PPT-Amides

BY Jacob Baird and Nathan Carrier Structural components Carbonyl Carbon pi bonded to oxygen httpsuploadwikimediaorgwikipediacommons446IUPACcarbonyldivalentgrouppng Structural components continued. Histamine. Amines. Amides. Amino acid. P. eptides. Comparison of NH. 3. to Amines . 15.1 Amines. pyramidal. VSEPR?. Classification of Amines. Amines are classified by the number of carbons directly bonded to the nitrogen atom: . Amines are basic nitrogen-containing compounds that are derivatives of ammonia. Amines are classified as:. Primary. . (the nitrogen atom has one hydrocarbon group directly attached). Secondary. . (the nitrogen atom has two hydrocarbon groups directly attached). Chapter 1.7 Amines and Amides • An amine is an organic compound, related to ammonia, that contains a nitrogen atom bonded to one or more alkyl groups on each molecule • An amide i A-7 N Li O 1 N N N Li2 N Li Ph 3 O N 4Li N N 5Ph N Li Ph 6 A-8of chiral lithium amides 1. Amines and Amides both contain nitrogen (N).. . 2. Amines and Amides. Classified . as . primary. , . secondary. , or . tertiary. based on the number of alkyl groups attached to the nitrogen atom.. alkaloids. Vinca. , . Rauwolfia. , Ergot, . Nux. . vomica. Indole. Alkaloids. Ergot . Alkaloids. Occurrence:. . Ergot. is the dried . sclerotium. . of a . fungus. ,. . Claviceps. . purpurea. Tylenol, an aspirin substitute, contains acetaminophen. Acetaminophen is an amide; it acts to reduce fever and pain; however, it has little anti-inflammatory effect.. Learning Goal . . Draw the amide product from . In a reverse reaction of . amidation. , hydrolysis occurs when water and an acid or a base split an amide.. Learning Goal . Write balanced chemical equations for the hydrolysis of amides.. Acid Hydrolysis of Amides. Nucleophilic Acyl Substitution. 2. Carboxylic Acids and . Their Derivatives. Carboxylic Acid Derivatives:. Acid Halides. Acid Anhydrides. Types of anhydrides. :. Cyclic esters. Types of amides. Cyclic amides. Amines and Amides. Bonding . Characteristics of . Amines & Amides. . . Hydrocarbons . compounds . containing nitrogen are . the focus of . the chapter 17 on . amines . Amines are derivatives of ammonia molecules that contain a nitrogen atom bonded to one or more alkyl groups on each molecule.. . Many amines have strong, unpleasant odours.. . ex. putrescine. cadaverine. . Instructor. Dr. . Upali. . Siriwardane. (Ph.D. Ohio State) . E-mail: . upali@latech.edu . Office. : 311 Carson Taylor Hall ; Phone: 318-257-4941;. Office Hours. : . MTW 8:00 - 10:00 am; . . Write the common and IUPAC names for amides and the products of formation and hydrolysis.. Tylenol, an aspirin substitute, contains acetaminophen. Acetaminophen is an amide. It acts to reduce fever and pain; however, it has little anti-inflammatory effect.. Transition Metal . Catalyzed . Amide . B. ond . F. ormation. - May, 11. th. 2016 -. Table of contents. Introduction. Generalities about amides. Metal Catalyzed C-N . bond formation. Ru-catalyzed conversion of alcohol and aldehydes into amides.