PPT-Alcohols, Phenols and

Thiols and ethers Nomencalture of alcohols Use the end ol Examples Hydrogen bonding in alcohols and phenols Alcohols and phenols form hydrogen bonds and hence they have relatively high boiling points This also makes the lower alcohols miscible with water As the R group becomes larger the solubility of alcohols in water decreases dramatically. Thiols. , Phenols, . And Ethers. IUG, . Fall . 2013. Dr. . Tarek. . Zaida. 1. 1. Alcohols. Alcohols are derivatives of hydrocarbons in which 1 or more of the hydrogen atoms has been replaced by a hydroxyl (-OH) . and how to identify them. 2. Classification. Primary. : carbon with –OH is bonded to one other carbon. Secondary. : carbon with –OH is bonded to two other carbons. Tertiary. : carbon with –OH is bonded to three other carbons. Properties & Synthetic Preps. Hydroxyl groups in natural compounds.. Alcohols. Naturally occurring p. henols: a . hydroxyl group directly attached to an aromatic ring.. Phenols. The –OH of an alcohol. 8-4. Methanol is commercially synthesized from . synthesis gas. , a mixture of CO and H. 2. :. A change of catalyst leads to the production of 1,2-ethanediol:. Ethanol can be prepared by the fermentation of sugars or the hydration of ethene:. Learning Objectives:. Know the general formula for alcohols.. Be able to name alcohols.. Describe the shape of alcohols.. Classify primary, secondary, and tertiary alcohols.. Describe the physical properties of alcohols.. Alcohol . – alkyl chain attached to an –OH. . R-OH. Phenol . - aromatic attached to an –OH. Nomenclature. 1. Name the longest chain of carbons which includes the carbon with the hydroxyl group.. PHENOLS. Alcohols and Phenols. Alcohols contain an OH group connected to a . a. saturated C (sp. 3. ). They are important solvents and synthesis intermediates. Phenols contain an OH group connected to a carbon in a benzene ring. 45. -Alcohols . have the general formula R. -. OH and are characterized by the presence of a . hydroxyl group, . -. OH. . -Phenols . have a hydroxyl group attached directly to an aromatic ring. . -Thiols . 1. Hydration of Alkenes - . addition of water. - uses H. 2. SO. 4. and heat. Ex.; Hydrate propene.. 2. Hydrogenation of Aldehydes & Ketones –. All . carbon-carbon double bonds in the molecule will be hydrogenated at the same time. In a phenol the OH group is directly attached to the benzene ring. . In a phenol the lone pair of electrons on the oxygen is delocalised with the electron charge cloud of the . arene. ring. . The delocalised bonding changes the reactivity of the OH group and the . , Ethers, Aldehydes, and Ketones. Anesthesia is typically administered by a nurse anesthetist who provides care before, during, and after a medical procedure. A nurse anesthetist gives medications to keep a patient asleep and pain-free while monitoring the patient’s vital signs.. Phenols are organic compounds with a hydroxyl group attached directly to an aromatic ring. They have the general formula . Ar. -OH. Examples of them include phenol, hydroquinone, resorcinol,. o. -cresol, . J. Princess . Gracia. , M.. Sc. .,M.Phil.,. Assistant Professor,. Department of . Chemistry,. Bon Secours College for Women, . Thanjavur. .. Introduction-. . Phenols also called as phenolics are a class of chemical compounds consisting of a hydroxyl group (-OH) bonded directly to an aromatic hydrocarbon group.. Most of the alcohols are known to be . colourless. liquids or even are said to behave as solid at room temperatures. Alcohols with less molecular weight are said to be highly soluble in water; and with their increase in molecular weight, they tend to become less soluble and their .