ITW Devcon30 Endicott StDanvers MA 01923Emergency telephone number 800 4249300CHEMTREC Other Calls 978 7771100EMERGENCY INFORMATION DUCO CEMENTPrinted 1292004 2 COMPOSITIONINFO ID: 823741
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MANUFACTURERITW Devcon30 Endicott St.Da
MANUFACTURERITW Devcon30 Endicott St.Danvers, MA 01923Emergency telephone number (800) 424-9300(CHEMTREC): Other Calls: (978) 777-1100EMERGENCY INFORMATIONDUCO CEMENTPrinted: 1/29/20042. COMPOSITION/INFORMATION ON INGREDIENTS"TLV" means the Threshold Limit Value exposure (eight-hour, time-weighted average, unless otherwise noted) established by the American Conference of Governmental Industrial Hygienists. "STEL" indicates a short-term exposure limit. "PEL" indicates the OSHA Permissible Exposure Limit."n/e" indicates that no exposure limit has been established. An asterisk (*) indicates a substance whose identity is a trade secret of our supplier and unknown to us.Last revised: 08/14/02HAZARDOUS CONSTITUENTS Emergency OverviewDANGER! Extremely Flammable. Eye, skin and respiratory irritant. May cause central nervous system effects.3. HAZARDS IDENTIFICATIONAppearance, form, odor:Clear to amber liquid with solvent odor.6245This product appears in the following stock number(s)ACGIH CAS No.Weight percentOSHAPEOther 1-methoxy-2-propanol acetate108656n/en/e100 ppm(AIHA-1000 ppm500ppm750 ppm(Canada)Cellulose Nitrate9004700n/en/e400 ppm400 ppmIPA400 ppm(Canada)2 mg/m^32 ppm2 ppm(Canada)Exposure limits1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONTradename: DUCO CEMENTGeneral use:Adhesive.Chemical family: Nitrocellulose solutionMSDS0619ITW DevconMaterial Safety Data Sheet Page 1Part No.: 6245PNUnusual fire and explosion hazards: Dry nitrocellulose resin is extremely flammable and burns explosively. Avoid friction and impact on dry resin.Ca
rbon dioxideDry chemicalFoamAlcohol f
rbon dioxideDry chemicalFoamAlcohol foamExtinguishing media:Flash Point (°F): - 4Method: TCCExplosive limits in air (percent) -- Lower: 0.6Special firefighting procedures: Keep containers in storage cool with water to prevent pressure build up and bursting. Self contained breathingapparatus should be worn to protect firefighters from toxic degradation products.5. FIRE FIGHTING MEASURESFirst aid for skin: Wash with soap and water. If irritation persists, see a physician.First aid for ingestion: Do not induce vomitting. Seek medical assistance.First aid for inhalation: Remove victim to fresh air. If not breathing, give artificial respiration. Get prompt medical attention.4. FIRST AID MEASURESFirst aid for eyes: Flush with water for 15 minutes and seek medical assistance.Medical conditions which may be aggravated by exposure: None known Effects of chronic overexposure: Prolonged exposure to vapor concentrations in excess of tlv or through prolonged absorption through skin may causedamage to blood, kidneys and nervous system.Other effects:See Section 11.OSHA regulated: NoACGIH: NoNational Toxicology Program: NoInternational Agency for Research on Cancer: NoCancer-suspect constituent(s) : NoneCarcinogenicity --Eyes: Severe eye irritant.Inhalation:Headache, lethargy, drowsiness, weakness, difficulty walking, personality change, poor appetite, nausea and weightloss.Headache, lethargy, drowsiness, weakness, difficulty walking, personality change, poor appetite, nausea and weightloss.Potential health effectsSkin: Irritation, evidenced by drying and cracking.
Symptoms of acute overexposure:Skin con
Symptoms of acute overexposure:Skin contactSkin absorptionEye contactInhalationPrimary routes of exposure:ITW DevconMaterial Safety Data Sheet Page 2Part No.: 6245PNHazardous products of combustion:Oxides of carbon, Oxides of nitrogen and other toxic gases.Containment: Dike, contain and absorb with clay, sand or other suitable non-combustible material. Cleanup: For large spills, pump to storage/salvage vessels. Soak up residue with an absorbent such as clay, sand, or othersuitable material and dispose of properly (RCRA hazardous waste). Special procedures: Prevent spill from entering drainage/sewer systems, waterways, and surface waters. Use non-sparking toolsStorage: Keep in a cool place, without direct exposure to sunlight. Keep container tightly closed and otherwise in accordancewith NFPA regulations. Maintain air space in storage containers. Other engineering controls : Keep container tightly closed. Observe label precautions. Have emergency eye wash and safety shower present.Skin protection: Chemical resistant gloves and apron are recommended.Respiratory protection: Use a NIOSH approved cartridge respirator for vapor concentrations above the tlv.Personal protective equipmentEye and face protection: Safety glasses with side shields or full face shield.8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering controlsVentilation : Mechanical or supplemental local exhaust may be required to keep vapor concentrations below tlv.7. HANDLING AND STORAGEHandling precautions: EXTREMELY FLAMMABLE! Do not breathe vapor or mist. Do not get in eyes, on skin or c
lothing. Wash thoroughlyafter handling.
lothing. Wash thoroughlyafter handling. Close container after each use. Ground container when pouring. Keep away from heat, flame orsparks. Use non-sparking tools. Wear appropriate respiratory protection against decomposition products whenwelding the cured material. Avoid friction and impact upon the cured material (nitrocellulose).Spill control: Avoid personal contact. Eliminate ignition sources. Ventilate area.6. ACCIDENTAL RELEASE MEASURESITW DevconMaterial Safety Data Sheet Page 3Part No.: 6245PNAcute dermal effects: No data available.LD50 (rabbit): No data available.Acute inhalation effects: No data available.LC50 (rat): No data available.Exposure: hours. 9. PHYSICAL AND CHEMICAL PROPERTIESMelting point (°F): n/dBoiling point (°F): 132-405Vapor density (air = 1): �1Evaporation rate (butyl acetate = 1): slower than etherSpecific gravity: 0.9Solubility in water: slightpH (5% solution or slurry in water): n/dPercent volatile by volume: 80-90VOC (grams/liter): Percent solids by weight: 10-20Vapor pressure (mmHg): 185 at 68 °FHazardous products of decomposition:Oxides of carbon, Oxides of nitrogen and other unknown organic combustion products.Conditions under which hazardous polymerization may occur: NoneIncompatible materials: Strong oxidizers, acids, bases and amines.Eye irritation:No data availableSubchronic effects: No data available.Other chronic effects: No data available.Carcinogenicity, teratogenicity, and mutagenicity: No data available.Acute oral effects: No data available.LD50 (rat): No data available.11. TOXICOLOGICAL INFORMATI
ON10. STABILITY AND REACTIVITYThis mate
ON10. STABILITY AND REACTIVITYThis material is chemically stable. Conditions to avoid : Heat, flames and other sources of ignition. Avoid allowing unmodified resin to become dry, avoid impact and friction.Hazardous polymerization will not occur.Toxicological information on hazardous chemical constituents of this product:MSDS0619ITW DevconMaterial Safety Data Sheet Page 4Part No.: 6245PNMobility and persistence: No data available.Environmental fate: No data available.14. TRANSPORT INFORMATIONProper shipping name: AdhesivesTechnical name : N/AHazard class : 3UN number: 1133Packing group: IIEmergency Response Guide no.: 128IMDG page number: N/AOther: *Depending upon the size and type of container, this material may be reclassified as "Consumer Commodity,ORM-D" for shipments within the United States, or "Limited Quantity" elsewhere. Refer to the appropriateregulation.LtdQty : YORM-D : Y13. DISPOSAL CONSIDERATIONSWaste management recommendations: Do not dispose of in a landfill. Incineration is the preferred method of disposal.Please see also Section 15, Regulatory Information.12 ECOLOGICAL INFORMATIONEcotoxicity: No data available.ConstituentOral LD50(rat) Dermal LD50(rabbit)Inhalation LC504hr, (rat)1-methoxy-2-propanol acetaten/d5800 mg/kg20 mL/kg70852 mg/m^3Cellulose Nitrate�5 g/kgn/d5045 mg/kg12.8 g/kg22627 ppmCamphor'n/d' = 'not determined'MSDS0619ITW DevconMaterial Safety Data Sheet Page 5Part No.: 6245PNFor purposes of SARA Section 312 hazardous materials inventory reporting, the following hazardclasses apply to this material:- Immediate he
alth hazard -- Delayed health hazard --
alth hazard -- Delayed health hazard -- Fire hazard -The information and recommendations in this document are based on the best information available to us at the time of preparation, but we make no other warranty, express or implied, as to its correctness or completeness, or as to the results of reliance on this document. Hazardous Materials Identification System (HMIS) ratings:Flammability 3Reactivity 216. OTHER INFORMATIONConstituentExtremely Hazardous* ToxicCERCLA RQ (lbs)TSCA 12B ExportNotification1-methoxy-2-propanol acetateNo 100.0Not requiredAcetoneCellulose NitrateNo 0.0Not requiredIsopropanol 100.0Required 0.0Not requiredRegulatory status of hazardous chemical constituents of this product:*Consult the appropriate regulations for emergency planning and release reporting requirements for substances on the SARA Section 301 Extremely Hazardous Substance list. **Substances for which the "Toxic Chemical" column is marked "Yes" are on the SARA Section 313 list ofToxic Chemicals, for which release reporting may be required. For specific requirements, consult the appropriate regulations.15. REGULATORY INFORMATIONU.S. Federal RegulationsThe following RCRA code(s) applies to this material if it becomes waste:D001All ingredients of this product are listed, or are exempt from listing, on the TSCA inventory.TSCAWHMIS hazard class(es) : B2Canadian regulationsAll components of this product are on the Domestic Substances List.Regulatory notes: Coating VOC: 375 g/l; Material VOC: 74 g/lMSDS0619ITW DevconMaterial Safety Data Sheet Page 6Part No.: 62