PPT-Amines and Amides

1 Amines and Amides both contain nitrogen N 2 Amines and Amides Classified as primary secondary or tertiary based on the number of alkyl groups attached to the nitrogen atom. Chehimi Iluminada Gallardo Jean Pinson and Neus Vila Departament de Qu mica Universitat Auto noma de Barcelona Bellaterra Espan a ITODYS Universite Paris 7Denis Diderot 75005 Paris France and Laboratoire dElectrochimie Mole culaire Universite Paris Amines are basic nitrogen-containing compounds that are derivatives of ammonia. Amines are classified as:. Primary. . (the nitrogen atom has one hydrocarbon group directly attached). Secondary. . (the nitrogen atom has two hydrocarbon groups directly attached). Amine nomenclature. diisopropylamine. pyrrole. nicotine. histamine. pyrrolidine. Formation of amines. triethylamine. Mechanism for LAH reduction of amides. 1-methylpiperidine. One equivalent . SN2 is faster the more R groups on N. Ch19 Amines( Page 1 Amines Amines are derivatives of ammonia with one or more alkyl groups bonded to the nitrogen . Amines can be classified as primary , secondary or tertiary , meaning one , t Tylenol, an aspirin substitute, contains acetaminophen. Acetaminophen is an amide; it acts to reduce fever and pain; however, it has little anti-inflammatory effect.. Learning Goal . . Draw the amide product from . A heterocyclic amine is a cyclic organic compound that consists of a ring of five or six atoms, of which one or two are nitrogen atoms.. The aroma of pepper is due to . piperidine. , a heterocyclic amine. In a reverse reaction of . amidation. , hydrolysis occurs when water and an acid or a base split an amide.. Learning Goal . Write balanced chemical equations for the hydrolysis of amides.. Acid Hydrolysis of Amides. . Instructor. Dr. Upali Siriwardane (Ph.D. Ohio State) . E-mail: upali@chem.latech.edu . Office. : 311 Carson Taylor Hall ; Phone: 318-257-4941;. Office Hours. : . MWF 8:00 . am - . 10:00 . am; . 108 . Chem. Learning Objectives. Chapter ten discusses the . amines and . by the end of this chapter the students will:. . Know the structure . . and classification of amines. . Know the. . naming rules for . Know what amines are and some reactions of amines. Outcomes:. Identify amines. Explain . the reactions of primary aliphatic amines, using . butylamine. as . an example. , with. : water . to form an alkaline . Amines are classified as primary, secondary, or tertiary based upon the number of carbon-containing groups that are attached to the nitrogen atom. Those amine compounds that have only one group attached to the nitrogen atom are primary, while those with two or three groups attached to the nitrogen atom are secondary and tertiary, respectively. Classification of amines. Nomenclature of amines. Physical Properties of amines. Preparation of amines. Reaction of amines. 2. By the end of this chapter the student . will know:. Learning. . Objectives. Write the common and IUPAC names for amides and the products of formation and hydrolysis.. Tylenol, an aspirin substitute, contains acetaminophen. Acetaminophen is an amide. It acts to reduce fever and pain; however, it has little anti-inflammatory effect.. Amines are more basic than ammonia due to the presence of unshared electron pair on nitrogen atom. THE ORDER OF BASICITY. T. ertiary amines- Secondary- Primary amine. H .