAEL FARADAY (1791-1867). first person to isolate and identify benzene. early benzene uses:. - . decaffeinate . coffee. - antiknock additive . in gasoline. - solvent in chem rxns. now we know benzene is a carcinogen!. Arenium Ion Mechanism . Some Aromatic Electrophilic Substitution Reactions Viz. Nitration, Sulphonation, Halogenation, Friedel- Crafts Reaction. Orientation & Reactivity in Mono Substituted Benzene. D. r. . Zamir G Khan . Assistant Professor . H R Patel Institute of Pharmaceutical Education and Research Shirpur, Dist. Dhule, (M.S) 425405. Copyright @ Mr. Z G Khan. 2. If benzene is 1,3,5-cyclohexatriene as .