PPT-Thermodynamics Calorimetry

The Experimental Measurement of Heat Outline Background Exothermic vs Endothermic Reactions Heat Capacity Specific Heat Specific Heat of Selected Substances and Mixtures Relevance Background. Introduction Differential scanning calorimetry DSC monitors heat effects associated with phase transitions and chemical reactions as a function of temperature In a DSC the difference in heat flow to the sample and a reference at the same temperature LIMITATION OF FIRST LAW OF . THERMODYNAMICS. It does not give information concerning feasibility of a thermodynamic . proces. .. why. NOT EXPLAINED BY FIRST LAW. It tells that work obtained is equal to heat absorbed but in actual heat absorbed can not be completely converted into work. 1. st. law of thermodynamics. Energy may be converted to different forms, but it is neither created nor destroyed during transformations. Energy from chemical bonds is converted to kinetic energy and heat (body and friction from tires). Thermodynamics. Rub your hands together for 15 seconds.. Are your hands warm?. Thermal energy. Thermodynamics. The study of the effects of work, heat flow, and energy on a system. Movement of thermal energy. No engine, working in a continuous cycle, can take heat from a reservoir at a single temperature and convert that heat completely to work.. Therefore, no engine can have a greater efficiency than a Carnot engine operating between the same two temperatures.. [4]. Change of phase . . ice. .  . water.  . steam. The Laws of Thermodynamics. The 1. st. Law. The 2. nd. Law. Applications. Heat engines. Refrigerators. Order to disorder. 2. Change of Phase. AP Environmental Science. What is Energy?. Energy is a . measurable quantity. that can be stored in a physical system. Energy can be . transferred. from one system to another and so . cause changes. Advanced Chemistry. Ms. . Grobsky. What is Energy?. Energy. . is the capacity to do work. Thermal energy. is the energy associated with the random motion of atoms and molecules. Kinetic energy . is the energy due to motion. Physics Lecture Notes. The Laws of Thermodynamics. FOUNDRY: It requires about 289 Joules of heat to melt one gram of steel. In this chapter, we will define the quantity of heat to raise the temperature and to change the phase of a substance. . The Basics. The brief definition of Thermodynamics is . the science concerned with the relations between heat and mechanical energy or work, and the conversion of one into the other: modern thermodynamics deals with the properties of systems for the description of which temperature is a necessary coordinate. Champion Deivanayagam. Center for Biophysical Sciences and Engineering. University of Alabama at Birmingham.. Outline:. Laws of thermodynamics. Enthalpy. Entropy. Gibbs free energy. some examples. Patreon.com/. scientistmel. Twitter.com/. scientistmel. 4-7-18 11 am CST. Thermodynamics. Studies the effects on a system. Work. Heat. Energy. System?. System – quantity of matter. Boundaries – fixed or moveable. Calorimetry Burning of a Match Zumdahl, Zumdahl, DeCoste, World of Chemistry 2002, page 293 Energy released to the surrounding as heat Surroundings System (Reactants) D (PE) Potential energy (Products) The net entropy will increase or stay the same It will never decreaseThe net entropy will increase or stay the same It will never decreaseSYSqSx0000 0SqT 0 only for a reversible processx0000 0 f