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Chemical Security - PowerPoint Presentation

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Chemical Security - PPT Presentation

Program Fundamentals of Wastewater Treatment Fundamentals of Wastewater Treatment Wastewater Treatment Activated sludge processes Fixed film and suspended processes Aerobicanoxicanaerobic processes modifications ID: 426387

wastewater sludge membrane water sludge wastewater water membrane activated plant process waste anaerobic aerobic anoxic removal processes treatment biological

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Slide1

Chemical Security

Program

Fundamentals

of Wastewater TreatmentSlide2

Fundamentals of Wastewater TreatmentSlide3

Wastewater Treatment

Activated sludge processes

Fixed film and suspended processes

Aerobic/anoxic/anaerobic processes modifications.Nutrient removal nitrification / denitrification, phosphorous removalWater reuse and reclamation membrane bioreactorsDisinfectionSatellite and On-site Wastewater Treatment

3Slide4

4

Wastewater

Contaminants

Bacteriological,

Vibrio

Cholerae

, Campylobacter, Salmonella ,

Shigella

,

Viruses

Hepatitis A, Norovirus

Protozoan

Giardia, Cryptosporidium,

Entamoeba

Biological

oxygen demand

Organic matter causes algae to thrive and deplete dissolved oxygen

Nutrient

removal to prevent eutrophication

Nitrogen and phosphorus from waste, and agricultureSlide5

What

Does Wastewater Look Like

?

5

Measurement

Value

Units

Total Suspended Solids (TSS)

210

mg/L

BOD

190

mg/LTOC 430mg/LCOD 140mg/LOrganic Nitrogen15mg/LFree Ammonia25 mg/LNitrite/Nitrate0/0 mg/LPhosphorous7mg/LTotal coliform107-109 colonies/100mLFecal coliform104-106 colonies/100mLCryptospiridium oocysts0.1-10 no./100mLGiardia Lamblia0.1-100no./100mL

Source: Wastewater Engineering, Metcalf and Eddy- medium strength WWSlide6

Routine

Bacterial Testing Consists

of Measuring Indicator Organisms

6Testing for pathogens directly is expensive and hazardous

Indicators from the family

Enterobacteriacae

are used

(E. Coli,

Citrobacter,Enterobacter

,

Klebsiella

)Grow bacteria on a specified medai and count the number of colonies after incubationOther assays are used and are approved by the US EPA (Colilert shown)Slide7

Initial

Steps

in Satellite and

Centralized Wastewater Treatment7

Fixed film process

Primary settling

Screens

Sludge drying

Grit removal

DigesterSlide8

Fixed

Film Biological Processes

8

Treated Water

Waste Water

Facultative/Anaerobic

Bed Media

Aerobic

100µm

~

1 mm

BiofilmSlide9

Fixed

Film Biological Processes

9

Trickling filter

Uses biofilm to treat water to remove BODSlide10

Trickling

Filter Effectiveness

10

BOD

5

removal rates for trickling filters

Filter Type

Hydraulic loading m

3

/m

2

day

BOD5 Removal (%)Low Rate1-480 - 90Intermediate 4-1050 - 70High Rate10-4065 - 85Roughing Filter 40 - 65Source: Environmental Engineers Handbook, 1997.Slide11

Suspended

Growth Biological Processes

11

Anoxic – no dissolved oxygen

Waste Water

Aerobic

Treated Water

Activated Sludge

Anoxic

sludge

Return activated sludge

Coagulation

ClarifierSlide12

BOD and

Nutrient

(Nitrogen and

Phosphorous) Removal 12

Aerobic Conditions

Anoxic Conditions

BOD + O

2

CO

2

+ increased cell mass

NO

3 Organic NNH4NO2 NO3 N2 Aerobic ConditionsPincreased cell massAnaerobic/Aerobic ConditionsAlumorganic sludgeinorganic sludgeSlide13

Suspended

Growth Activated Sludge Processes Requires Energy

13

Use forced air suspension of biological sludge to reduce BOD

Largest expense for this process is the electrical energy requiredSlide14

14

Anoxic Basin

Sedimentation

Final Clarification

Aerobic Basin

Activated

Sludge Process StagesSlide15

Anaerobic

Sludge Digestion Reduces

Solids -

Makes Methane15

Anaerobic sludge digestors produce methane

(65% CH

4

- 35% CO

2

)

On-site electricity is produced with the methane 50% of plant power (2.2MW)Slide16

Liquid

Process Train

16

Aeration

Sedimentation

Sedimentation

Solids Handling

N

org

NH

3+NH3+  NO2NO2  N2MixingC6H14  Biomass + CO2Slide17

Exemplary

Process Stages

17

Modified Ludzack-Ettinger (MLE Process)

A

2

O

Bardenpho

RAS = Return Activated Sludge

WAS = Waste Activated SludgeSlide18

18

CH

4

+ CO

2

C

6

H

14

+ H

2

O

Anaerobic Fermentation (30 days)Aeration Blowers6.6 MWDisposal or Reuse (150 t/day)Diesel GeneratorsBiosolidsCentrifugesPNMSolids Handling Involves Anaerobic ConditionsSlide19

A Typical

Process :

19

NH

3

+

Settling & Aeration

Fermentation

River

Sewers

CO

2

N2CH4MicrobesCompostingCO2H2OH2O+C+N+SO2HumusHeatPowerH2SCO2HOCl-SO2(Biosolids)Slide20

Water

Reuse Often Uses Membrane Bioreactor

with Submerged Membranes

20

Uses submerged hollow fiber membranes

High Solids Retention Time membrane bioreactor

Conventional activated sludge plant

MBR membrane cassetteSlide21

21

Screens

Anoxic

Aerobic

Submerged Membrane

Membrane

Bioreactors Offer Small Size

,

High Rate

of

Reaction

for

Satellite

WWSlide22

Membrane

Separation Spectrum

22

Source: Zenon MembranesSlide23

Screen

Before Membrane Bio Reactor

23Slide24

Kubota MBR

Pilot Plant

24Slide25

25

Raw

Feed

and MBR P

roductSlide26

26

RO treated water is better than most surface water sources

Reverse

Osmosis After

MBR

Makes Water Suitable

for

Groundwater RechargeSlide27

Hyperion Wastewater Plant

Los Angeles 450

mgd

27

10% of discharge from this plant is sent to microfiltration plant to purify for groundwater injectionSlide28

West Basin Microfiltration Plant

(35

mgd from Hyperion)

28

Submerged microfiltration for treated wastewater effluentSlide29

The

Final Step

is Disinfection and

Discharge (No Residual Free Chlorine)29

Chlorination to kill the remaining pathogens

Cl

2

HOCl

Dechlorination

to remove chlorineSO2 + HOCl + H2O  HCl + H2SO4SO2 + NH2Cl + 2H2O  NH4Cl + H2SO4UV radiation reduces chemical needs and chlorinated productsSlide30

Effect of

Wastewater

on Disinfection

30

Chlorine

Ozone

UV

BOD,COD,TOC

Chlorine demand

Ozone demand

Little effect

Oil and grease

Chlorine demandOzone demandMay block lightNitriteForms NDMAOxidized No effectNitrateForms chloraminesReduce O3effectivenessNo effectIron and ManganeseOxidizedOxidizedMay block lightForms disinfection byproductsYesYes, but nonchlorinatedNoSource: Wastewater Engineering- Metcalf & EddySlide31

Satellite and

On-site Waste Disposal

Satellite facilities are mid scale sewage treatment plants that treat waste near the point of generation

LagoonsAeration ditchesTrickling filters

Membrane bioreactor

On-site

waste disposal is septic tank system with drain field

Provides low cost alternative

Can be very effective

Need little maintenance (but maintenance is important)

31