PPT-16.1 Intro to Alcohols

Learning Objectives Know the general formula for alcohols Be able to name alcohols Describe the shape of alcohols Classify primary secondary and tertiary alcohols Describe the physical properties of alcohols. Thiols. , Phenols, . And Ethers. IUG, . Fall . 2013. Dr. . Tarek. . Zaida. 1. 1. Alcohols. Alcohols are derivatives of hydrocarbons in which 1 or more of the hydrogen atoms has been replaced by a hydroxyl (-OH) . Write a definition. Write an equation of combustion for . the following alcohols:. Ethanol. Methanol. Propanol. Combustion – The process of burning by reacting a fuel with oxygen. C. 2. H. 5. OH . (l) . and how to identify them. 2. Classification. Primary. : carbon with –OH is bonded to one other carbon. Secondary. : carbon with –OH is bonded to two other carbons. Tertiary. : carbon with –OH is bonded to three other carbons. Mass spectrometer. n-hexane. MS. Alcohols, ethers, thiols. Sweet. Hydrogen . bonding. Hydrophilic. Hydrophobic. Oxidation. 12.1 Alcohols: Structure and Physical Properties. An organic compound containing a hydroxyl group attached to an alkyl group. 1. Chapter 12. Alcohols from. Carbonyl Compounds. Oxidation-Reduction & Organometallic. Compounds. Ch. 12 - . 2. About The Authors. . These PowerPoint Lecture Slides were created and prepared by Professor William Tam and his wife, Dr. Phillis Chang. . 8-4. Methanol is commercially synthesized from . synthesis gas. , a mixture of CO and H. 2. :. A change of catalyst leads to the production of 1,2-ethanediol:. Ethanol can be prepared by the fermentation of sugars or the hydration of ethene:. Alcohol . – alkyl chain attached to an –OH. . R-OH. Phenol . - aromatic attached to an –OH. Nomenclature. 1. Name the longest chain of carbons which includes the carbon with the hydroxyl group.. Starter:. Draw a graph to compare the boiling points of alkanes and alcohols. Keywords:. Volatility, solubility, hydrogen bonding. Alkane. Molecular mass. Boiling point. 30. -89. 44. -42. 58. -0.5. 72. Thiols. , . and ethers. Nomencalture. of alcohols. Use the end . ol. Examples. . Hydrogen bonding in alcohols and phenols. Alcohols and phenols form hydrogen bonds, and hence they have relatively high boiling points. This also makes the lower alcohols miscible with water. As the R group becomes larger, the solubility of alcohols in water decreases dramatically.. 1. Hydration of Alkenes - . addition of water. - uses H. 2. SO. 4. and heat. Ex.; Hydrate propene.. 2. Hydrogenation of Aldehydes & Ketones –. All . carbon-carbon double bonds in the molecule will be hydrogenated at the same time. Chapter . 13. Alcohols, Phenols, . Thiols. , and Ethers. Anesthesia is typically administered by a nurse anesthetist who provides care before, during, and after a medical procedure. A nurse anesthetist gives medications to keep a patient asleep and pain-free while monitoring the patient’s vital signs. , Ethers, Aldehydes, and Ketones. Anesthesia is typically administered by a nurse anesthetist who provides care before, during, and after a medical procedure. A nurse anesthetist gives medications to keep a patient asleep and pain-free while monitoring the patient’s vital signs.. st. 1439 . Learning. . Objectives. By the end of this chapter the student will:. . know the structure of alcohol. Knew the different classes of alcohols.. Knew the nomenclature of Alcohols . Knew the physical Properties. . Most of the alcohols are known to be . colourless. liquids or even are said to behave as solid at room temperatures. Alcohols with less molecular weight are said to be highly soluble in water; and with their increase in molecular weight, they tend to become less soluble and their .