PPT-Lecture 13 CATALYSIS – OXIDATION OF ALKENES

Copyright The McGrawHill Companies Inc Permission required for reproduction or display Acetaldehyde of commercial importance oxidation to acetic acid dehydration to acetic anhydride. Chapter 4. Reactions in Aqueous Solution. James F. Kirby. Quinnipiac University. Hamden, CT. Solutions. Solutions. are defined as homogeneous mixtures of two or more pure substances.. The . solvent. 9. . Slides. LIPID. CATABOLISM. lipid menagerie. phospholipid. triglyceride. from McDonalds to Metabolism…. fig17-1. from McDonalds to Metabolism…. The chylomicron: a lipoprotein. fig17-2. mobilization . 11-1. Alkenes are characterized by the presence of a double bond.. The general formula of an alkene is C. n. H. 2n. , the same as for a cycloalkane.. Common nomenclature for alkenes replaces the corresponding alkane suffix –ane with -ylene. . My office hours. rh. 2130 Pacific Hall. Wed . 3:00-4:00. Thr. . 3:00-4:00. Metabolic Biochemistry BIBC 102. hppt://courses.ucsd.edu/rhampton/bibc102. office hours. . 2130 . Pac Hall. exams. 1 midterm, 1 final. . H—. O. H. C. C. +. O. H. C. C. H. Acid-Catalyzed Hydration of Alkenes. reaction is acid catalyzed; typical hydration medium is 50% H. 2. SO. 4. -50% H. 2. O. Follows Markovnikov's Rule. H. ydrohalogenation. Division of Material. Alkenes and Alkynes are very versatile molecules in Organic Chemistry. As a result, there is a lot of information we need for them. . To make it manageable, the information is divided into two chapters.. Katja. Dove. PhD Candidate, . Department of Biochemistry, University of Washington. Email: Katja.Dove@seattlecolleges.edu. Please turn in your take-home part for midterm 1 BEFORE class. I will hand back in-class exams at the end of class today. Unsaturated Hydrocarbons. Unsaturated hydrocarbon. :. . contains one or more carbon-carbon double or triple bonds. alkene. :. . contains a carbon-carbon double bond and has the general formula C. n. Dohyung. . Kim. May 2, 2013. Physics 141A. Catalysis. Catalysis . : . Increase . in the rate of reaction due to a catalyst. Types of Catalysts. Homogeneous : Catalyst and Reactant in the same phase. (Redox Titration). 1. Announcements. Midterm. :. . Monday, May . 2, 2016 . from . 11:00 . am – . 11:55 . am in CS . 76, . NO . MAKE UP EXAM. .. . The midterm is a closed book exam. No lab notebooks, no lab manuals, no lecture materials or other materials are allowed. If you are with OSD, make sure to inform them early enough so that they have room for you.. OXIDATION INVOLVING CARBON–NITROGEN SYSTEMS. Metabolism of nitrogen functionalities (e.g., amines, . amides) is . important because such functional groups are found . in many . natural products (e.g. CATALYSIS APPLICATIONS Catalysis Applications Catalysis is the process of increasing the rate of a chemical reaction by the addition of a substance known as a catalyst. The reaction itself does not c Ulrich . Hintermair. , Staff Sheehan, Julie Thomsen . Crabtree & . Brudvig. Labs. Yale Chemistry. Water Oxidation. Two Half Reactions:. . 4H. +. + 4e− → 2H. 2. . Reduction (lower activation barrier) . Announcements I. Mastering – Assignment due this Saturday. Lab Next Week. Quiz on Experiments 9 and 10 and Electrochemistry and Start to Transition Metals. Experiment 9 lab report due Mon./Tues.. Announcements II.