Klean Strip Green Denatured Alcohol SAFETY DATA SHEET - PDF document

1SAFETY DATA SHEET 30 07/11/201411/13/2008Revision:Supersedes Revision:07/21/2014Printed: * Key wordGHS hazard phraseAspiration Toxicity, Category 1DangerAquatic Toxicity (Acute), Category 3noneAquatic Toxicity (Chronic), Category 3none Ethyl alcohol {Ethanol}64-17-567-56-1108-10-1 Acetic acid, ethyl ester {Ethyl acetate}141-78-6Heptane142-82-5 PEL: 1000 ppmNo data.Hazardous Components (Chemical Name)ACGIH TWAEthyl alcohol {Ethanol}64-17-5CAS #OSHA PELOther LimitsPEL: 200 ppmNo data.PEL: 100 ppmNo data.PEL: 400 ppmNo data.Acetic acid, ethyl ester {Ethyl acetate}141-78-6PEL: 500 ppmNo data.Heptane142-82-5 07/11/2014Revision:07/21/2014Printed:SAFETY DATA SHEET11/13/2008Supersedes Revision:Page:Engineering Controls (Ventilation etc.)Use only with adequate ventilation to prevent build-up of vapors. Open all windows and doors. Use only with across ventilation of moving fresh air across the work area. If strong odor is noticed or you experience slightWork/Hygienic/Maintenance PracticesA source of clean water should be available in the work area for flushing eyes and skin.9. Physical and Chemical Properties[ ] Gas [ X ] Liquid [ ] SolidPhysical States:No data.Melting Point:174.20 FBoiling Point:685.00 FAutoignition Pt:55.00 F Method Used: UnknownFlash Pt:LEL: 3.3 % UEL: 19%Explosive Limits:0.789 - 0.83 at 60.0 FSpecific Gravity (Water = 1):6.75 LB/GABulk density:~ 44 MM HG at 20.0 CVapor Pressure (vs. Air or mm Hg):~ 1.6Vapor Density (vs. Air = 1):~ 2 (BuAC=1)Evaporation Rate:miscibleSolubility in Water:Solubility NotesCompletely soluble in water.100.0 % by weight.Percent Volatile:789.0000 G/LVOC / Volume:Appearance and OdorClear, water white, thin liquid10. Stability and ReactivityUnstable [ ] Stable [ X ]Stability:Conditions To Avoid - InstabilityHeat, flames and sparks. Avoid temperatures exceeding the flash point.Incompatibility - Materials To AvoidIncompatible with strong oxidizing agents.Hazardous Decomposition Or ByproductsDecomposition may produce carbon monoxide, carbon dioxide, and possibly other unidentified organiccompounds.Will occur [ ] Will not occur [ X ]Possibility of Hazardous Reactions:Conditions To Avoid - Hazardous ReactionsNo data available.Licensed to W.M. Barr and CompanyGHS format 07/11/2014Revision:07/21/2014Printed:SAFETY DATA SHEET11/13/2008Supersedes Revision:Page:11. Toxicological InformationToxicological InformationCAS# 64-17-5: Acute toxicity, LD50, Oral, Rat, 7060. MG/KG.Acute toxicity, LC50, Inhalation, Rat, 20000. PPM, 10 H.Result:Standard Draize Test, Skin, Species: Rabbit, 20.00 MG, 24 H, Moderate.Result:Standard Draize Test, Eyes, Species: Rabbit, 500.0 MG, Severe.Result:CAS# 67-56-1: Reproductive Effects:, TDLo, Oral, Rat, 42.00 mL/kg, 21 day after birth.Mutagenicity:, Mutation test: DNA damage., Oral, Rat, 10.00 UMOL/KG.Result:Acute toxicity, LD50, Oral, Rat, 5628. MG/KG.Result:Acute toxicity, LC50, Inhalation, Rat, 64000. PPM, 4 H.Licensed to W.M. Barr and CompanyGHS format 07/11/2014Revision:07/21/2014Printed:SAFETY DATA SHEET11/13/2008Supersedes Revision:Page:Result:Behavioral: Altered sleep time (including change in righting reflex).Standard Draize Test, Skin, Species: Rabbit, 20.00 MG, 24 H, Moderate.Result:Standard Draize Test, Eyes, Species: Rabbit, 40.00 MG, Moderate.Result:Standard Draize Test, Eyes, Species: Rabbit, 100.0 MG, 24 H, Moderate.Result:CAS# 108-10-1: Acute toxicity, LD50, Oral, Rat, 2080. MG/KG; Union Carbide Data Sheet, Union Carbide Corp., 39 OldStandard Draize Test, Skin, Species: Rabbit, 500.0 MG, 24 H, Mild; Prehled Prumyslove Toxikologie, Marhold,J., Organicke Latky, Prague Czechoslovakia, Vol/p/yr: -,284, 1986Standard Draize Test, Eyes, Species: Rabbit, 40.00 MG, Severe; Union Carbide Data Sheet, Union Carbide Corp.,39 Old Ridgebury Rd., Danbury, CT 06817, Vol/p/yr: 4/25, 1958CAS# 141-78-6: Acute toxicity, LD50, Oral, Rat, 5620. MG/KG.Acute toxicity, LC50, Inhalation, Rat, 200.0 GM/M3.Result:Licensed to W.M. Barr and CompanyGHS format 1n.a.Ethyl alcohol {Ethanol}64-17-5NTPIARCACGIHOSHAn.a.n.a.67-56-1n.a.2Bn.a.108-10-1n.a.n.a.n.a.Acetic acid, ethyl ester {Ethyl acetate}141-78-6n.a.n.a.n.a.Heptane142-82-5n.a. 07/11/2014Revision:07/21/2014Printed:SAFETY DATA SHEET11/13/2008Supersedes Revision:Page:LC50, Fathead Minnow (Pimephales promelas), juvenile(s), 13480000. UG/L, 96 H, Mortality, Watertemperature: 18.00 C - 22.00 C C.LC50, Fathead Minnow (Pimephales promelas), juvenile(s), 100000. UG/L, 96 H, Mortality, Water temperature:20.00 C C, pH: 8.50.LC50, Water Flea (Daphnia magna), 9300000. UG/L, 48 H, Mortality.Result:LC50, Water Flea (Daphnia magna), larva(e), 100000. UG/L, 96 H, Mortality, Water temperature: 20.00 C C, pH:8.50.LC50, Water Flea (Daphnia magna), neonate, 11853000. UG/L, 48 H, Mortality, Water temperature: 20.00 C -20.80 C C, pH: 8.30, Hardness: 159.60 MG/L.CAS# 67-56-1: LC50, Fathead Minnow (Pimephales promelas), 28200000. UG/L, 96 H, Mortality, Water temperature: 25.00 CLC50, Fathead Minnow (Pimephales promelas), 28400000. UG/L, 72 H, Mortality.Result:Licensed to W.M. Barr and CompanyGHS format 07/11/2014Revision:07/21/2014Printed: 10Klean Strip Green Denatured AlcoholSAFETY DATA SHEET11/13/2008Supersedes Revision:Page:LC50, Fathead Minnow (Pimephales promelas), juvenile(s), 100000. UG/L, 96 H, Mortality, Water temperature:20.00 C C, pH: 8.50.LC50, Fathead Minnow (Pimephales promelas), 28400. MG/L, 24 H, Mortality, Water temperature: 25.00 C C.Result:LC50, Fathead Minnow (Pimephales promelas), 28400. MG/L, 48 H, Mortality, Water temperature: 25.00 C C.Result:LC50, Fathead Minnow (Pimephales promelas), 28100. MG/L, 96 H, Mortality, Water temperature: 25.00 C C.Result:LC50, Water Flea (Daphnia magna), larva(e), 100000. UG/L, 96 H, Mortality, Water temperature: 20.00 C C, pH:8.50.LC50, Water Flea (Daphnia magna), neonate, 4816. MG/L, 24 H, Mortality, Water temperature: 20.00 C C.Result:LC50, Water Flea (Daphnia magna), neonate, 3289. MG/L, 48 H, Mortality, Water temperature: 20.00 C C.Result:CAS# 108-10-1: LC50, Fathead Minnow (Pimephales promelas), juvenile(s), 537000. UG/L, 96 H, Mortality, Water temperature:Licensed to W.M. Barr and CompanyGHS format 07/11/2014Revision:07/21/2014Printed: 11Klean Strip Green Denatured AlcoholSAFETY DATA SHEET11/13/2008Supersedes Revision:Page:- Acute Toxicity of Organic Chemical Mixtures to the Fathead Minnow, Broderius, S., and M. Kahl, 1985CAS# 141-78-6: LC50, Fathead Minnow (Pimephales promelas), 270000. UG/L, 48 H, Mortality, Water temperature: 20.00 C C.LC50, Fathead Minnow (Pimephales promelas), 230000. UG/L, 96 H, Mortality, Water temperature: 24.30 C C,pH: 7.40, Hardness: 45.00 MG/L.LC50, Fathead Minnow (Pimephales promelas), 180000. - 320000. UG/L, 24 H, Mortality, Water temperature:20.00 C C.LC50, Fathead Minnow (Pimephales promelas), 270000. UG/L, 48 H, Mortality, Water temperature: 20.00 C C.Result:LC50, Water Flea (Daphnia magna), 560000. UG/L, 48 H, Mortality.Result:LC50, Water Flea (Daphnia magna), 590.0 MG/L, Mortality.Result:LC50, Water Flea (Daphnia magna), 790.0 MG/L, 24 H, Intoxication,, Water temperature: 20.00 C - 22.00 C C,pH: 7.70, Hardness: 16.00 dH.Licensed to W.M. Barr and CompanyGHS format NoNoEthyl alcohol {Ethanol}64-17-5Sec.302 (EHS)Sec.304 RQSec.313 (TRI)Sec.110Yes 5000 LBNo67-56-1NoYes 5000 LBYes108-10-1NoYes 5000 LBNoAcetic acid, ethyl ester {Ethyl acetate}141-78-6NoNoNoHeptane142-82-5NoNoNoEthyl alcohol {Ethanol}64-17-5CAA HAP,ODCCWA NPDESTSCACA PROP.65NoYes67-56-1HAPNoYes108-10-1HAPNoNoAcetic acid, ethyl ester {Ethyl acetate}141-78-6NoNoNoHeptane142-82-5No 07/11/2014Revision:07/21/2014Printed: 13Klean Strip Green Denatured AlcoholSAFETY DATA SHEET11/13/2008Supersedes Revision:Page:EPA Hazard Categories:This material meets the EPA 'Hazard Categories' defined for SARA Title III Sections 311/312 as indicated:[X] Yes [ ] No Acute (immediate) Health Hazard[X] Yes [ ] No Chronic (delayed) Health HazardRegulatory Information StatementAll components of this material are listed on the TSCA Inventory or are exempt.16. Other InformationCompany Policy or DisclaimerThe information contained herein is presented in good faith and believed to be accurate as of the effective dateshown above. This information is furnished without warranty of any kind. Employers should use this information07/11/2014Revision Date:Licensed to W.M. Barr and CompanyGHS format