PPT-Benzene

By Taylor Hatchett What is Benzene Chemical C olorless or light yellow L iquid at room temperature Has a sweet odor H ighly flammable E vaporates quickly into air What is Benzene Vapor is heavier than air. M.ARULSELVAN. Syllabus. Benzene and Aromaticity. 4.1 Concept of aromaticity:. . . -Huckel's rule for aromaticity, . -identification of aromatic, . -Non-aromatic and anti aromatic systems based on planarity, conjugation and Huckel's rule.. (. Benzene. ). 140 pm. 140 pm. 140 pm. 140 pm. 140 pm. 140 pm. All C—C bond distances = 140 pm. Benzene. empirical formula. = CH. 140 pm. 140 pm. 140 pm. 140 pm. 140 pm. 140 pm. . 146 pm. 134 pm. 15-4. The UV-visible spectrum of benzene reveals its electronic structure.. The energy gap between bonding and antibonding orbitals is greater in benzene than for acyclic trienes.. The UV spectra of benzene shows absorbances at smaller wavelengths (higher energy) than does the spectra of 1,3,5-hexatriene:. Bitter almonds are the source of the aromatic compound benzaldehyde. Sources of Benzene. Some Facts About Benzene. Reacts mainly by substitution. Friedrich August Kekule’. The Orbital Model for Benzene. 15-11. Carbon-carbon bonds to benzene can be created using a sufficiently electrophilic carbon based electrophile.. To create the necessary electrophilic carbon atom, a Lewis acid such as AlCl. 3. is employed.. Chemistry 122/121. Cyclic Hydrocarbons. Both saturated and unsaturated hydrocarbons may be found in the form of a ring. The resulting structure has two less hydrogen than its straight chain counterpart. Dr. . Shatha. I . Alaqeel. 108 . Chem. Learning Objectives. By the end of chapter four the students will:. Understand the resonance description of structure of benzene. Understand the hybridization in benzene. Research Task. Benzene – . research task. Find out about and describe, including diagrams, . Kekule’s. structure for benzene – C. 6. H. 6. Explain the discrepancies and limitations in the model with respect to the low reactivity . 15. TH. FEB 2012. PRESENTED BY. HARIDASAN V A. CAPACITY AND TECHNOLOGY. Plant capacity : 290,000 MT of Cumene per year. On stream factor : 8,000 Hours. Hourly production rate : 36.25 MT/hr of Cumene . Bitter almonds are the source of the aromatic compound benzaldehyde. Sources of . Benzene. Benzene. , C. 6. H. 6. , is the . parent hydrocarbon . of the . especially stable . compounds known . as . In 1825, Michael Faraday isolated a hydrocarbon called benzene, which consists of a six-carbon ring with alternating double bonds and the molecular formula C. 6. H. 6. . . Learning Goal . Describe the bonding in benzene; name aromatic compounds, and draw their line-angle structural formulas.. with the molecular formula . C. 6. H. 6. . benzene is a . colorless. and . highly flammable . liquid with a . sweet smell . and a relatively . high melting point. .. What is Benzene ?. Molecular orbital structure of benzene. Objective. To know about . electrophilic. substitution reactions. Success criteria. Understand . the mechanism of the . electrophilic. substitution reactions of . benzene. Understand this for . halogenation. The Discovery of Benzene. Benzene was discovered in . 1825. by the English chemist . Michael Faraday . (Royal Institution). Faraday called this new hydrocarbon “. bicarburet. of hydrogen”.. Faraday isolated benzene from a compressed illuminating gas that had been made by .