UVvis observations of the troposphere Lecture at the PANDA summer school 2015 Bremen August 25 2015 Andreas Richter Institute of Environmental Physics University of Bremen Bremen Germany ID: 777787
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Slide1
1
Satellite Remote
Sensing I
UV/vis observations of the troposphere
Lecture at the
PANDA summer school 2015
Bremen, August 25, 2015
Andreas Richter
Institute of Environmental Physics
University of Bremen
Bremen, Germany
(
richter@iup.physik.uni-bremen.de
)
Slide22
Overview
What is Remote Sensing?
How can trace gases be detected using UV/vis remote sensing from satellite ?
What are typical light paths for UV/vis satellite observations?
What are the sensitivities of the measurements?
What needs to be considered when comparing satellite data to other observations / to models?
Some examples of UV/vis instruments & applications
Slide3Who am I?Leading DOAS group at Institute of Environmental Physics, University of Bremen, head: Prof. John Burrows.Working on all aspects of UV/vis remote sensingInstruments (ground, airborne, satellite)Radiative transferRetrieval algorithmsData interpretationSome atmospheric topics I‘m interested inNOx emissions, distributionsand chemistryEmission changes / trendsHalogen chemistry inpolar regions3
www.doas-bremen.de
Slide4Basic Principles of Remote Sensing“Remote sensing is the science and art of obtaining information about an object, area, or phenomenon through the analysis of data acquired by a device that is not in contact with the object, area, or phenomenon under investigation“ (Lillesand and Kiefer 1987)“The art of dividing up the world into little multi-coloured squares and then playing computer games with them to release unbelievable potential that's always just out of reach.” (Jon Huntington, Commonwealth Scientific and Industrial Research Organisation Exploration, Geoscience, Australia)
4
Slide5Schematic of Remote Sensing Observation
5
Validation
Sensor
Measurement
Object
Changed Radiation
Radiation
Data Analysis
Final Result
A priori information
Forward Model
Slide6The Electromagnetic Spectrumnearly all energy on Earth is supplied by the sun through radiationwavelengths from many meters (radio waves) to nm (X-ray) short wavelength = high energyradiation interacts with atmosphere and surfaceabsorption (heating, shielding)excitation (energy input, chemical reactions)re-emission (energy balance)
6
Slide7Wavelength Ranges in Remote SensingUV: some absorptions + profile information aerosols vis: surface information (vegetation) some absorptions aerosol information IR: temperature information cloud information water / ice distinction many absorptions / emissions + profile information
MW:
no problems with clouds
ice / water contrast
surfaces
some emissions + profile information
7
Slide8Wavelength Ranges in Remote SensingUV: some absorptions + profile information aerosols vis: surface information (vegetation) some absorptions aerosol information IR: temperature information cloud information water / ice distinction
many absorptions / emissions
+ profile information
MW:
no problems with clouds
ice / water contrast
surfaces
some emissions + profile information
8
Slide9How are trace gases detected in the UV/vis?Method used is Absorption SpectroscopyRadiation coming from the sun is attenuated as it passes through the atmosphereThe wavelength dependence of the absorption is molecule specificThe magnitude of the absorption depends on the amount of absorber along the light pathThis is described by Lambert Beer‘s law:ρ = density of absorber λ = wavelength σ = absorption cross-section of absorber9
Slide10Atmosphere
Absorption on the ground
Scattering / Reflection on the ground
Emission from
the ground
Scattering from a cloud
Transmission through a cloud
Transmission through a cloud
Scattering / reflection on a cloud
Scattering within a cloud
Cloud
Emission from
a cloud
Absorption
Scattering
Aerosol / Molecules
Emission
Radiative
Transfer in the
Atmosphere
passive sensor, UV / visible / IR
10
Slide11Atmosphere
Absorption on the ground
Scattering / Reflection on the ground
Scattering from a cloud
Transmission through a cloud
Transmission through a cloud
Scattering / reflection on a cloud
Scattering within a cloud
Cloud
Absorption
Scattering
Aerosol / Molecules
Radiative Transfer in the
Atmosphere
passive sensor, UV / visible
11
Slide12Radiative transfer in the atmosphereThe change of radiation along the light path: Solution is complex, in particular in spherical geometryComplications are polarisation, inealasic
scattering
, angular
dependent surface
reflectivity
,
complex
phase functions of aerosols and cloud particlesEven
if
only
one
scattering
event
is considered,
manypossible light paths need tobe
included 12
Slide13Retrieval ApproachIn general, a retrieval always consists of Solutions are for example using the Optimal Estimation methodOften, several pieces of information can be extracted such as concentrations in two layers A widely used method which is fast and simple is to separate the retrieval of the amount of absorber found in the measurement andThe length of the light pathThis is often done using the Differential Optical Absorption Spectroscopy (DOAS) 13
Measurement
Forward Model
A priori
Parameters
Simulation
OK?
Slide1414
DOAS
equation I
The intensity measured at the instrument is the
extraterrestrial
intensity weakened by absorption, Rayleigh scattering and Mie scattering along the light path:
absorption by all trace gases j
extinction by Mie scattering
extinction by Rayleigh scattering
unattenuated intensity
integral over light path
scattering efficiency
exponential from Lambert Beer’s law
Slide1515
DOAS equation
II
If the absorption cross-sections do not vary along the light path, we can simplify the equation by introducing the slant column
SC.
Slant Column
=
absorber
concentration
integrated
along
light
path
Slide1616
DOAS equation
III
As Rayleigh and Mie scattering efficiency vary smoothly with wavelength, they can be approximated by low order polynomials. Also, the absorption cross-sections can be separated into a high (“differential”) and a low frequency part, the later of which can also be included in the polynomial:
polynomial
slant column
differential cross-section
Slide1717
DOAS equation
IV
Finally, the logarithm is taken and the scattering efficiency included in the polynomial. The result is a linear equation between the optical depth, a polynomial and the slant columns of the absorbers. by solving it at many wavelengths (least squares approximation), the slant columns of several absorbers can be determined simultaneously.
DOAS retrieves absorber amount along light path – but what is the light path?
Slide18Satellite Viewing GeometriesDirect Sun / MoonLot‘s of lightSimple geometryVertical resolutionNo tropospheric observationsLow spatial resolutionFew measurementsLimb scattered lightVertical resolutionMany measurementsComplex light pathNo tropospheric observationsLow spatial resolutionNadir scattered light
High spatial resolution
Sensitivity to the troposphere
Little vertical resolution
Complex light path
18
Slide19Typical light paths: UVDark surfaceStrong Rayleigh scatteringMost photons are scattered above absorption layer=> Low sensitivity to BL signals!
19
sensitivity
altitude
Slide20Typical light paths: visibleBrighter surfaceSignificant Rayleigh ScatteringMany photons are scattered above absorption layer=> Reduced sensitivity to BL signals!
20
sensitivity
altitude
Slide21Bright surface (snow, ice): UV and visibleSurface reflection dominatesMultiple scattering in surface layer=> Enhanced sensitivity to BL signals!
21
sensitivity
altitude
Slide22Typical light paths: NIRBright surface (except for oceans)Negligible Scattering=> Very good sensitivity to BL signals!
22
sensitivity
altitude
Slide23Typical light paths: visible with cloud
23
sensitivity
altitude
Slide24Typical light paths: visible with cloudEven if cloud covers only part of the scene, most photons are reflected thereSensitivity below cloud is reducedSensitivity above cloud is enhanced=> Cloud fraction and cloud height are important!
24
sensitivity
altitude
Slide25Tropospheric sensitivity of UV/vis observationsWavelengthSensitivity decreases towards UVVertical profile of absorberSensitivity decreases to surface unless it is very brightCloudsSensitivity below clouds is close to 0Thin clouds (or aerosols) can increase / decrease sensitivitySurface albedoSensitivity increases with surface reflectanceSolar zenith angleLower sun increases sensitivity geometrically, at least in mid and upper troposphereLower sun decreases sensitivity to the surface layers25
Slide26Vertical sensitivity of satellite measurementsThe sensitivity of the satellite measurements depends on the altitude of the absorbing layerThis is often expressed in the form of weighting functions which give the sensitivity of the signal as function of altitude of the trace gas layerAs the vertical distribution can usually not be (completely) determined from the measurements, a priori information is needed in the retrievalThe dependence of the retrieved quantity on the real atmospheric profile depends on both, the sensitivity of the measurements and the assumptions made in the a prioriThis is often expressed as averaging kernels which describe the sensitivity of the retrieved quantity on the amounts of trace gas in the different altitudes in the atmosphereComparison of satellite retrievals with other measurements are only meaningful if the averaging kernels are accounted for
26
Slide27Satellite Orbits(Near) Polar Orbit:orbits cross close to the poleglobal measurements are possiblelow earth orbit LEO (several 100 km)ascending and descending branchspecial case: sun-synchronous orbit:overpass over given latitude always at the same local time, providing similar illuminationfor sun-synchronous orbits: day and night branchesGeostationary Orbit:satellite has fixed position relative to the Earthparallel measurements in a limited area from low to middle latitudes36 000 km flight altitude, equatorial orbit
http://www2.jpl.nasa.gov/basics/bsf5-1.htm
http://www.ccrs.nrcan.gc.ca/ccrs/learn/tutorials/fundam/chapter2/chapter2_2_e.html
27
Slide28Considerations for use of UV/vis satellite dataSpatial resolutionSatellite data is coarse in comparison to in-situ observations but finer than global models => averaging is neededSpatial samplingDue to orbital pattern, scan and cloud gaps, only part of the globe is covered by observations every day=> other data must be sampled accordinglyTime of overpassSun sun-sychronous orbits have overpasses at a constant local time => other data needs to be interpolated to that timeVertical resolutionSatellite data have coarse or no vertical resolution=> other data must be integrated to become comparableImpact of a priori
The vertical sensitivity of the retrievals (averaging kernel) needs to be considered
Summary: We should always compare apples to apples, not oranges!
28
Slide29Effect of Spatial Resolution: Example NO2
29
For species with short atmospheric life time, horizontal variability is large
Spatial resolution of sensor is relevant for interpretation
Spatial resolution also influences cloud fraction
Time of overpass may also play a role!
OMI: 13:30 LT
Slide30Examples30
Slide31TOMSInstrument: UV discrete (6) wavelengths grating spectrometerOperational: October 1978 - 2004Spatial resolution: 50 x 50 km2Global coverage: 1.5 daysSpecies: O3, SO2
31
Slide32TOMS: Ozone columns Large scale tropospheric ozone patterns retrieved using the cloud slicing methodDuring El Nino year, clear ozone maximum over IndonesiaOrigins: photochemical smog from biomass burning and change in circulation pattern
32
Ziemke, J. R et al., (2001), “Cloud slicing”: A new technique to derive upper tropospheric ozone from satellite measurements,
J. Geophys. Res.
, 106(D9), 9853–9867
October
1996
October
1997
October
1998
Slide33GOME / GOME-2Instrument: 4 channelUV/vis grating spectrometerOperational on ERS-2 7.1995 – 6.2003 - 2011Spatial resolution 320 x 40 km2Global coverage: 3 daysSpecies: O3, NO2, HCHO, CHOCHO, BrO, IO, SO2, H2O
33
GOME-2 A
on
MetOp
A since
1.2007
80 x 40
km
2
1.5
days
GOME-2 B
on
MetOp
B since 1.2013
80 x 40 km
2
1.5 days
40
x 40
km
2
3 days
Slide3434
Satellite NO
2
Trends
NO
2
reductions in Europe and parts of the US
strong increase over China
consistent with significant NO
x
emission changes
7 years of GOME satellite data
DOAS retrieval + CTM-stratospheric correction
seasonal and local AMF based on
1997 MOART-2 run
cloud screening
1996 - 2002
GOME annual changes in tropospheric NO
2
A. Richter et al.,
Increase
in
tropospheric
nitrogen
dioxide
over
China
observed
from
space
, Nature, 437 2005
Slide35NO2 Trends: Comparison with bottom up estimatesOverall pattern in emission data base is correctIncrease in China is underestimatedIncrease in India and Middle East is overestimatedDecrease in Europe / US is underestimated
35
GOME and SCIAMACHY
EDGAR v4.2
Hilboll, A., Richter, A., and Burrows, J. P.: Long-term changes of tropospheric NO
2
over megacities derived from multiple satellite instruments
, Atmos. Chem. Phys.
13, 4145-4169, doi:10.5194/acp-13-4145-2013, 2013
Slide36Until 2011, there was continuous increase in NO2After two years of stagnation, 2014 saw a large decreaseeconomic slow down? Improved technology?Switch in fuels used?Other factors?
Satellite NO
2
Trends above Central Eastern China
Slide37SCIAMACHYInstrument: 8 channel UV/vis/NIR grating spectrometernadir, limb + occultation measurementsOperational on ENVISAT 8.2003 – 4.2012Spatial resolution (30) 60 x 30 km2Global coverage: 6 daysSpecies: O3, NO2, HCHO, CHOCHO, BrO, IO, SO2, H2O, CH4, CO2, CO
37
scanner modules
telescope
pre-disperser
UV channels 1-2
Vis channels 3-4
NIR channels 5-6
SWIR channels 7-8
www.sciamachy.de
Slide38Buchwitz et al., ACP, 2007; Schneising et al., ACP, 2008Buchwitz et al., personal communication, 2014SCIAMACHY: CO
2
in the Northern Hemisphere
38
Detection of annual cycle
Detection of year-to-year increase
Detection of spatial variability
Not yet accurate enough for Kyoto monitoring on country level
SCIAMACHY and GOSAT: CO
2
Slide39OMIInstrument: UV/vis imaging grating spectrometer (push-broom)Operational on Aura since October 2004Spatial resolution: up to 13 x 24 km2Global coverage: 1 daySpecies: O3, NO2, HCHO, CHOCHO, BrO, SO2
39
www.
knmi
.nl/
omi
/
Slide40OMI: SO2 columnsSO2 signals from volcanoes in Ecuador and Columbia Clear signature of Peruvian copper smeltersVery large sources of local pollutionEffect of (temporary) shut down and (permanent) implementation of emission reductions (H2SO4 production) can be monitored
40
Carn, S. A., et al., t (2007), Sulfur dioxide emissions from Peruvian copper smelters detected by the Ozone Monitoring Instrument, Geophys. Res. Lett., 34, L09801, doi:10.1029/2006GL029020.
9.2004 – 6.2005
Slide41Summary and ConclusionsSatellite observations of tropospheric composition in the UV/vis and NIR provide consistent global datasets for many species including major air pollutants such as O3, CO, NO2, and HCHOThe measurements are averaged horizontally and vertically which makes them difficult to compare to point measurementsRemote sensing in an indirect method that necessitates use of a priori information in the data retrieval which has an impact on the resultsVisible and NIR measurements provide good sensitivity to the boundary layerIn spite of the relative large uncertainties involved in satellite remote sensing , they provide a unique source of information on the composition of the troposphere
41
Slide42What is the future of UV/vis satellite measurements of tropospheric trace gases?Satellite measurements will be improved byBetter spatial resolution (Sentinel 5P, Sentinel 5, CARBONSAT)Better temporal resolution (geostationary observations Sentinel 4)Better coverage of species and vertical resolution (extension of the wavelengths covered (from UV to IR)High vertical resolution (active systems)The usefulness of satellite data will be improved by better integration with other measurementsSatellite data will be strongly integrated in atmospheric models
42
Slide43Active measurements: CALIOP aerosol
43
http://www-calipso.larc.nasa.gov/
Slide44Thank you for your attention
and
questions
please!
http://www.animationlibrary.com/animation/25494/Alarm_jumps/
44
www.doas-bremen.de