PPT-Aldehydes, Ketones, and carboxylic acids

Aldehydes The term Aldehyde come for the words al cohol dehy drogenation Preparation Oxidation of primary alcohols according to the following equation Note Oxidation can be considered as removal of hydrogens. Dr. Talat R. Al-Ramadhany. Introduction . Aldehydes are compounds of the general formula . RCHO. ;. Ketones are compounds of the general formula . RR´CO. . The groups R and R´ may be aliphatic or aromatic. . 18-4. Alkylation of enolates can be difficult to control.. The alkylation of an aldehyde or ketone enolate is an example of a nucleophilic substitution reaction.. The alkylation of aldehydes and ketones is complicated by several unwanted side reactions.. In General. Fragrant odors. Basic building block of housing materials. Hormones. Digestion. Vision. 2. In General. Carbonyl group. C=O. Aldehydes. RCH=O. Formyl. Ketones. RC=OR’. 3. Nomenclature. Chemistry of Cooking. Flavours in Food. Many of the flavours in foods are due to the presence of . volatile. molecules. . Many . flavour and aroma molecules belong to the family called . aldehydes. . Dr. . Sheppard. CHEM . 2412. Summer 2015. Klein (2. nd. ed. .) . sections: 21.1, 21.2, 21.6, 21.3, 21.15,. . . 21.4, 21.5, 21.10, 21.7, 21.8,. . . 21.9, 21.11, 21.12, 21.13, 21.14. The Civet Cat is the original source of . civetone. , a sweet and pungent ketone used as a fixative in perfumery. Aldehydes and ketones are found in many fragrant odors of many fruits, fine perfumes, hormones etc. some examples are listed below.. 19-4. Carboxylic acids are relatively strong acids.. Carboxylic acids have much lower pK. a. values than do alcohols.. The lowered pK. a. values are due to the electron-withdrawing effect of the positively polarized carbonyl carbon and the resonance stabilization of the carboxylate group.. 17-1. The aldehyde function takes precedence over the ketone group in nomenclature.. Simpler aldehydes often retain their common names. These are constructed by dropping the –. ic. or –. oic. . 17-7. Aldehydes and ketones form hemiacetals reversibly.. The reaction of alcohols with aldehydes and ketones parallels the reaction with water:. These equilibria usually favor the starting carbonyl compound.. 18-1. The pK. a. values of the . -hydrogens of aldehydes and ketones range from 16 to 21, comparable to those of alcohols (15-18).. Strong bases can remove  hydrogens leading to anions called . The Civet Cat is the original source of civetone, a sweet and pungent ketone used as a fixative in perfumery. Aldehydes and ketones are found in many fragrant odors of many fruits, fine perfumes, hormones etc. some examples are listed below.. 1. Chapter 16. Aldehydes & Ketones:. Nucleophilic Addition. to the Carbonyl Group. Ch. 16 - . 2. About The Authors. . These PowerPoint Lecture Slides were created and prepared by Professor William Tam and his wife, Dr. Phillis Chang. . Fourth Edition. Karen Timberlake. 14.1. Aldehydes and Ketones. Chapter 14. Aldehydes, Ketones, and Chiral Molecules. © 2013 Pearson Education, Inc.. Lectures. Aldehydes and Ketones. A . carbonyl group. Organic compounds. Functional group identification. Many organic compounds contain an atom or group of atoms that substitute for hydrogen or carbon in a basic hydrocarbon.. The atom or group of atoms is commonly referred to as functional group..