APES – UNIT 9 GLOBAL IMPACT ACID RAIN *a result
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APES UNIT 9 GLOBAL IMPACT ACID RAIN a result of pollution released from -burning fossil fuels -smoke stacks -vehicle exhausts -wood burning -smelting metals ACID RAIN COMPOSITION MOSTLY SULFUR OXIDES (SO3) AND NITROGEN OXIDES (NO2) MIXED
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01
APES – UNIT 9 GLOBAL IMPACT<br>
02
ACID RAIN *a result of pollution released from
-burning fossil fuels
-smoke stacks
-vehicle exhausts
-wood burning
-smelting metals<br>
-burning fossil fuels
-smoke stacks
-vehicle exhausts
-wood burning
-smelting metals<br>
03
ACID RAIN COMPOSITION MOSTLY SULFUR OXIDES (SO3) AND NITROGEN OXIDES (NO2) MIXED
WITH WATER AND ATMOSPHERIC OXYGEN TO FORM ACIDS
SO2 + H2O H2SO3 (sulfurous acid)
H2SO3 + ½ O2 H2SO4 (sulfuric acid)
OR
NO + ½ O2 NO2 (nitrogen dioxide)
2NO2 + H2O HNO2 + HNO3 (nitrous acid and nitric acid)<br>
WITH WATER AND ATMOSPHERIC OXYGEN TO FORM ACIDS
SO2 + H2O H2SO3 (sulfurous acid)
H2SO3 + ½ O2 H2SO4 (sulfuric acid)
OR
NO + ½ O2 NO2 (nitrogen dioxide)
2NO2 + H2O HNO2 + HNO3 (nitrous acid and nitric acid)<br>
04
ACID DEPOSITION *ACID RAIN DEPOSITED ON EARTH IS HIGHLY DILUTED *ACID RAIN IS SLIGHLY ACIDIC WITH pH 5.6 – 5.7 because
water reacts with the CO2
*note: pH scale is LOGARITHMIC = each whole pH value below
7 is 10X more acidic than the next value<br>
water reacts with the CO2
*note: pH scale is LOGARITHMIC = each whole pH value below
7 is 10X more acidic than the next value<br>
05
ACID RAIN SIGNIFICANCE 1.causes sink holes due to acid dissolving limestone
2.dissolution= dissolves most building structures
3.affect water sources by increasing acidity
4.affects leaves by damaging waxy covering which disrupts leaf gas exchange
5.causes NUTRIENT LEACHING: metals (lead, zinc, copper, aluminum) in soil react with acid rain adding Hydrogen ions which in turn react with minerals (calcium, magnesium, potassium) and prevent them from being absorbed<br>
2.dissolution= dissolves most building structures
3.affect water sources by increasing acidity
4.affects leaves by damaging waxy covering which disrupts leaf gas exchange
5.causes NUTRIENT LEACHING: metals (lead, zinc, copper, aluminum) in soil react with acid rain adding Hydrogen ions which in turn react with minerals (calcium, magnesium, potassium) and prevent them from being absorbed<br>
06
ACID RAIN PREVENTION SWITCH TO FUELS WITH ZERO OR LOW SULFUR
USE SMOKE STACK SCRUBBERS
USE CATALYTIC CONVERTERS IN CARS
REDUCE IT IN WATER WAYS BY ADDING LARGE AMOUNTS OF SODA ASH (LIME WATER) WHICH RAISES ALKALINITY **CLEAN AIR ACT (1990) = regulates amount of SO2 & Nox that are released form industrial plants which go by the NAAQS (National Ambient Air Quality Standards) http://acidrainmix.weebly.com/uploads/2/5/2/7/25273212/771105_orig.jpg ABOUT SMOKE STACK SCRUBBERS<br>
USE SMOKE STACK SCRUBBERS
USE CATALYTIC CONVERTERS IN CARS
REDUCE IT IN WATER WAYS BY ADDING LARGE AMOUNTS OF SODA ASH (LIME WATER) WHICH RAISES ALKALINITY **CLEAN AIR ACT (1990) = regulates amount of SO2 & Nox that are released form industrial plants which go by the NAAQS (National Ambient Air Quality Standards) http://acidrainmix.weebly.com/uploads/2/5/2/7/25273212/771105_orig.jpg ABOUT SMOKE STACK SCRUBBERS<br>
07
GLOBAL WARMING Caused by Greenhouse gases that absorb infrared radiation which traps the heat and builds up in the atmosphere
Industrial revolution increased levels of greenhouse gases
Greenhouse gases emissions are mostly Anthropogenic (caused by humans)<br>
Industrial revolution increased levels of greenhouse gases
Greenhouse gases emissions are mostly Anthropogenic (caused by humans)<br>
08
GREENHOUSE GASES and GLOBAL WARMING CO2 = carbon dioxide from burning fossil fuels, cellular respiration, decomposition
CCl4 = carbon tetrachloride from cleaning solvents
CFC= chlorofluorocarbons from air conditioners, refrigerants like Freon
HCFC= hydroclorofluorocarbons from foam products and insulator materials
CH4 = methane from coal production, natural gas, rice cultivation, trash decomposition
N2O = nitrous oxide from fertilizers, livestock waste, burning fossil fuels
O3 = ozone from burning fossil fuels<br>
CCl4 = carbon tetrachloride from cleaning solvents
CFC= chlorofluorocarbons from air conditioners, refrigerants like Freon
HCFC= hydroclorofluorocarbons from foam products and insulator materials
CH4 = methane from coal production, natural gas, rice cultivation, trash decomposition
N2O = nitrous oxide from fertilizers, livestock waste, burning fossil fuels
O3 = ozone from burning fossil fuels<br>
09
GREENHOUSE GASES<br>
10
IMPACTS OF GLOBAL WARMING 1.Acidification= in soil and water affects organisms growth
2.Changes in weather patterns ( hotter temperature higher evaporation higher rainfall El Nino & La Nina)
3.More erosion due to more rainfall
4.Glacier melting rise in sea level flooding increased water flows slows or shuts down Thermohaline Circulation by decreases saline concentration sinking and changing water temperature
5.Loss in Biodiversity from food web disruptions (from deaths, migration patterns altered due to temperature changes)<br>
2.Changes in weather patterns ( hotter temperature higher evaporation higher rainfall El Nino & La Nina)
3.More erosion due to more rainfall
4.Glacier melting rise in sea level flooding increased water flows slows or shuts down Thermohaline Circulation by decreases saline concentration sinking and changing water temperature
5.Loss in Biodiversity from food web disruptions (from deaths, migration patterns altered due to temperature changes)<br>
11
REDUCING CLIMATE CHANGE ***DECREASE GREENHOUSE GAS EMISSIONS
HOW:
*increase car efficiency
*use renewable energy sources
*stop deforestation and increase reforestation
*use less nitrogen based fertilizers
*support protocols to reduce greenhouse gas emissions
****KYOTO ACCORD (1997) = 38 countries agreed to reduce
greenhouse gas emissions<br>
HOW:
*increase car efficiency
*use renewable energy sources
*stop deforestation and increase reforestation
*use less nitrogen based fertilizers
*support protocols to reduce greenhouse gas emissions
****KYOTO ACCORD (1997) = 38 countries agreed to reduce
greenhouse gas emissions<br>
12
OZONE OZONE PROTECTS US FROM UV RADIATION
UVA = (320 nm - 400 nm) skin tans, safest
UVB = (290 nm – 320 nm) causes skin cancer
UVC = (10 nm – 290 nm) forms ozone in stratosphere, harmful *OZONE forms in stratosphere by UV radiation reactions:
O2 + uv O + O then O + O2 O3 (ozone)<br>
UVA = (320 nm - 400 nm) skin tans, safest
UVB = (290 nm – 320 nm) causes skin cancer
UVC = (10 nm – 290 nm) forms ozone in stratosphere, harmful *OZONE forms in stratosphere by UV radiation reactions:
O2 + uv O + O then O + O2 O3 (ozone)<br>
13
OZONE DEPLETION https://www.youtube.com/watch?v=OMtZC4FV_zM OZONE LAYER THINNING DUE TO CFC’s:
In the Stratosphere, UV decomposes CFC into CL which reacts
and destroys ozone
CL + O3 ClO + O2
**It takes CFC’s 8 years to reach stratosphere
**Hole over Antarctic discovered in 1950’s:<br>
In the Stratosphere, UV decomposes CFC into CL which reacts
and destroys ozone
CL + O3 ClO + O2
**It takes CFC’s 8 years to reach stratosphere
**Hole over Antarctic discovered in 1950’s:<br>
14
Ozone Depletion Effects *increased skin cancer (mutations)
*eye cataracts
*crop reduction
*climate change
*kills phytoplankton REDUCE OZONE DEPLETION:
by not using Halogen compounds (chlorine, bromine, fluorine)
found in refrigerant coolants EX: Freon and Aerosols MONTREAL PROTOCOL (1987) =agreement to phase out CFC’s<br>
*eye cataracts
*crop reduction
*climate change
*kills phytoplankton REDUCE OZONE DEPLETION:
by not using Halogen compounds (chlorine, bromine, fluorine)
found in refrigerant coolants EX: Freon and Aerosols MONTREAL PROTOCOL (1987) =agreement to phase out CFC’s<br>
15
WATER POLLUTION Due to land runoff with excess nutrients and pollutants
POINT SOURCE: directly from source that produces the pollutants
NON-POINT SOURCE: indirectly from many sources combined
GULF OF MEXICO DEAD ZONE= 5000 sq. miles of Gulf of Mexico where
Mississippi River delivers land runoff https://www.youtube.com/watch?v=BqaxdKXO9yc<br>
POINT SOURCE: directly from source that produces the pollutants
NON-POINT SOURCE: indirectly from many sources combined
GULF OF MEXICO DEAD ZONE= 5000 sq. miles of Gulf of Mexico where
Mississippi River delivers land runoff https://www.youtube.com/watch?v=BqaxdKXO9yc<br>
16
WATER QUALITY TESTS pH = measures acidity (should be at pH 6 – 8)
Hardness = measures concentrations of calcium and magnesium
Turbidity = measures density of suspended particles
Dissolved Oxygen (DO) = measures amount of oxygen dissolved in
water (warm water holds more DO than cold)
Biochemical Oxygen Demand (BOD) = measures rate at which bacteria absorbs oxygen from water<br>
Hardness = measures concentrations of calcium and magnesium
Turbidity = measures density of suspended particles
Dissolved Oxygen (DO) = measures amount of oxygen dissolved in
water (warm water holds more DO than cold)
Biochemical Oxygen Demand (BOD) = measures rate at which bacteria absorbs oxygen from water<br>
17
WATER QUALITY LEGISLATION CLEAN WATAER ACT (1972) = reduced direct pollutant discharge into waterways
OCEAN DUMPING ACT (1972) = unlawful to dump waste into ocean
SAFE DRINKING WATER ACT (1974) = monitors safe drinking water supply
OIL SPILL PREVENTION ACT (1990) = regulates prevention and response of oil
spills<br>
OCEAN DUMPING ACT (1972) = unlawful to dump waste into ocean
SAFE DRINKING WATER ACT (1974) = monitors safe drinking water supply
OIL SPILL PREVENTION ACT (1990) = regulates prevention and response of oil
spills<br>
18
CULTURAL EUTROPHICATION *process whereby human activity increases the amount of nutrients
that enter the waterways
*caused mainly by Nitrates (NO3-) and Phosphates (PO4) from fertilizers, sewage discharge, and animal wastes
*these nutrients allow phytoplankton and algae to grow uncontrollably
1.ALGAL BLOOM 2.decreases light penetration
3.kills deeper plants 4.lowers DO concentration
5.kills fish/ other aquatic organisms
6.decomposition uses DO and produces toxins https://www.youtube.com/watch?v=qON4FtQAKOs<br>
that enter the waterways
*caused mainly by Nitrates (NO3-) and Phosphates (PO4) from fertilizers, sewage discharge, and animal wastes
*these nutrients allow phytoplankton and algae to grow uncontrollably
1.ALGAL BLOOM 2.decreases light penetration
3.kills deeper plants 4.lowers DO concentration
5.kills fish/ other aquatic organisms
6.decomposition uses DO and produces toxins https://www.youtube.com/watch?v=qON4FtQAKOs<br>
19
SOLID WASTE/ GARBAGE Includes municipal waste, industrial waste, & hazardous waste
***REDUCE, REUSE, RECYCLE****
PRIMARY RECYCLING= reusing material to make the same product
EX. plastic & aluminum
SECONDARY RECYCLING= reusing material to make a new product
EX. old tires for carpet
COMPOSTING: using scraps of food and organic materials in solid waste
in a decomposition process that makes organic fertilizer https://www.youtube.com/watch?v=gWNzLY5Sjyg<br>
***REDUCE, REUSE, RECYCLE****
PRIMARY RECYCLING= reusing material to make the same product
EX. plastic & aluminum
SECONDARY RECYCLING= reusing material to make a new product
EX. old tires for carpet
COMPOSTING: using scraps of food and organic materials in solid waste
in a decomposition process that makes organic fertilizer https://www.youtube.com/watch?v=gWNzLY5Sjyg<br>
20
LANDFILLS https://www.youtube.com/watch?v=mA608GJ-EzM<br>
21
LANDFILL REGULATIONS *landfills must not be near geological faults, wetlands, flood plains
*landfills must be positioned at least six feet above water table
*landfill site must consist of a hole that is lined with geo-membranes or plastic sheets that are reinforced with 2 ft of clay on bottom and sides
*landfill waste must be covered with soil to control animal infestation
*LEACHATE= the decomposed liquid material that percolates to the bottom of landfill must be piped to the top of the site and collected in leachate ponds ( the methane gas can be used as fuel or burned)<br>
*landfills must be positioned at least six feet above water table
*landfill site must consist of a hole that is lined with geo-membranes or plastic sheets that are reinforced with 2 ft of clay on bottom and sides
*landfill waste must be covered with soil to control animal infestation
*LEACHATE= the decomposed liquid material that percolates to the bottom of landfill must be piped to the top of the site and collected in leachate ponds ( the methane gas can be used as fuel or burned)<br>
22
LOVE CANAL https://www.youtube.com/watch?v=AqWaaBpNUWs *canal near Niagara Falls N.Y. that originally was built to produce power
became landfill for hazardous waste was covered
became a residential community illnesses occur
lawsuits against government
*as a result:
RCRA (Resource Conservation & Recovery Act)
CERCLA (Comprehensive Environmental Response Compensation
Liability Act)<br>
became landfill for hazardous waste was covered
became a residential community illnesses occur
lawsuits against government
*as a result:
RCRA (Resource Conservation & Recovery Act)
CERCLA (Comprehensive Environmental Response Compensation
Liability Act)<br>
23
FISHERY – OCEAN RESOURCE Fishery: industry devoted to catching fish (about 125 million tons of fish are harvested each year – mostly in China)
HOW?
1.DRIFTNETS = net floats through water, catches everything in path
2.LONGLINING= long lines with baited hooks
3.BOTTOM TRAWLING= heavy nets scrape ocean floor
BY CATCH= refers to the other organisms caught that are NOT target fish
EX. Dolphins of Tuna catch<br>
HOW?
1.DRIFTNETS = net floats through water, catches everything in path
2.LONGLINING= long lines with baited hooks
3.BOTTOM TRAWLING= heavy nets scrape ocean floor
BY CATCH= refers to the other organisms caught that are NOT target fish
EX. Dolphins of Tuna catch<br>
24
OVERFISHING *Overfishing has depleted 50 % of major fish stocks
SOLUTION: AQUACULTURE or FISH FARMING
raising fish in captivity for harvest EX. Salmon & shrimp
PROBLEM: ACCIDENTAL RELEASE
*some fish are genetically modified
*transmission of new diseases https://www.youtube.com/watch?v=tUrGKVJcd9M<br>
SOLUTION: AQUACULTURE or FISH FARMING
raising fish in captivity for harvest EX. Salmon & shrimp
PROBLEM: ACCIDENTAL RELEASE
*some fish are genetically modified
*transmission of new diseases https://www.youtube.com/watch?v=tUrGKVJcd9M<br>
25
INVASIVE/ NON-NATIVE SPECIES *species transported to any area where they do NOT naturally live
EX: from Marine Ballast
*they become pests and crowd out native organisms
*they have no natural predators
*they out compete native organisms for space and food
*they alter the ecological processes of that habitat https://www.youtube.com/watch?v=1090CKi_Lzo<br>
EX: from Marine Ballast
*they become pests and crowd out native organisms
*they have no natural predators
*they out compete native organisms for space and food
*they alter the ecological processes of that habitat https://www.youtube.com/watch?v=1090CKi_Lzo<br>
26
LOSS OF BIODIVERSITY ACCORDING TO NATURE CONSERVANCY:
1/4 of all mammals and reptiles are endangered
1/8 of all birds are endangered
1/6 of conifers are endangered
PROTECT BIODIVERSITY
1. establish breeding programs and reintroduce species
2. protect habitats and create sanctuaries
3. reduce non-native species
4. update laws to protect endangered species https://www.youtube.com/watch?v=jWvWf01ObdY<br>
1/4 of all mammals and reptiles are endangered
1/8 of all birds are endangered
1/6 of conifers are endangered
PROTECT BIODIVERSITY
1. establish breeding programs and reintroduce species
2. protect habitats and create sanctuaries
3. reduce non-native species
4. update laws to protect endangered species https://www.youtube.com/watch?v=jWvWf01ObdY<br>
27
LAWS SUPPORTING BIODIVERSITY *MULTIPLE-USE ACT (1960) – manages national forests
*CITES (Convention on International Trade in Endangered Species
of wild fauna and flora) (1963)- international agreement
between governments to regulate trade of animals & plants
*ENDANGERED SPECIES ACT (1973) - to provide conservation
programs for endangered species and habitats
*ENVIRONMENTAL EDUCATION ACT (1990) – to develop environmental
education programs<br>
*CITES (Convention on International Trade in Endangered Species
of wild fauna and flora) (1963)- international agreement
between governments to regulate trade of animals & plants
*ENDANGERED SPECIES ACT (1973) - to provide conservation
programs for endangered species and habitats
*ENVIRONMENTAL EDUCATION ACT (1990) – to develop environmental
education programs<br>
28
SUSTAINABILITY https://www.youtube.com/watch?v=gTamnlXbgqc SUSTAINABILITY= deals with the aspects of human society and preservation of biodiversity and the environment
COST-BENEFIT ANALYSIS – a technique for deciding whether to make a change or not by:
1st-weighing the benefits of how to use a piece of land/waterway
EX: jobs , lumber
2nd-against the cost of using that piece of land/waterway
EX: loss of space, CO2, biodiversity https://www.youtube.com/watch?v=_5r4loXPyx8<br>
COST-BENEFIT ANALYSIS – a technique for deciding whether to make a change or not by:
1st-weighing the benefits of how to use a piece of land/waterway
EX: jobs , lumber
2nd-against the cost of using that piece of land/waterway
EX: loss of space, CO2, biodiversity https://www.youtube.com/watch?v=_5r4loXPyx8<br>