PPT-Relative Reactivities, Structures and Spectra of Carboxylic

201 Carboxylic acid derivatives undergo substitution reactions via the often acid or basecatalyzed additionelimination sequence The relative reactivities of the substrates follow a consistent order. Starter:. Use molecular models to make various alcohol molecules. Keywords:. Esterification, elimination, ester, dehydration. Learning Objectives. A. Model the esterification of alcohols with carboxylic acids. Dr. . Sheppard. CHEM . 2412. Summer 2015. Klein (2. nd. ed. .) . sections: 21.1, 21.2, 21.6, 21.3, 21.15,. . . 21.4, 21.5, 21.10, 21.7, 21.8,. . . 21.9, 21.11, 21.12, 21.13, 21.14. Alcohols. Ethanol. Ethanol is produced from the fermentation of glucose. Glucose is often derived from the hydrolysis of more complex carbohydrates. (C. 6. H. 10. O. 5. ). n. + nH. 2. O . . nC. 6. Upon heating, a slower but thermodynamically more favorable reaction between the carboxylic acid and the amine takes place.. Dicarboxylic acids react with amines to give imides.. Imides, or the nitrogen analogs of cyclic anhydrides, can be formed through the reaction of a dicarboxylic acid and ammonia or a primary amine.. Carboxylic Acid Derivatives. Chapter 14. 1. Carboxylic acids. The . carboxyl group. consists of carbonyl and hydroxyl groups attached to the same carbon.. carb. onyl + hydr. oxyl. . = . carboxyl. An . Chapter 16. Carboxylic Acids. and Esters. Chapter . 16 . Carboxylic Acids and Esters. Surgical technicians prepare the operating room and the patients for surgery by . creating a . sterile environment . :. Sample Problem . 16.1 . Naming Carboxylic Acids. Solution. Step 1 . Identify the longest carbon chain and replace the . e . in the . corresponding alkane . name with . oic. acid. . The IUPAC name of a carboxylic acid . Nucleophilic Acyl Substitution. 2. Carboxylic Acids and . Their Derivatives. Carboxylic Acid Derivatives:. Acid Halides. Acid Anhydrides. Types of anhydrides. :. Cyclic esters. Types of amides. Cyclic amides. Fourth Edition. Karen Timberlake. 16.1. Carboxylic Acids. Chapter 16. Carboxylic Acids and Ethers. © 2013 Pearson Education, Inc.. Lectures. A . carboxylic acid . contains a a hydroxyl group (. –. group. to the carbon in a carbonyl group.. IUPAC Names for Carboxylic . Acids. In the IUPAC names of carboxylic acids, . the . e. . in the alkane name is replaced with . oic. . acid. . Common Carboxylic Acids . By Grant Morgan. The “Benchmark”. 20 Years in developing a Successor. Spectra was Highly rated & very successful. . We’ve developed a close “RELATIONSHIP” . Converting to Spectra Optia is daunting. Book chapter: 14. Pages: 472-511. Carbon atom of a carbonyl group is attached to a hydroxyl group forming a carboxyl group. As functional group – attached to an alkyl group or an aromatic group. IUPAC names. RCOOH and . ArCOOH. Functional Group =. O. C -OH. Common Names…. 1C – Formic Acid (. Methanoic. Acid). From Formaldehyde (. methanal. ). . 2C – Acetic Acid (. Ethanoic. Acid). From Acetaldehyde (. Aldehyde, Ketone, and Carboxylic acids.. Functional Groups Reactivity. :. Functional groups play a significant role in increasing organic compound reactivity, by controlling the direction of the reactions..