PPT-Benzene and its derivatives

D r Zamir G Khan Assistant Professor H R Patel Institute of Pharmaceutical Education and Research Shirpur Dist Dhule MS 425405 26022024 2 26022024 3 Methods for preparation of benzene. 15-8. Benzene undergoes substitution reactions with electrophiles.. Electrophiles attack benzene by substituting for a hydrogen atom, not addition to the ring.. Under the conditions of this type of reaction, ordinary non-aromatic conjugated polyenes would polymerize rapidly.. Aromaticity. TNT. 8-methyl-N-vanillyl-6-nonenamide (. Capsaicin). Buckminsterfullerene. Key points & objectives:. Aromatic molecules are cyclic, conjugated, flat, and unusually stable. 4n + 2 electrons (. M.ARULSELVAN. Syllabus. Benzene and Aromaticity. 4.1 Concept of aromaticity:. . . -Huckel's rule for aromaticity, . -identification of aromatic, . -Non-aromatic and anti aromatic systems based on planarity, conjugation and Huckel's rule.. Environmental Health, Safety and Risk Management. University of Alaska Fairbanks. August 2011. 1. Overview. Properties and Sources of Benzene. Exposure Limits. Routes of Exposure and Health Effects. Protecting Yourself. Arenes are . aromatic hydrocarbons . containing 1 or more benzene rings. . A benzene ring is a ring of . 6 carbon atoms. , each of which is also bonded to a hydrogen atom, with molecular formula . C. By Taylor Hatchett. What is Benzene?. Chemical. C. olorless or light yellow. L. iquid at room temperature. Has a sweet odor . H. ighly flammable. E. vaporates quickly into air. What is Benzene?. Vapor is heavier than air. 15-4. The UV-visible spectrum of benzene reveals its electronic structure.. The energy gap between bonding and antibonding orbitals is greater in benzene than for acyclic trienes.. The UV spectra of benzene shows absorbances at smaller wavelengths (higher energy) than does the spectra of 1,3,5-hexatriene:. Dr. . Shatha. I . Alaqeel. 108 . Chem. Learning Objectives. By the end of chapter four the students will:. Understand the resonance description of structure of benzene. Understand the hybridization in benzene. Benzene. Colorless liquid with sweet scent often produced from petroleum . Flammable (flashpoint below 37.8 °C). Carcinogenic, reproductive toxin . Toxic, skin irritation and burns. Extremely toxic to aquatic life. with the molecular formula . C. 6. H. 6. . benzene is a . colorless. and . highly flammable . liquid with a . sweet smell . and a relatively . high melting point. .. What is Benzene ?. Molecular orbital structure of benzene. AROMATIC HYDROCARBONS-. -------Benzene. Synonyms. Benzol. , . Benzole. , . Benzolene. , Coal naphtha, Phenyl hydride, . Annulene. , Carbon oil, . Cyclohexatriene. , Mineral naphtha,. Motor benzol, Phene, Pyrobenzol, Pyrobenzole.. UNIT I : Benzene & its derivatives. PART -I. Electrophilic Aromatic . Substitution Reactions. Aromatic compounds (Benzene) . undergo electrophilic aromatic substitution (. EAS).. Arene . (. Ar. -H) is the generic term for an aromatic . Objective. To know about . electrophilic. substitution reactions. Success criteria. Understand . the mechanism of the . electrophilic. substitution reactions of . benzene. Understand this for . halogenation. D. r. . Zamir G Khan . Assistant Professor . H R Patel Institute of Pharmaceutical Education and Research Shirpur, Dist. Dhule, (M.S) 425405. Copyright @ Mr. Z G Khan. 2. If benzene is 1,3,5-cyclohexatriene as .