PPT-Physiological Properties and Uses of Alcohols and Ethers

911 Methanol Formed by catalytic reduction of CO and H 2 at high temperatures and pressure Used as a solvent a fuel for camp stoves and soldering torches and as a synthetic intermediate Highly poisonous May lead to blindness or death. Thiols. , Phenols, . And Ethers. IUG, . Fall . 2013. Dr. . Tarek. . Zaida. 1. 1. Alcohols. Alcohols are derivatives of hydrocarbons in which 1 or more of the hydrogen atoms has been replaced by a hydroxyl (-OH) . Alcohols and Ethers. Alcohols. Alcohols are compounds whose molecules have a hydroxyl group attached to a saturated carbon atom. The saturated carbon may be that of a simple alkyl group . Examples. Or the saturated carbon may be connected to an . Mass spectrometer. n-hexane. MS. Alcohols, ethers, thiols. Sweet. Hydrogen . bonding. Hydrophilic. Hydrophobic. Oxidation. 12.1 Alcohols: Structure and Physical Properties. An organic compound containing a hydroxyl group attached to an alkyl group. Properties & Synthetic Preps. Hydroxyl groups in natural compounds.. Alcohols. Naturally occurring p. henols: a . hydroxyl group directly attached to an aromatic ring.. Phenols. The –OH of an alcohol. 9-4. Organic esters are derivatives of carboxylic acids.. Inorganic esters are the analogous derivatives of inorganic acids.. Organic and Inorganic Esters from Alcohols. 9-4. Alcohols react with carboxylic acids to give organic esters.. 9-6. Ethers are prepared by S. N. 2 reactions.. Ethers can be prepared by the reaction of an alkoxide with a primary haloalkane or sulfonate ester under S. N. 2 conditions.. The parent alcohol of the alkoxide can be used as the solvent, however other polar solvents are often better, such as DMSO (dimethyl sulfoxide) or HMPA (hexamethylphosphoric triamide).. Starter:. Draw a graph to compare the boiling points of alkanes and alcohols. Keywords:. Volatility, solubility, hydrogen bonding. Alkane. Molecular mass. Boiling point. 30. -89. 44. -42. 58. -0.5. 72. Thiols. , . and ethers. Nomencalture. of alcohols. Use the end . ol. Examples. . Hydrogen bonding in alcohols and phenols. Alcohols and phenols form hydrogen bonds, and hence they have relatively high boiling points. This also makes the lower alcohols miscible with water. As the R group becomes larger, the solubility of alcohols in water decreases dramatically.. (R-OH) and (R-O-R). Members. Smita Jirayingcharoen (Mudmee). Pattraporn Kheerinpharadorn (BB). Sumanas Chamneandamrongkarn (Punpun). Vetaka Prajakchaikul (Ting-Ting). Sidaporn Muangsiri (Kaimod). Alcohol. Ether. Chemistry 11. Ms. McGrath. Ethers. General formula: Ethers are organic compounds that have two alkyl groups joined by an oxygen atom.. R-O-R’, where R and R’ are two alkyl groups (they can be the same or different). 45. -Alcohols . have the general formula R. -. OH and are characterized by the presence of a . hydroxyl group, . -. OH. . -Phenols . have a hydroxyl group attached directly to an aromatic ring. . -Thiols . , Ethers, Aldehydes, and Ketones. Anesthesia is typically administered by a nurse anesthetist who provides care before, during, and after a medical procedure. A nurse anesthetist gives medications to keep a patient asleep and pain-free while monitoring the patient’s vital signs.. Chem. 1. st. 1439 . Outline. Structure of Ethers. Nomenclature of Ethers. Physical Properties of Ethers. Preparation of Ethers. Reactions of Ethers. Epoxides: Structure and Nomenclature. Synthesis of Epoxides. n-hexane. MS. Alcohols, ethers, thiols. Sweet. Hydrogen . bonding. Hydrophilic. Hydrophobic. Oxidation. 12.1 Alcohols: Structure and Physical Properties. An organic compound containing a hydroxyl group attached to an alkyl group.