PPT-Complex Alcohols: An Introduction to Synthetic Strategy

89 Mechanisms help in predicting the outcome of a reaction Bromide is a better leaving group than fluoride The negatively polarized alkyl group in the organometallic reagent attacks the positively polarized carbonyl carbon in the carbonyl group. Thiols. , Phenols, . And Ethers. IUG, . Fall . 2013. Dr. . Tarek. . Zaida. 1. 1. Alcohols. Alcohols are derivatives of hydrocarbons in which 1 or more of the hydrogen atoms has been replaced by a hydroxyl (-OH) . Properties & Synthetic Preps. Hydroxyl groups in natural compounds.. Alcohols. Naturally occurring p. henols: a . hydroxyl group directly attached to an aromatic ring.. Phenols. The –OH of an alcohol. 8-4. Methanol is commercially synthesized from . synthesis gas. , a mixture of CO and H. 2. :. A change of catalyst leads to the production of 1,2-ethanediol:. Ethanol can be prepared by the fermentation of sugars or the hydration of ethene:. Learning Objectives:. Know the general formula for alcohols.. Be able to name alcohols.. Describe the shape of alcohols.. Classify primary, secondary, and tertiary alcohols.. Describe the physical properties of alcohols.. Alcohol . – alkyl chain attached to an –OH. . R-OH. Phenol . - aromatic attached to an –OH. Nomenclature. 1. Name the longest chain of carbons which includes the carbon with the hydroxyl group.. Domitilla. Del . Vecchio. Department of Mechanical Engineering. MIT. May 24. th. . 2011, . Sontagfest. 1. Molecular Systems Biology . and Eduardo. 2. CDC 2005 Tutorial Session an EJC 2005: Molecular Systems Biology and Control. PHENOLS. Alcohols and Phenols. Alcohols contain an OH group connected to a . a. saturated C (sp. 3. ). They are important solvents and synthesis intermediates. Phenols contain an OH group connected to a carbon in a benzene ring. 1. Hydration of Alkenes - . addition of water. - uses H. 2. SO. 4. and heat. Ex.; Hydrate propene.. 2. Hydrogenation of Aldehydes & Ketones –. All . carbon-carbon double bonds in the molecule will be hydrogenated at the same time. European Data Access . Forum. Luxembourg, 24.03.2015. Jörg . Drechsler. The Idea . B. ehind . S. ynthetic . D. ata. SDL technique for data dissemination. i. dea . is closely related to multiple imputation for nonresponse. What is synthetic biology?. The synthetic yeast project. The Scramble system. Network analysis to understand cell dynamics. Synthetic Biology?. What is. Robert H. Newman. North Carolina A&T State University. st. 1439 . Learning. . Objectives. By the end of this chapter the student will:. . know the structure of alcohol. Knew the different classes of alcohols.. Knew the nomenclature of Alcohols . Knew the physical Properties. . Alcohols contain an OH group connected to a . a. saturated C (sp. 3. ). They are important solvents and synthesis intermediates. Phenols contain an OH group connected to a carbon in a benzene ring. Methanol, CH. Domitilla. Del . Vecchio. Department of Mechanical Engineering. MIT. May 24. th. . 2011, . Sontagfest. 1. Molecular Systems Biology . and Eduardo. 2. CDC 2005 Tutorial Session an EJC 2005: Molecular Systems Biology and Control. Most of the alcohols are known to be . colourless. liquids or even are said to behave as solid at room temperatures. Alcohols with less molecular weight are said to be highly soluble in water; and with their increase in molecular weight, they tend to become less soluble and their .