PPT-Alcohols & Phenols

Alcohol alkyl chain attached to an OH ROH Phenol aromatic attached to an OH Nomenclature 1 Name the longest chain of carbons which includes the carbon with the hydroxyl group. YX = 0 1 o 2 = 1 2 o 3 henol, styrenated (96- O -- cresol) OHp US EPA, Office of Pollution Prevention and Toxics. Development of Chemical Categories, Chemical RightKnow Initiative. ht Thiols. , Phenols, . And Ethers. IUG, . Fall . 2013. Dr. . Tarek. . Zaida. 1. 1. Alcohols. Alcohols are derivatives of hydrocarbons in which 1 or more of the hydrogen atoms has been replaced by a hydroxyl (-OH) . Mass spectrometer. n-hexane. MS. Alcohols, ethers, thiols. Sweet. Hydrogen . bonding. Hydrophilic. Hydrophobic. Oxidation. 12.1 Alcohols: Structure and Physical Properties. An organic compound containing a hydroxyl group attached to an alkyl group. 8-4. Methanol is commercially synthesized from . synthesis gas. , a mixture of CO and H. 2. :. A change of catalyst leads to the production of 1,2-ethanediol:. Ethanol can be prepared by the fermentation of sugars or the hydration of ethene:. Learning Objectives:. Know the general formula for alcohols.. Be able to name alcohols.. Describe the shape of alcohols.. Classify primary, secondary, and tertiary alcohols.. Describe the physical properties of alcohols.. Ar. -OH). Phenols . are compounds of the general formula . Ar. -OH, where . Ar. - is phenyl, substituted phenyl, or one of the other aryl groups. . I. Structure . and nomenclature:. Phenols . differ from alcohols in having the -OH group attached directly to an aromatic . PHENOLS. Alcohols and Phenols. Alcohols contain an OH group connected to a . a. saturated C (sp. 3. ). They are important solvents and synthesis intermediates. Phenols contain an OH group connected to a carbon in a benzene ring. 45. -Alcohols . have the general formula R. -. OH and are characterized by the presence of a . hydroxyl group, . -. OH. . -Phenols . have a hydroxyl group attached directly to an aromatic ring. . -Thiols . In a phenol the OH group is directly attached to the benzene ring. . In a phenol the lone pair of electrons on the oxygen is delocalised with the electron charge cloud of the . arene. ring. . The delocalised bonding changes the reactivity of the OH group and the . Phenols are organic compounds with a hydroxyl group attached directly to an aromatic ring. They have the general formula . Ar. -OH. Examples of them include phenol, hydroquinone, resorcinol,. o. -cresol, . Alcohols contain an OH group connected to a . a. saturated C (sp. 3. ). They are important solvents and synthesis intermediates. Phenols contain an OH group connected to a carbon in a benzene ring. Methanol, CH. J. Princess . Gracia. , M.. Sc. .,M.Phil.,. Assistant Professor,. Department of . Chemistry,. Bon Secours College for Women, . Thanjavur. .. Introduction-. . Phenols also called as phenolics are a class of chemical compounds consisting of a hydroxyl group (-OH) bonded directly to an aromatic hydrocarbon group.. Ch. 11.4. Combustion of alcohols . Alcohols undergo complete combustion to form carbon dioxide and water.. Denatured alcohol is a useful portable fuel (e.g. for camping stoves) as, unlike LPG, it does not need to be transported in heavy, specialized containers. It is also used as a solvent.. Most of the alcohols are known to be . colourless. liquids or even are said to behave as solid at room temperatures. Alcohols with less molecular weight are said to be highly soluble in water; and with their increase in molecular weight, they tend to become less soluble and their .