PPT-Preparations of Alcohols & Phenols

1 Hydration of Alkenes addition of water uses H 2 SO 4 and heat Ex Hydrate propene 2 Hydrogenation of Aldehydes amp Ketones All carboncarbon double bonds in the molecule will be hydrogenated at the same time. YX = 0 1 o 2 = 1 2 o 3 henol, styrenated (96- O -- cresol) OHp US EPA, Office of Pollution Prevention and Toxics. Development of Chemical Categories, Chemical RightKnow Initiative. ht Mass spectrometer. n-hexane. MS. Alcohols, ethers, thiols. Sweet. Hydrogen . bonding. Hydrophilic. Hydrophobic. Oxidation. 12.1 Alcohols: Structure and Physical Properties. An organic compound containing a hydroxyl group attached to an alkyl group. 8-4. Methanol is commercially synthesized from . synthesis gas. , a mixture of CO and H. 2. :. A change of catalyst leads to the production of 1,2-ethanediol:. Ethanol can be prepared by the fermentation of sugars or the hydration of ethene:. Learning Objectives:. Know the general formula for alcohols.. Be able to name alcohols.. Describe the shape of alcohols.. Classify primary, secondary, and tertiary alcohols.. Describe the physical properties of alcohols.. Alcohol . – alkyl chain attached to an –OH. . R-OH. Phenol . - aromatic attached to an –OH. Nomenclature. 1. Name the longest chain of carbons which includes the carbon with the hydroxyl group.. Thiols. , . and ethers. Nomencalture. of alcohols. Use the end . ol. Examples. . Hydrogen bonding in alcohols and phenols. Alcohols and phenols form hydrogen bonds, and hence they have relatively high boiling points. This also makes the lower alcohols miscible with water. As the R group becomes larger, the solubility of alcohols in water decreases dramatically.. 45. -Alcohols . have the general formula R. -. OH and are characterized by the presence of a . hydroxyl group, . -. OH. . -Phenols . have a hydroxyl group attached directly to an aromatic ring. . -Thiols . Objective:. To know what phenol is. Success criteria:. Recognise phenol compounds. Recall . the reaction of phenol with bromine water. Compare the reactions of phenols to that of bromine. Explain the difference in reactivity between phenols and benzene. Chapter . 13. Alcohols, Phenols, . Thiols. , and Ethers. Anesthesia is typically administered by a nurse anesthetist who provides care before, during, and after a medical procedure. A nurse anesthetist gives medications to keep a patient asleep and pain-free while monitoring the patient’s vital signs. , Ethers, Aldehydes, and Ketones. Anesthesia is typically administered by a nurse anesthetist who provides care before, during, and after a medical procedure. A nurse anesthetist gives medications to keep a patient asleep and pain-free while monitoring the patient’s vital signs.. st. 1439 . Learning. . Objectives. By the end of this chapter the student will:. . know the structure of alcohol. Knew the different classes of alcohols.. Knew the nomenclature of Alcohols . Knew the physical Properties. . Jamshedpur Cooperative College Jamshedpur. B. Sc. (. Chem. . Hons. ) Semester III. Outline. Nomenclature. Structure. Synthesis. Physical and Chemical Properties. Nomenclature. Phenols . are defined as compounds having hydroxyl group attached directly to a benzene nucleus. Its general formula is . Lecturer . Luma. . Amer. Department of . Pharmaceutical Chemistry. /Collage of pharmacy . 2 . ed. . stage.. Identification of Phenols. phenols are stronger acids than water and. will dissolve in 5% . Most of the alcohols are known to be . colourless. liquids or even are said to behave as solid at room temperatures. Alcohols with less molecular weight are said to be highly soluble in water; and with their increase in molecular weight, they tend to become less soluble and their .