PDF-Chapter Aldehydes and Ketones I

Nucleophilic Addition to the Carbonyl Group Aldehydes replace the e of the parent alkane with al The functional group needs no number Aldehyde bonded to a ring are named using suffix carbaldehyde Benzaldehyde is common short name for benzenecarbalde. Studies on Direct and Indirect Reductive Amination Procedures Ahmed F AbdelMagid Kenneth G Carson Bruce D Harris Cynthia A Maryanoff and Rekha D Shah The R W Johnson Pharmaceutical Research Institute Department of Chemical Development Spring House P Dr. Talat R. Al-Ramadhany. Introduction . Aldehydes are compounds of the general formula . RCHO. ;. Ketones are compounds of the general formula . RR´CO. . The groups R and R´ may be aliphatic or aromatic. . Aldehydes and ketones. Carbonyl Compounds. Contain the carbonyl group . C=O. . Aldehydes: . R may be hydrogen, usually a carbon containing group. Ketones: . R contains carbon. Short. forms. Structures of Aldehydes . In General. Fragrant odors. Basic building block of housing materials. Hormones. Digestion. Vision. 2. In General. Carbonyl group. C=O. Aldehydes. RCH=O. Formyl. Ketones. RC=OR’. 3. Nomenclature. Ketones and aldehydes are related in that they each possess a C=O (carbonyl) group. They differ in that the carbonyl carbon in ketones is bound to two carbon atoms (RCOR ,-Unsaturated Aldehydes and Ketones. 18-8. Conjugated unsaturated aldehydes and ketones are more stable than their unconjugated isomers.. Enones, or . ,-unsaturated carbonyl groups, are stabilized by resonance.. ketons. Formaldehyde.. Acetaldehyde.. Chloral hydrate.. Benzaldehyde. .. Aceton. .. Acetophenone. .. It . contains variety of chemical compound including benzoate, . ceosol. ,, . benzaldehyde. , y-. terpineol. Before you can learn about aldehydes and ketones, you must first know something about the nomenclature of carboxylic acids since many of the names of aldehydes and ketones are derived from the names of the corresponding carboxylic acids.. 1. Chapter 16. Aldehydes & Ketones:. Nucleophilic Addition. to the Carbonyl Group. Ch. 16 - . 2. About The Authors. . These PowerPoint Lecture Slides were created and prepared by Professor William Tam and his wife, Dr. Phillis Chang. . Lesson on the following:. The Carbonyl group. Nomenclature for . Aldehydes. and . Ketones. Properties of . Aldehydes. and . Ketones. . 1.5 . Aldehydes. . and . Ketones. Aldehydes and Ketones. Fourth Edition. Karen Timberlake. 14.1. Aldehydes and Ketones. Chapter 14. Aldehydes, Ketones, and Chiral Molecules. © 2013 Pearson Education, Inc.. Lectures. Aldehydes and Ketones. A . carbonyl group. 1. CHAPTER 16. Aldehydes & Ketones. General, Organic, & Biological Chemistry. Janice . Gorzynski. . Smith. CHAPTER 16 Aldehydes & Ketones. Smith, Janice Gorzynski. General, Organic, & Biological Chemistry 2nd Ed.. Formation of an Aldehyde. Oxidation of Primary Alcohols. General equation:. Primary alcohol aldehyde. RCH. 2. CH=O. EXAMPLE:. 1-propanol. Formation of a Ketone. Oxidation of Secondary Alcohols. Carbonyl Compounds. Contain the carbonyl group . C=O. . Aldehydes: . R may be hydrogen, usually a carbon containing group. Ketones: . R contains carbon. Short. forms. Structures of Aldehydes . and Ketones.