Muhammad Al Fredey Abdullah Alshaye 1 Radiocarbon dating Radiocarbon dating or simply carbon dating is a radiometric dating technique that uses the decay of carbon14 14 C ID: 783479
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Slide1
Application of Differential Equations in different Scenarios
Muhammad Al
Fredey
Abdullah
Alshaye
Slide21. Radiocarbon dating
Radiocarbon dating
(or simply
carbon dating
) is a
radiometric dating
technique that uses the decay of
carbon-14
(
14
C
6
) to estimate the age of
organic materials
, such as wood and leather, up to about 58,000 to 62,000 years
Before Present
(BP, present defined) .
Before Present
(
BP
) years is a
time scale
used mainly in
geology
and other
scientific
disciplines to specify when events in the past occurred. Because the "present" time changes, standard practice is to use …
Slide3Radiocarbon dating (Continued)
1
st January 1950 as commencement date of the age scale, reflecting the fact that
radiocarbon dating
became practicable in the 1950s.
Carbon dating was presented to the world by
Willard Libby
in 1949, for which he was awarded the
Nobel Prize in Chemistry
.
Since the introduction of carbon dating, the method has been used to date many items, including samples of the
Dead Sea Scrolls
, the
Shroud of Turin
, enough
Egyptian
artefacts
to supply a
chronology
of
Dynastic Egypt
, and
Ötzi
the Iceman
Slide4Radiocarbon dating (Continued)
The Earth's atmosphere contains various
isotopes
of
carbon
, roughly in constant proportions. These include the main stable isotope (
12
C
6
) and an unstable isotope (
14
C
6
). Through photosynthesis, plants absorb both forms from
carbon dioxide
in the atmosphere. When an organism dies, it contains the standard ratio of
14
C
6
to
12
C
6
, but as the
14
C
6
decays with no possibility of replenishment, the proportion of carbon
14
C
6
decreases at a known constant rate. The time taken for it to reduce by half is known as the
half-life
of
14
C
6
.
Slide5Radiocarbon dating (Continued)
The measurement of the remaining proportion of
14
C
6
in organic matter thus gives an estimate of its age (a
raw
radiocarbon age). However, over time there are small fluctuations in the ratio of
14
C
6
to
12
C
6
in the atmosphere, fluctuations that have been noted in natural records of the past, such as
sequences of tree rings
and
cave deposits
. These records allow fine-tuning, or "
calibration
", of the raw radiocarbon age, to give a more accurate estimate of the calendar date of the material. One of the most frequent uses of radiocarbon dating is to estimate the age of organic remains from archaeological sites.
Slide6Radiocarbon dating (Continued)
Calculating ages
:
While a plant or animal is alive, it is exchanging carbon with its surroundings, so that the carbon it contains will have the same proportion of
14
C
6
as the biosphere (
12
C
6
). Once it dies, it ceases to acquire
14
C
6
, but the
14
C
6
that it contains will continue to decay, and so the proportion of radiocarbon in its remains will gradually reduce. Because
14
C
6
decays at a known rate, the proportion of radiocarbon can be used to determine how long it has been since a given sample stopped exchanging carbon—the older the sample, the less
14
C
6
will be left . The equation governing the decay of a radioactive isotope is
Slide7Radiocarbon dating (Continued)
where
N
0
is the number of atoms of the isotope in the original sample (at time
t
= 0), and
N
is the number of atoms left after time
t.
The mean-life, i.e. the average or expected time a given atom will survive before undergoing radioactive decay denoted by
τ
, of
14C6 is 8,267 years, so the equation above can be rewritten as
Slide8Radiocarbon dating (Continued)
The ratio of
14
C
6
atoms in the original sample,
N
0
, is taken to be the same as the ratio in the biosphere
12
C
6
, so measuring
N, the number of 14C6 atoms currently in the sample, allows the calculation of t, the age of the sample.
Slide9Radiocarbon dating (Continued)
The
half-life
of a radioactive isotope (the time it takes for half of the sample to decay, usually denoted by
T
1/2
) is a more familiar concept than the mean-life, so although the equations above are expressed in terms of the mean-life, it is more usual to quote the value of
14
C
6
half-life than its mean-life. The currently accepted value for the half-life of radiocarbon is 5,730 years. The mean-life and half-life are related by the following equation
Slide10Radiocarbon dating (Continued)
For over a decade after Libby's initial work, the accepted value of the half-life for
14
C
6
was 5,568 years; this was improved in the early 1960s to 5,730 years, which meant that many calculated dates in published papers were now incorrect (the error is about 3%). However, it is possible to incorporate a correction for the half-life value into the calibration curve, and so it has become standard practice to quote measured radiocarbon dates in "radiocarbon years", meaning that the dates are calculated using Libby's half-life value and have not been calibrated.
Slide11Examples (Radiocarbon dating) (Continued)
A fossil bone is found to contain 1/1000 the original amount of 6C14 Determine the age of the fossil.
We have the equation governing the given phenomenon as under , which gives the amount of
y(t) =
y0.
where y0 is the initial amount of the radioactive substance. For t = 5730 years ( the half – age of 6C14 ), this equation gives,
y(t) = y0 /2.
Slide12Radiocarbon dating (Continued)
Thus
from the above equation we can determine the value of the constant k as under,
y0/2 =
y0. or
- 5730 k = In (1/2).
Thus we get,
k= In(1/2)/(-5730) 0.000120
Therefore the above equation becomes,
y(t) =
y0.
Thus , when y(t) = y0 / 1000, as given , we get,
y0/1000 =
y0.
Slide13Radiocarbon dating (Continued)
On
taking log-natural of both sides this equation gives,
-0.00012097 t = In (1/1000) = - In ( 1000 ).
So that ,
t = In ( 1000 ) /0.00012097 = 57136 years.
Note : In the above method radioactive Carbon dating much of the accuracy of result depends upon the chemical analysis of the fossil. In order to obtain better estimations of 6C14 present in the fossil , destruction of large samples of the specimen are required. The same may not always be possible from archival point of view. In view of the same the age estimation of the fossil in the above example is not very accurate.
Slide14Radiocarbon dating (Continued)
In
the recent years geologists have shown that age estimation of the fossils by the above mentioned method may be out by as much as 3500 years in certain cases. One of the possible reasons for this error is the fact that 6C14 levels in the air very with time. They have devised another method for the purpose, based on the fact that the living organisms ingest traces of Uranium. By measuring the relative amounts of Uranium and Thorium (the isotope into which Uranium decays ), and by knowing
Slide15Radiocarbon dating (Continued)
the
half-lives of these elements, one can determine the age of the fossil. By this method one can estimate the ages of even 5000,000 old fossils. However, this method is not applicable to marine fossils. Some other techniques can also be used for the purpose including the use of Potassium – 40 and Argon 40 (which can estimate ages up to millions of years), and non-isotopic , methods based on the use of amino acids.
Slide162. Newton's Law of Cooling
Newton's Law of Cooling states that the rate of change of the temperature of an object is proportional to the difference between its own temperature and the ambient temperature (i.e. the temperature of its surroundings).
Newton's Law makes a statement about an
instantaneous
rate of change of the temperature. We will see that when we translate this verbal statement into a differential equation, we arrive at a differential equation. The
solution
to this equation will then be a function that tracks the complete record of the temperature over time.
Slide17Newton's Law of Cooling (Continued)
Crime Scene
A detective is called to the scene of a crime where a dead body has just been found. She arrives on the scene at 6:00 pm and begins her investigation. Immediately, the temperature of the body is taken and is found to be 85
o
F. The detective checks the programmable thermostat and finds that the room has been kept at a constant 72
o
F for the past 3 days.
Slide18Newton's Law of Cooling (Continued)
After evidence from the crime scene is collected, the temperature of the body is taken once more and found to be 78
o
F. This last temperature reading was taken exactly three hour after the first one (i.e., at 9:00 pm). The next day the detective is asked by another investigator,
“What time did our victim die?”
Assuming that the victim’s body temperature was normal (98.6
o
F) prior to death, what is her answer to this question? Newton's Law of Cooling can be used to determine a victim's time of death.
Slide19Newton's Law of Cooling (Continued)
The governing equation for the temperature, T of the body is
where
T = temperature of the body,
To = ambient temperature
t = time in hrs
k = constant based on thermal properties of body and air
Slide20Newton's Law of Cooling (Continued)
The characteristic equation of the above differential equation is
Slide21Newton's Law of Cooling (Continued)
Let the particular solution is
Substituting this particular solution into the ordinary differential equation
The complete solution is
Slide22Newton's Law of Cooling (Continued)
Given is
where B = time of death,
We get
Slide23Use equations. (1) and (2) to find A and K, we get
Substituting the values of A and K into equation (3), to find B
The time of death is 3.221 hrs, that is 0.3221*60 = 13.326 minutes after 3 pm.
Time of death = 3:13 pm
Newton's Law of Cooling (Continued)
Slide243. Exponential Population Growth
Bacterial growth
Suppose the population of bacteria doubles every 3 hours. What exactly does that mean? Imagine you inoculate a fresh culture with N bacteria at 12:00 pm. At 3 pm, you will have 2N bacteria, at 6 pm you will have 4N bacteria, at 9 pm you will have 8N bacteria, and so on. If these cell divisions occur at EXACTLY each of these time points the cells are said to be growing synchronously. If this were the case, the growth process would be
geometric.
Slide25Exponential Population Growth(Continued)
A geometric growth model
predicts that the population
increases at discrete time points
(in this example hours 3, 6, and 9).
In other words, there is not a
continuous increase in the
population.
Slide26Exponential Population Growth(Continued)
Slide27Exponential Population Growth(Continued)
However, this is not what actually happens. Imagine you take a small sample of the culture every hour and count the number of bacteria cells present. If bacterial growth were geometric, you would expect to have N bacteria between 12 pm and 3pm, 2N bacteria between 3 pm and 6 pm, etc.
However, if you perform this experiment in the laboratory, even under the best experimental conditions, this will not be the case.
Slide28Exponential Population Growth(Continued)
If you go a step further
and make a graph with
the number of bacteria
on the
y
-axis and time
on the
x
-axis, you will
get a plot that looks much
more like exponential
growth than geometric growth.
Slide29Exponential Population Growth(Continued)
Why does bacterial growth look like exponential growth in practice?
The answer is because bacterial growth is not completely synchronized. Some cells divide in fewer than 3 hours; while others will take a little longer to divide. Even if you start a culture with a single cell, synchronicity will be maintained only through a few cell divisions. A single cell will divide at a discrete point in time, and the resulting 2 cells will divide at ABOUT the same time, and the resulting 4 will again divide at ABOUT the same time.
Slide30Exponential Population Growth(Continued)
As the population grows, the individual nature of cells will result in a smoothing of the division process. This smoothing yields an exponential growth curve, and allows us to use exponential functions to make calculations that predict bacterial growth. So, while exponential growth might not be the perfect model of bacterial growth by binary fission, it is the appropriate model to use given experimental reality.
Slide31Exponential Population Growth(Continued)
Problem -Calculate the number of bacteria in a culture at a given time
How many bacteria are present after 51 hours if a culture is inoculated with 1 bacterium? Use the model,
N
(
t
) =
N
o
e
kt
, and assume the population doubles every 3 hours. (
N(t) is the population size at time t and k
is a constant.)
Slide324. Radioactive Decay
In nature, there are a large number of atomic nuclei that can spontaneously emit elementary particles or nuclear fragments. Such a phenomenon is called
radioactive decay
. This effect was studied at the turn of 19-20 centuries by
Antoine Becquerel
,
Marie and Pierre Curie
,
Frederick Soddy
,
Ernest Rutherford
, and other scientists. As a result of the experiments,
F.Soddy
and E.Rutherford derived the radioactive decay law, which is given by the differential equation
Slide33Radioactive Decay(Continued)
where
N
is the amount of a radioactive material,
λ
is a positive constant depending on the radioactive substance. The minus sign in the right side means that the amount of the radioactive material
N
(
t
) decreases over time. The given equation is easy to solve, and the solution has the form
Slide34Radioactive Decay(Continued)
To determine the constant
C
, it is necessary to indicate an initial value. If the amount of the material at the moment
t =
0 was
N
0
, then the radioactive decay law is written as
The
half life
or
half life period
T of a radioactive material is the time required to decay to one-half of the initial value of the material. Hence, at the moment T:
Slide35Example ( Radioactive Decay )
(continued)
In
a certain radioactive substance the rate of decrease in mass is proportional to the current mass. If the mass present is reduced by half, in half , an hour, what percent of the original mass is expected to remain present at the end of 0.9 hours?
Slide36Radioactive Decay (
continued)
Let
the mass at time is y(t). Then the given problem can be represented by
dy
/
dt
=
ky
,
where k is constant of proportionality. On solving at we get,
y= c e-
kt
where c is the constant of integration. If y0 is the mass at t =0, the above equation becomes,
y0 = c e0 = 1⁄2 y0 = c e-k/2 = y0 e-k/2 Thus, 1⁄2 = e-k/2 ,
Slide37Taking log-natural of both sides we get 1⁄2 k = In(1/2)= In (2),
or k = In 4.
Therefore, the desired solution is,
y = y0 e-(In4)t
The
above solution can be put as : y = y0 / et(In4) = y0/4t .
Therefore , when t = 0.9 (given ), then the above equation
gives: y = y0 / 40.9 = 0.2871745 , y0 = 29% of y0 (
approx
)
Thus at the end of 0.9 hours about 29 percent of the original quantity of the given radioactive substance would be left.
Radioactive Decay (continued
)
Slide385. Compound Interest
Compound Interest: Non-Continuous
P
= principal amount invested
m
= the number of times
per year
interest is compounded
r
= the interest rate
t
= the number of years interest is being compounded A = the compound amount, the balance after
t
years
Slide39Compound Interest(Continued)
Notice
that as
m
increases, so does
A
. Therefore, the maximum amount of interest can be acquired when
m
is being compounded all the time - continuously.
Slide40Compound Interest(Continued)
Compound Interest: Continuous
P
= principal amount invested
r
= the interest rate
t
= the number of years interest is being compounded
A
= the compound amount, the balance after
t
years
Compound Interest: Continuous
Slide41Compound Interest(Continued)
EXAMPLE
(
Continuous Compound
) Ten thousand dollars is invested at 6.5% interest compounded continuously. When will the investment be worth $41,787?
SOLUTION
We must first determine the formula for
A
(
t
). Since interest is being compounded continuously, the basic formula to be used is
Since the interest rate is 6.5%,
r
= 0.065. Since ten thousand dollars is being invested,
P
= 10,000. And since the investment is to grow to become $41,787,
A
= 41,787. We will make the appropriate substitutions and then solve for
t
.
This is the formula to use.
P
= 10,000,
r
= 0.065, and
A
= 41,787.
Slide42Compound Interest(Continued)
Therefore, the $10,000 investment will grow to $41,787, via 6.5% interest compounded continuously, in 22 years.
Slide43Thanks