PPT-ALCOHOLS 1 340 Chem 1

st 1439 Learning Objectives By the end of this chapter the student will know the structure of alcohol Knew the different classes of alcohols Knew the nomenclature of Alcohols Knew the physical Properties . Thiols. , Phenols, . And Ethers. IUG, . Fall . 2013. Dr. . Tarek. . Zaida. 1. 1. Alcohols. Alcohols are derivatives of hydrocarbons in which 1 or more of the hydrogen atoms has been replaced by a hydroxyl (-OH) . Properties & Synthetic Preps. Hydroxyl groups in natural compounds.. Alcohols. Naturally occurring p. henols: a . hydroxyl group directly attached to an aromatic ring.. Phenols. The –OH of an alcohol. 8-4. Methanol is commercially synthesized from . synthesis gas. , a mixture of CO and H. 2. :. A change of catalyst leads to the production of 1,2-ethanediol:. Ethanol can be prepared by the fermentation of sugars or the hydration of ethene:. Learning Objectives:. Know the general formula for alcohols.. Be able to name alcohols.. Describe the shape of alcohols.. Classify primary, secondary, and tertiary alcohols.. Describe the physical properties of alcohols.. Alcohol . – alkyl chain attached to an –OH. . R-OH. Phenol . - aromatic attached to an –OH. Nomenclature. 1. Name the longest chain of carbons which includes the carbon with the hydroxyl group.. Thiols. , . and ethers. Nomencalture. of alcohols. Use the end . ol. Examples. . Hydrogen bonding in alcohols and phenols. Alcohols and phenols form hydrogen bonds, and hence they have relatively high boiling points. This also makes the lower alcohols miscible with water. As the R group becomes larger, the solubility of alcohols in water decreases dramatically.. PHENOLS. Alcohols and Phenols. Alcohols contain an OH group connected to a . a. saturated C (sp. 3. ). They are important solvents and synthesis intermediates. Phenols contain an OH group connected to a carbon in a benzene ring. 45. -Alcohols . have the general formula R. -. OH and are characterized by the presence of a . hydroxyl group, . -. OH. . -Phenols . have a hydroxyl group attached directly to an aromatic ring. . -Thiols . 1. Hydration of Alkenes - . addition of water. - uses H. 2. SO. 4. and heat. Ex.; Hydrate propene.. 2. Hydrogenation of Aldehydes & Ketones –. All . carbon-carbon double bonds in the molecule will be hydrogenated at the same time. Chem. 1. st. 1439 . Outline. Structure of Ethers. Nomenclature of Ethers. Physical Properties of Ethers. Preparation of Ethers. Reactions of Ethers. Epoxides: Structure and Nomenclature. Synthesis of Epoxides. Shatha. I . Alaqeel. 108 . Chem. Learning Objectives. Chapter eight . discusses. . carbonyl . compounds. and . by the end of this chapter the students will:. Know the structural differences between aldehydes and ketones. Alcohols contain an OH group connected to a . a. saturated C (sp. 3. ). They are important solvents and synthesis intermediates. Phenols contain an OH group connected to a carbon in a benzene ring. Methanol, CH. Most of the alcohols are known to be . colourless. liquids or even are said to behave as solid at room temperatures. Alcohols with less molecular weight are said to be highly soluble in water; and with their increase in molecular weight, they tend to become less soluble and their . Kratzel A, Todt D, V’kovski P, Steiner S, Gultom M, Thao T, et al. Inactivation of Severe Acute Respiratory Syndrome Coronavirus 2 by WHO-Recommended Hand Rub Formulations and Alcohols. Emerg Infect Dis. 2020;26(7):1592-1595. https://doi.org/10.3201/eid2607.200915.