PPT-Chapter 11: Amines and Related Nitrogen Compounds

The painkiller morphine is obtained from opium the dried sap of unripe seeps of the poppy P apaver somniferum Amines are relatives of ammonia and are usually classified as primary secondary or tertiary. Chehimi Iluminada Gallardo Jean Pinson and Neus Vila Departament de Qu mica Universitat Auto noma de Barcelona Bellaterra Espan a ITODYS Universite Paris 7Denis Diderot 75005 Paris France and Laboratoire dElectrochimie Mole culaire Universite Paris Histamine. Amines. Amides. Amino acid. P. eptides. Comparison of NH. 3. to Amines . 15.1 Amines. pyramidal. VSEPR?. Classification of Amines. Amines are classified by the number of carbons directly bonded to the nitrogen atom: . Amine nomenclature. diisopropylamine. pyrrole. nicotine. histamine. pyrrolidine. Formation of amines. triethylamine. Mechanism for LAH reduction of amides. 1-methylpiperidine. One equivalent . SN2 is faster the more R groups on N. Ch19 Amines( Page 1 Amines Amines are derivatives of ammonia with one or more alkyl groups bonded to the nitrogen . Amines can be classified as primary , secondary or tertiary , meaning one , t Chapter 16. Amines. Amines are nitrogen-containing compounds. Structure and Classification. Amines are classified as 1°, 2°, or 3° depending on the number of carbon groups bonded to nitrogen.. Aliphatic amine:. A heterocyclic amine is a cyclic organic compound that consists of a ring of five or six atoms, of which one or two are nitrogen atoms.. The aroma of pepper is due to . piperidine. , a heterocyclic amine. . Instructor. Dr. Upali Siriwardane (Ph.D. Ohio State) . E-mail: upali@chem.latech.edu . Office. : 311 Carson Taylor Hall ; Phone: 318-257-4941;. Office Hours. : . MWF 8:00 . am - . 10:00 . am; . Amines are derivatives of ammonia molecules that contain a nitrogen atom bonded to one or more alkyl groups on each molecule.. . Many amines have strong, unpleasant odours.. . ex. putrescine. cadaverine. Brønsted. and Lewis bases. Amines are basic because they possess a pair of unshared electron create an electron density around the nitrogen atom.. Amine are more basic than water and less basic than hydroxide ion:. Book chapter: 14. Pages: 472-511. Carbon atom of a carbonyl group is attached to a hydroxyl group forming a carboxyl group. As functional group – attached to an alkyl group or an aromatic group. IUPAC names. * up to 8 carbon atoms in the main chain, with sides chains limited to a maximum of 2 carbon atoms. * one or more amine groups. Amines contain one or more amino functional group (-NH. 2. ). Naming amines follows the alkane naming conventions, adding ‘amine’ as the suffix.. Indigofera tinctoria. .. Learning . Goal . Write the common names for amines; draw the condensed structural formulas when given their names. Classify amines as primary . (1. °. ), . secondary . (. 2. Amines are classified as primary, secondary, or tertiary based upon the number of carbon-containing groups that are attached to the nitrogen atom. Those amine compounds that have only one group attached to the nitrogen atom are primary, while those with two or three groups attached to the nitrogen atom are secondary and tertiary, respectively. Amines. may be considered as derivatives of ammonia, NH. 3. , in which . an alkyl or aryl group. has replaced one or more of the . hydrogen. . . Those . amines . that carry only alkyl groups are classified as .