PPT-Aromatic Electrophilic Substitution Reactions

Dr Geeta Singh Assistant Professor Department of Chemistry DDU Gorakhpur University Gorakhpur Introduction Key terms General reaction for aromatic electrophilic substitution Common reactions of AES. Benzene is aromatic: a cyclic conjugated compound with 6 . . electrons. Reactions of benzene lead to the retention of the aromatic core. Types of Reactions. Electrophilic. substitution. Diazonium. 15-8. Benzene undergoes substitution reactions with electrophiles.. Electrophiles attack benzene by substituting for a hydrogen atom, not addition to the ring.. Under the conditions of this type of reaction, ordinary non-aromatic conjugated polyenes would polymerize rapidly.. Most common reactions for aromatics involve replacement of ring . hydrogens. by other atoms or groups . (substitution reactions). Mechanism of Electrophilic Aromatic Substitution Reactions. Electrophile. Newehy. Chemistry Department, College of Science, King Saud University. http://fac.ksu.edu.sa/melnewehy. Aromatic . Compounds. The Structure of Benzene Ring. - . Benzene. is . the . parent hydrocarbon of . Reactions of Arenes. Reactions involving the ring. A. Reduction. a. Catalytic hydrogenation (Chapter 11.4). b. Birch reduction (Chapter 11.11). B. . Electrophilic. aromatic substitution (Chapter 12). 240 . Chem. 1. The expressing . aromatic compounds . came to mean . benzene. . and derivatives of benzene. .. . Structure of Benzene: Resonance Description. C. 6. H. 6. It contains a six-membered ring and three additional degrees of unsaturation.. Fall . 2018. Schedule of . day. PPE . and Pre-lab check . – at the door. Quiz. Recitation. Safety. Put bags away. Goggles. Gloves. Lab Coat. Lab part 1. IR . Review. Lab part 2. Due . Dates. . Today. MICHAEL FARADAY (1791-1867). first person to isolate and identify benzene. early benzene uses:. - . decaffeinate . coffee. - antiknock additive . in gasoline. - solvent in chem rxns. now we know benzene is a carcinogen!. HL only . Syed . Arshad. . Mushtaq. Chemistry Teacher . Australian School of Abu Dhabi . Nucleophilic substitution reactions. Learning outcomes . Understand:. Nucleophilic. . unimolecular. substitution reactions are represented by S. UNIT I : Benzene & its derivatives. PART -I. Electrophilic Aromatic . Substitution Reactions. Aromatic compounds (Benzene) . undergo electrophilic aromatic substitution (. EAS).. Arene . (. Ar. -H) is the generic term for an aromatic . Reactions involving the ring. A. Reduction. a. Catalytic hydrogenation (Chapter 11.4). b. Birch reduction (Chapter 11.11). B. . Electrophilic. aromatic substitution (Chapter 12). C. . Nucleophilic. Objective. To know about . electrophilic. substitution reactions. Success criteria. Understand . the mechanism of the . electrophilic. substitution reactions of . benzene. Understand this for . halogenation. The Discovery of Benzene. Benzene was discovered in . 1825. by the English chemist . Michael Faraday . (Royal Institution). Faraday called this new hydrocarbon “. bicarburet. of hydrogen”.. Faraday isolated benzene from a compressed illuminating gas that had been made by . Arenium Ion Mechanism . Some Aromatic Electrophilic Substitution Reactions Viz. Nitration, Sulphonation, Halogenation, Friedel- Crafts Reaction. Orientation & Reactivity in Mono Substituted Benzene.